CdS纳米薄膜的水浴法制备与表征

CdS是一种直接能隙半导体，其带隙约为2．42eV，是一种良好的太阳能电池窗口层材料和过渡层材料。化学水浴法沉积CdS薄膜具有工艺简单，成本低廉，成膜均匀、致密以及可大面积生产等优点。本文通过对化学水浴法沉积CdS薄膜的研究，阐述了CdS膜的生成和生长过程及其机理，并不断优化此方法中的各种工艺参数，得到了适合做铜铟镓硒薄膜太阳能电池过渡层的CdS薄膜，并对该薄膜的形貌、结构和性能进行了分析。     

High-performance polymer light emitting diodes with interface-engineered graphene anodes

Recently, graphene-based organic light emitting diodes (OLEDs) were successfully demonstrated using graphene as anodes. However, the graphene electrodes have not been utilized for polymer light emitting diodes (PLEDs) yet, although the simpler device structure and the solution-based fabrication process of PLEDs are expected to be more advantageous in terms of time and cost. Here we demonstrate high-performance polymer light emitting diodes (PLEDs) with simple two-layer structures using interface-engineered single-layer graphene films as anodes. The single-layer graphene synthesized by chemical vapor deposition methods was transferred onto a glass substrate utilizing an elastic stamp, and its work function was engineered by varying the duration and the power of ultraviolet ozone (UVO) treatment. Thus, we were able to optimize the contact between silver electrodes and the graphene anodes, leading to the considerable enhancement of light-emitting performance.     

Growth mechanisms and their effects on the opto-electrical properties of CdS thin films prepared by chemical bath deposition

Chemically deposited CdS exhibits high sensitivity in the opto-electrical performance to the growth mechanisms. Hence it is of a great interest to study the effects of growth mechanisms on the opto-electrical performance in such films. Studies were carried out by the means of spectroscopic ellipsometry, and coupled with structural, optical, and electrical characterization. A range of bath temperatures (55 °C–95  °C) were used as the means to alter the growth mechanisms. Ion-by-ion process dominated deposition at lower bath temperatures throughout the length of the deposition. This mechanism produced films composed of single phase cubic crystals with corresponding opto-electrical properties inherent to such structures. Complex formations at higher bath temperatures supplement the sole ion-by-ion mechanisms with the cluster-by-cluster mechanism. This results in a mixed cubic/hexagonal structure, and deviation from stoichiometry. As a result, carrier concentrations and mobility increased nearly eight and four fold respectively. Resistivity decreased more than four times from 33.2 to 7.5 Ω cm. A noticeable decrease of, ~0.2 was observed in the refractive index and an increase of ~0.07 eV in the band gap is also reported. Nuclear magnetic resonance analysis confirms deviation from stoichiometry in the cluster-by-cluster mechanisms, resulting in interstitially trapped Cd⁺² and S⁻² ions. The trapped ions act as donors in the film enhancing its electrical performance.     

A probabilistic framework for next best view estimation in a cluttered environment

In this article, we present an information gain-based variant of the next best view problem for occluded environment. Our proposed method utilizes a belief model of the unobserved space to estimate the expected information gain of each possible viewpoint. More precise, this belief model allows a more precise estimation of the visibility of occluded space and with that a more accurate prediction of the potential information gain of new viewing positions. We present experimental evaluation on a robotic platform for active data acquisition, however due to the generality of our approach it also applies to a wide variety of 3D reconstruction problems. With the evaluation done in simulation and on a real robotic platform, exploring and acquiring data from different environments we demonstrate the generality and usefulness of our approach for next best view estimation and autonomous data acquisition.     

Electronic structure of polythieno[3,4-b]-thiophene-co-benzodithiophene (PTB7) derivatives for organic solar cell applications

Among the new materials currently employed as electron donor element in active layers of organic solar cells (OSCs), PTB7 holds the best results. It has been extensively studied and now there is a search for new derivatives to improve its properties. In this work, a set of 24 polymers derived from polythieno[3,4-b]-thiophene-co-benzodithiophene (PTB7) was studied theoretically, using chemical modifications in the benzodithiophene (BDT) moiety of the PTB7 monomeric units. After evaluations of the electronic and optical properties, including the open circuit voltage and exciton dissociation and recombination conditions, the results indicate that employing chlorine as substituent yields the most promising material for application in active layers together with Phenyl-C₆₁-Butyric-Acid-Methyl-Ester (PCBM) as electron acceptor material.     

非氧化物陶瓷－金属接合及其机理

综述了近年来非氧化物陶瓷－金属接合的发展动态，概括了活性合金法非氧化物陶瓷－金属的接合机理。     

探放水综合监管系统在下梨园煤矿的应用

煤矿井下地质工作者通过探放水的方式预防煤矿水害,探放水施工中的监管必不可少.本文介绍了探放水综合监管系统的原理及构成,并在朔州茂华下梨园矿井搭建探放水综合监管系统.该系统的应用对探放水的全过程进行有效监管,提高了生产效率、减小了监管部门的工作强度.     

基于轨道倾角约束的小行星探测弹、轨道拼接设计研究

设计一个完整的小行星探测轨道方案需要分别对整条轨迹中的弹道段和轨道段进行优化并拼接。目前拼接设计方法中对弹道段终点约束考虑不足、设计效率低。基于实际弹道运算数据计算了指定运载火箭发射弹道对停泊轨道倾角的约束形式,并研究了火箭偏航能力和射向变化对弹道-轨道拼接后无量纲运载能力的影响。结果表明,算例中的健神星探测窗口不适合低轨道倾角发射弹道。考虑一般情况,高轨道倾角发射弹道可以更好适应飞出地球引力影响球的深空探测类任务需求。根据研究结果,提出了对未来深空探测运载火箭的设计需求。     

Improvement of TEOS-chemical mechanical polishing performance by control of slurry temperature

Effects of slurry temperature on the chemical mechanical polishing (CMP) performance of tetra-ethyl ortho-silicate (TEOS) film with silica and ceria slurries were investigated. The change of slurry properties as a function of different slurry temperatures was also studied to obtain higher removal rates and smoother surface morphology. The changes observed with increasing temperature are as follows: the pH showed a slight tendency to decrease, the conductivity of the slurry showed a tendency to increase, the particle size in the slurry decreased, and the zeta potential of the slurry decreased with temperature. The removal rates linearly increased and maintained at the temperature of about 40 °C. The hydroxyl (OH⁻) groups increased in the slurry as the slurry temperature increased and then they diffused into the TEOS film. The surface of the TEOS film became hydro-carbonated by the diffused hydroxyl groups. The hydro-carbonated surface of TEOS film could be removed more easily. Better surface morphology of TEOS films could be obtained at 40 °C of silica slurry and at 90 °C of ceria slurry. It is found that the CMP performance of TEOS film could be significantly improved or controlled by change of slurry temperature with the same slurry.     

Epitaxy of Si:C on Si(001) via methyldichlorosilane

Methyldichlorosilane (CH₃SiHCl₂) is compared to methylsilane (CH₃SiH₃) for vapor phase epitaxy of cubic silicon - carbon (NO :) (Si:C) alloys on Si (001). Parameters of interest are growth rate, percent carbon and crystallinity. Carbon incorporation efficiency and experimental window for epitaxial growth are similar for both precursors. The two precursors differ in Si contribution to the film growth rate.