Fabrication of Novel Superhydrophobic Surfaces and Droplet Bouncing Behavior — Part 2: Water Droplet Impact Experiment on Superhydrophobic Surfaces Constructed Using ZnO Nanoparticles

When a liquid droplet impacts a solid surface, it spreads up to a point and the kinetic energy is dissipated by viscosity, collision and surface energy during the process. The droplet can retract if the energy dissipation during the impact process which is only partly governed by surface properties is not too large. Otherwise, the droplet would stick to the surface or break into smaller droplets. In this second part, we introduced contact angle hysteresis (CAH) and studied the impact behavior between a water droplet and a superhydrophobic surface both theoretically and experimentally. On our superhydrophobic surface, the contact angle is about 155° , so the kinetic energy of the droplet can be largely transferred to surface energy. Thus, under certain conditions, the droplet can fully bounce. The impact behavior of normal impact was analyzed theoretically. The critical falling heights for rebound (CFHR) were investigated on constructed ZnO–PDMS superhydrophobic surface in both normal and oblique impact conditions, and CFHR was found to increase with the increase of tilt angle. This shows that the normal Weber number (We _n ) is the major factor governing the rebound, while the tangential Weber number (We _t ) also has effect on the phenomenon. Compared to the energy dissipated by collision and viscosity, the influence of surface properties is relatively small. The adhesion number (N _a ) is the parameter determining the energy dissipated by surface tension and N _a has direct relation with contact angle (CA) and CAH.     

1st Mediterranean Conference on Heat Treatment and Surface Engineering

Abstract

Energy and the environment are not only receiving mass public attention, but are also indisputably the main drivers for the development of present day scientific, industrial, economic and social progress. However, anyone attempting to review these topics faces two huge problems: the overwhelming volume of often conflicting information and the rapidly evolving national, international and global situation. Thus, the survey presented here, with heat treatment and surface engineering in mind, is a selection of ideas, discussion material and data that is designed to trigger focused discussion and substantive contributions.     

33—THE SNARLING OF HIGHLY TWISTED MONOFILAMENTS. PART II: CYLINDRICAL SNARLING

An account is given of an experimental investigation of the cylindrical snarling of highly twisted monofilaments.

The theory underlying cylindrical snarling is set out, and an expression is derived for calculating the critical twist level at which normal snarling will be replaced by cylindrical snarling. Experiments on rubber filaments are described, and it is shown that there is good agreement between the theoretical and experimental results. Further experiments, in which the specimen was allowed to contract freely or forced into other forms, are also described.

It is shown from these experiments that it is difficult to establish the true equilibrium behaviour, since the situation appears to be dominated by frictional effects or by direct barriers to relative movement.     

Influence of heat treatment processes on fatigue performance of particle reinforced aluminium alloys

Abstract

The fatigue performance of particle reinforced metal matrix composites improves as the matrix strength is increased. However, the heat treatment required for high matrix strength induces residual stresses into the material, which need to be balanced against potential distortion during machining of components. This paper reports results showing the fatigue behaviour of a 2124 aluminium alloy reinforced with 25 vol.-% of silicon carbide particles. The effect of quench medium on tensile and rotating bend fatigue strength is reported. Results are correlated with residual stress profiles measured in quenched plates of the material.     

国内外平板电视节能标准对比解析

在介绍国际标准IEC 62087中电视产品工作状态功率测量方法的基础上,分别介绍了美国能源之星、欧洲EnergyLabelling和澳大利亚的MEPS的技术要求和能效标识,并与中国的能效标准GB 24850-2010进行对比,分析异同点.提出未来能效标准应考虑的内容和方向.     

Influence of silane coupling agents on the surface energetics of glass fibers and mechanical interfacial properties of glass fiber-reinforced composites

The effect of various silane coupling agents on glass fiber surfaces has been studied in terms of the surface energetics of fibers and the mechanical interfacial properties of composites. γ-Methacryloxypropyltrimethoxysilane (MPS), γ-aminopropyltriethoxysilane (APS), and γ-glycidoxypropyltrimethoxysilane (GPS) were used for the surface treatment of glass fibers. From contact angle measurements based on the wicking rate of a test liquid, it was observed that silane treatment of glass fiber led to an increase in the surface free energy, mainly due to the increase of its specific (or polar) component. Also, for the glass fiber-reinforced unsaturated polyester matrix system, a constant linear relationship was observed in both the interlaminar shear strength (ILSS) and the critical stress intensity factor (K_IC) with the specific component, γ_S ^SP, of the surface free energy. This shows that the hydrogen bonding, which is one of the specific components of the surface free energy, between the glass fibers and coupling agents plays an important role in improving the degree of adhesion at the interfaces of composites.     

Inverse gas chromatography investigation of the surface properties of cellulose

Cellulose samples differing in origin and crystallinity were examined by inverse gas chromatography (IGC). Surface energy characteristics such as the apparent dispersive component of the surface energy and acid-base properties, and also nanomorphology indices of the different cellulose samples, were assessed. The influence of humidity on these properties was demonstrated. A decrease of 10-20% of the interaction potential was detected. Crystalline cellulose is the most sensitive to the presence of adsorbed water, which possibly disorders its surface structure. IGC appears to be an appropriate method for the evaluation of the surface characteristics of cellulose. However, care has to be taken when trying to understand differences in surface properties between various cellulose samples, since IGC is very sensitive to minor variations in surface characteristics.     

Fiber-stretching test: a new technique for characterizing the fiber–matrix interface using direct observation of crack initiation and propagation

A new micromechanical technique for experimental determination of fiber-matrix interfacial properties is presented. This technique consists in tensile loading of the fiber, with a matrix droplet on it, at both ends, accompanied by continuous direct observation of interfacial crack propagation. In comparison with the well-known microbond test, the new method has two important advantages. First, crack propagation is stable for any embedded fiber length and any relation between adhesion and friction at the interface. Second, compliance of the test equipment does not affect the results, and specimens with long free fiber ends can be successfully tested. A similar result can be reached using the pull-out or microbond test with an 'infinite' (very long) embedded fiber length. An algorithm for separate determination of the interfacial adhesion and friction from experimental relationships between the crack length and applied load is described. The new test was employed to determine the interfacial parameters for composites of glass fibers with polypropylene, polystyrene, and polycarbonate. For each fiber-polymer system investigated, the following parameters were calculated: ultimate interfacial shear strength; critical energy release rate for crack propagation; and adhesional pressure. Our approach to the estimation of the work of adhesion, WA, from micromechanical tests, based on the concept of adhesional pressure, allowed us to calculate the WA values for several thermoplastic matrix-glass fiber pairs and to obtain values consistent with previous estimations made according to other approaches.     

Fracture mechanics testing of the bond between composite overlays and a concrete substrate

This paper presents a methodology for assessing the bond strength of composite overlays to concrete utilizing a fracture toughness test. The principles and practices of existing ASTM standards for determining the fracture toughness of adhesive bonds between double cantilever beam (DCB) metallic and composite specimens (D 3433-93 and D 5528-94a) have been extended to cover the case of an elastic composite layer bonded to a rigid concrete/masonry substrate. In the theoretical section, the dominant loading conditions, relevant ASTM standards, and the development of energy release rate concepts for analyzing a disbonding composite layer modeled as an elastic cantilever beam are presented. The experimental section covers specimen fabrication and preparation, experimental setup, test procedures, post-test evaluation of the specimens, and data processing. The discussion of test results focuses on explaining the variability in measured strain energy release rate, and identifies trends between the measured strain energy release rate and the fraction of the fracture surface retaining cement paste after disbonding. It was found that good-quality composite-to-concrete bond is associated with high fracture toughness of the adhesive and location of the crack path in the concrete substrate. Strict enforcement of surface preparation and adhesive handling procedures was found to play an important role in promoting good bond strength and high fracture toughness. The fracture toughness test developed in this paper can be used for screening various composite-repair systems, to assess the effect of different environmental attacks, and as a quality control tool.     

Characterization of epoxy resin surface energetics

This study has characterized the energetics of both the liquid state and the solid state of two commercially available epoxy resins: a DGEBA- and a TGMDA-based epoxy system. The surface properties of the liquid epoxies were evaluated by wetting measurements using a dynamic contact angle analysis (DCA). The Lifshitz-van der Waals components of the surface tension were found to be similar for both epoxy systems, while the acid-base components were found to be slightly different. Two different techniques were used to characterize the cured epoxy surface properties: wetting measurements and vapor adsorption measurements by means of inverse gas chromatography (IGC). The Lifshitz-van der Waals components of the surface energy were observed to be nearly the same for both epoxies, confirming that both resins have the same potential for non-specific interactions, in both liquid and solid states. Evaluations of the acid-base components of the work of adhesion by DCA and the Gibbs free energy change by IGC suggest that both cured epoxies show non-negligible specific interactions with both acidic and basic probes. However, computations of the accepticity and donicity parameters showed that both cured epoxies are predominantly basic, but also possess non-negligible acidity. It is likely that the presence of water on the solid surface contributes to the acidic character of the cured epoxies. The temperature dependence of the liquid surface tension for both epoxy systems was investigated. The same temperature dependence was observed: the surface tension decreased with temperature, following a linear regression. Corrections for viscous-drag effects on the liquid surface tension measurements were also made.