塔河油田中半径水平井钻井液技术难点与对策

塔河油田中半径水平井存在直井段易缩径、三开井段井壁易坍塌、斜井段和水平段岩屑携带困难等技术难点，室内通过流型调节剂、防塌抑制剂和润滑剂的优选，开发出了性能优良的聚磺混油防塌钻井液体系，并制定了相应的现场施工技术措施。TK449H井、TH48—1井两口水平井的现场试验证明：聚磺混油防塌钻井液具有良好的防塌抑制性、流变性和润滑性，现场钻井液维护处理技术工艺合理、可操作性强；流变性控制理想，井眼清洁，携岩洗井效果好；试验井井壁稳定，井径较规则。聚磺混油防塌钻井液适合在该地区中半径水平井钻井中推广应用。     

天然气C_3―C_8烃类浓缩分析新方法

目前在天然气研究中,对湿气和凝析油气来说,主要是以其中油的C4―C7烃类指纹和天然气的碳同位素来揭示天然气的成因,但在很多情况下,天然气和油是不同源的,并且在高―过成熟天然气中可用的有效信息量少。针对这一现状,自制了天然气C3―C8烃浓缩器,在现场井口直接采集天然气浓缩样品,并建立了天然气C3―C8烃浓缩实验新方法。该方法能有效地分析出天然气中的C3―C8烃类,为解决天然气组分少而气源对比困难等问题提供了新思路和新方法。     

Hierarchical NiMoS and NiFeS Nanosheets with Ultrahigh Energy Density for Flexible All Solid‐State Supercapacitors

Highly flexible supercapacitors (SCs) have great potential in modern electronics such as wearable and portable devices. However, ultralow specific capacity and low operating potential window limit their practical applications. Herein, a new strategy for the fabrication of free‐standing Ni?Mo?S and Ni?Fe?S nanosheets (NSs) for high‐performance flexible asymmetric SC (ASC) through hydrothermal and subsequent sulfurization technique is reported. The effect of Ni²⁺ is optimized to attain hierarchical Ni?Mo?S and Ni?Fe?S NS architectures with high electrical conductivity, large surface area, and exclusive porous networks. Electrochemical properties of Ni?Mo?S and Ni?Fe?S NS electrodes exhibit that both have ultrahigh specific capacities (≈312 and 246 mAh g^?1 at 1 mA cm^?2), exceptional rate capabilities (78.85% and 78.46% capacity retention even at 50 mA cm^?2, respectively), and superior cycling stabilities. Most importantly, a flexible Ni?Mo?S NS//Ni?Fe?S NS ASC delivers a high volumetric capacity of ≈1.9 mAh cm^?3, excellent energy density of ≈82.13 Wh kg^?1 at 0.561 kW kg^?1, exceptional power density (≈13.103 kW kg^?1 at 61.51 Wh kg^?1) and an outstanding cycling stability, retaining ≈95.86% of initial capacity after 10 000 cycles. This study emphasizes the potential importance of compositional tunability of the NS architecture as a novel strategy for enhancing the charge storage properties of active electrodes.     

（英）基于SU8的远红外超材料完美吸收器理论研究

设计了一种基于SU8介质材料的工作波段为20-30微米范围内的的多层超材料吸收器。该吸收器由金属颗粒周期阵列、介质间隔层和金属底层组成。利用LC模型和FDTD数值模拟方法,通过对SU8介质层厚度、金属颗粒阵列周期、金属颗粒尺寸等参数的优化,实现了对20-30微米波段范围内入射波的接近100%的完美吸收。并在上述研究基础上进一步设计了具有双层谐振腔的双模完美吸收器。通过数值模拟发现,由于SU8介质间隔层厚度的增加,上下两个谐振吸收器可以分别独立实现对特定波长的完美吸收。相应的特征共振吸收波长符合LC模型的预测。同时,数值模拟结果进一步证实了共振吸收频率与入射角度无关。该完美吸收机制可以归因于入射光在金属底层-SU8介质层-金属颗粒层所组成的谐振腔内多次反射吸收。     

Stimuli‐Responsive DNA‐Gated Nanoscale Porous Carbon Derived from ZIF‐8

Stimuli‐responsive nanoscale porous carbon derived from ZIF‐8 (NCZIF) gated by DNA capping units is reported. The NCZIF is first obtained by calcination of nano‐ZIF‐8 crystals under an inert atmosphere. It is further conjugated with amine‐modified single‐stranded DNA after carboxylation (DNA/NCZIF). The guest molecules are sealed in the pore of NCZIF by the formation of a DNA duplex structure on the surface of NCZIF. As proof of principle, two systems that can be, respectively, used for controlled drug delivery and biosensing are introduced. In the first system, the drug model (rhodamine 6G, Rh6G) is locked in the NCZIF by the DNA capping units composed of rich‐G sequences and its complementary DNA strand. The in vitro cellular experiments reveal that DNA/NCZIF has good biocompatibility and can controllably release Rh6G upon the K⁺‐stimuli in cells. In the second system, the signal probe (methylene blue, MB) is locked in the NCZIF and then released after the unlocking of the pores triggered by the dissociation of the aptamer‐hybrid capping units. The MB‐loaded DNA/NCZIF can linearly respond to target molecules in the range from 1 × 10^?9 to 10 × 10^?6 m and has good specificity.     

基于STM8S的室内甲醛检测系统设计

针对目前越来越严重的室内甲醛污染问题,设计了以STM8S为控制核心的便携式室内甲醛检测系统。该系统创造性地设计了一种基于减法器的硬件抗干扰电路,克服了以往甲醛电化学传感器检测设计电路中,采用温、湿敏电阻对传感器温、湿度系数进行补偿所造成的测量精度不足问题,并结合采样滤波算法和拉格朗日插值算法对采集的数据进行软优化。系统具有甲醛浓度阈值设定与超限报警功能,温度、湿度、万年历显示等辅助功能,真正实现了便携式与智能化的结合。实验结果证明,该系统在实际应用中具有较高的灵敏度、准确度、操作简单、性价比高等特色,还可推广应用于其他需要对甲醛浓度进行检测的场合。     

利用背面曝光技术制造大高宽比SU8结构的一种新方法

提出了一种解决大高宽比SU8结构的新方法.该方法是将SU8胶涂在一块掩模上,紫外光从掩模的背面照射,这样SU8胶的曝光将从底部开始,不需要进行过曝光来保证底部胶的曝光剂量,从而很容易控制曝光剂量和SU8胶结构的内应力.实验结果表明,该方法能够得到高宽比为32的SU8结构,而文献报道的SU8胶结构的高宽比最大仅为18.     

8mm高分辨机载合成孔径雷达

介绍了8mm高分辨机载SAR雷达的组成、主要技术参数、工作原理及其研制情况,最后给出了该雷达飞行成像试验的结果。     

填丝TIG焊接Mo—Cu合金与18-8不锈钢接头的微观组织

采用填丝钨极氩弧焊（TIG）对Mo—Cu合金与18—8不锈钢进行焊接．采用金相显微镜、扫描电镜、显微硬度计及x射线衍射仪等对Mo—Cu／18—8接头的微观组织、显微硬度、元素分布及熔合区附近的物相组成进行分析．结果表明,Mo—Cu合金侧的熔合区为马氏体和奥氏体的混合组织,焊缝和18—8钢侧的熔合区为奥氏体和铁素体双相组...     

ZIF-8衍生柔性多孔炭材料的制备及其电容性能研究

随着柔性可穿戴电子器件的迅速发展,柔性储能电极材料引起众多学者们的广泛关注。金属有机框架结构（MOFs）衍生物具有优异的储能性能,但其本征无柔性的物理特性亟需解决。采用静电纺丝技术将ZIF-8结构单元嵌入纤维结构中,获得高电容性能柔性多孔炭纤维。同时,探究了ZIF-8的嵌入量（CF-ZIF-8-1.2）对柔性多孔炭纤维结构及电容性能的影响。实验结果表明：柔性多孔炭纤维CF-ZIF-8-1.2的比电容可以达到425.5 F?g^-1（电流密度为1 A?g^-1）,并呈现出较小的电荷转移电阻（R_s=0.06 Ω）和接触电阻（R_ct=2.31 Ω）,这主要归因于CF-ZIF-8-1.2具有较大的比表面积（212.83 m²?g^-1）、相对丰富的孔隙结构和丰富的N和O原子共掺杂。随后,进一步将其组装成对称柔性超级电容器（CF-ZIF-8-1.2//CF-ZIF-8-1.2）,其能量密度高达7.6 Wh?kg^-1（功率密度为250 W?kg^-1）,在不同弯曲角度和扭曲下呈现出优异的电容保持率（97%以上）,说明柔性多孔炭纤维电极材料具有优异的柔性和稳定性。因此,CF-ZIF-8-1.2柔性多孔炭纤维材料具有潜在应用前景。