On the Predominant Electron-Donicity of Polar Solid Surfaces

The reasons for the predominant electron-donicity of almost all solid polar surfaces and its implications are discussed in this paper. By contact angle or interfacial tension measurements, the electron-accepting as well as the electron-donating properties of polar liquids can be ascertained, through the interplay between their energies of adhesion and cohesion. For the solid-liquid interface, direct interfacial tension measurements are not possible, but indirectly, solid/liquid interfacial tensions of polar systems can be obtained by contact angle measurement. However, as the energy of cohesion of a solid does not influence the contact angle formed by a liquid drop placed upon its surface, one can only measure the solid surface'ks residual polar property, manifested by the energy of adhesion between solid and liquid. This residual polar property is of necessity the dominant component; in most cases this turns out to be its electron donicity. When, by means of contact angle measurements with polar liquids, both electron-accepting and electron-donating potentials are found on a polar solid, it is most likely still partly covered with a polar liquid: usually water. The amount of residual water of hydration of a polar solid follows from its polar (Lewis acid-base) surface tension component (γ^AB). The degree of orientation of the residual water of hydration on a polar solid can be expressed by the ratio of the electron-donating to electron-accepting potentials (γ^⊖/γ^⊕), measured on the hydrated surface.     

锌系工件的静电粉末涂装和工艺管理

讨论了锌系工件喷涂的相关工艺、现场管理、技术参数、质量检验和环境要求等。     

An ExPosition of multivariate analysis with the singular value decomposition in R

ExPosition is a new comprehensive R package providing crisp graphics and implementing multivariate analysis methods based on the singular value decomposition (svd). The core techniques implemented in ExPosition are: principal components analysis, (metric) multidimensional scaling, correspondence analysis, and several of their recent extensions such as barycentric discriminant analyses (e.g., discriminant correspondence analysis), multi-table analyses (e.g.,multiple factor analysis, Statis, and distatis), and non-parametric resampling techniques (e.g., permutation and bootstrap). Several examples highlight the major differences between ExPosition and similar packages. Finally, the future directions of ExPosition are discussed.     

Prediction of multicomponent adsorption equilibrium of gas mixtures including supercritical components

A new model to predict the adsorption equilibrium of mixtures containing supercritical components was presented. The difference in the adsorption mechanism between the supercritical components and the condensable components was accounted for in the new model. Lateral interaction in the adsorbed phase was also considered in the local isotherm. The new model was verified by the experimental data of the mixture CH₄/CO₂/C₂H₆ on activated carbon JX101 collected for 283-313 K and pressures up to . It was also verified with the experimental data published previously in literature. Considerable improvement in the prediction precision was achieved in using the new model to predict the adsorption of mixtures on activated carbon.     

取代基及分子量对非离子型纤维素醚表面特性的影响

根据Washburn的浸渍理论(Penetration Theory)和van Oss-Good- Chaudhury的组合理论(Combining Theory)及应用柱状灯芯技术(Column Wicking Technique),对几种非离子型纤维素醚,如甲基纤维素、羟丙基纤维素和羟丙基甲基纤维素的表面特性进行了测试。由于这些纤维素醚的取代基、取代度和分子量不同,所以它们的表面能及其组成部分有着明显的差异。数据说明,非离子型纤维素醚Lewis碱大于Lewis酸,表面自由能的主要成分是Lifshitz-van der Waals力。羟丙基的表面能及其成分都大于羟甲基。而在相同取代基和取代度的前提下,羟丙基纤维素的表面自由能正比于分子量;而羟丙基甲基纤维素的表面自由能则正比于取代度,反比于分子量。实验还发现非离子型纤维素醚中的取代基羟丙基和羟丙基甲基的表面能似乎都大于纤维素的表面能,而实验证明所测试得出的纤维素的表面能及其成分的数据是与文献所吻合的。     

陶瓷部件挤出成型工艺

本文以蜂窝陶瓷生产工艺为例，讨论了陶瓷部件挤出成型过程中，塑性泥料的制备、成型、干燥和烧成等工艺技术和装备问题。     

现代汽车非金属部件的修补涂装

介绍了汽车塑料件的识别、预处理和修补涂装。     

Thermooxidative degradation of natural rubber/clay composite

The clay is treated with a reducing agent and an acid so as to obtain a clay containing various metal components with a variable‐valence state. Then, the clay is coprecipitated with natural rubber (NR) latex to prepare a vulcanized NR/clay composite. The degradation process of the NR/clay composite under hot air condition was studied dynamically by using a Fourier transform infrared spectrometer attaching an in situ sample cell and was also investigated using the TGA method. The test result obtained from the infrared spectrometry indicated that under low decomposition temperature, the decomposition products of the test samples mainly are ethylene, low molecular olefinic hydrocarbon, and carbonyl compounds. As the decomposition temperature rises, the low molecular olefinic hydrocarbon content decreases, the olefine with longer chain is formed, and a lot of alkane decomposition products are formed at the same time. When the content of the metal components with a variable‐valence state in clay such as Cu, Mn, Co, and Fe increases, the oxidation products containing the carbonyl group, the olefinic hydrocarbon, and CO₂ in the decomposition product of the test sample also increase. The TGA result clearly shows a shoulder peak that appears by the side of the main peak on the DTG curve of NR/clay composite. With the increase in the content of metal components with variable‐valence state in clay, the initial degradation temperature of the test sample (T₀), the degradation peak temperature (T_p1), and the final degradation temperature (T_f1) in first‐stage reaction, as well as the degradation peak temperature (T_p2) and the last final degradation temperature (T_f) in second‐stage reaction of all the test samples more or less shift to the direction of low temperature; besides, the activation energy (E) of the reaction of the test samples more or less decreases. This means that the metal components with variable‐valence state promote the oxidative degradation of the clay–rubber masterbatch. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 100: 3809–3815, 2006     

丙烯酸高级酯共聚物组成与其无皂乳液稳定性研究

制备了不同分子结构的丙烯酸高级酯共聚物无皂乳液,测定了丙烯酸和甲基丙烯酸十六酯的竟聚率,考察了共聚物的组成对无皂乳液电解质稳定性、机械稳定性和pH值稳定性的影响。结果显示,丙烯酸竟聚率为2.32,甲基丙烯酸十六酯竟聚率为0.59,随共聚物中丙烯酸组分含量增加,乳液粒子表面羧基含量增大,乳液机械稳定性和pH值稳定性提高,乳液适合在偏碱性条件下使用。     

湿浸法制备活性组分非均匀分布负载型催化剂过程的计算机模拟

对活性组分非均匀分布的负载型催化剂的湿浸法制备过程进行了计算机模拟,其模拟程度可适用于任意多个活性组分的浸渍。发现单组分浸渍时,通过控制浸渍时间可获得活性组分由薄到厚的蛋壳型分布和均匀分布,但通过预浸渍吸附至一定分布后,再在空白溶液中浸渍洗脱,控制洗脱条件也可获得蛋黄、蛋白型的分布;加入竞争吸附剂,进行双组分及多组分浸渍,通过控制浸渍溶液性质及浸渍时间可获得各种类型的活性组分分布,诸如蛋壳型、蛋白型、蛋黄型和均匀型。通过对制备过程参数(如竞争吸附剂的选择、各组分有效扩散系数、初始浓度、吸脱附速率常数等)与活性组分分布形式之间关系的分析,可实现对任一分布形式的催化剂的制备过程参数的优化。这对实际制备催化剂具有指导意义。