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81.
介绍了陕钢集团汉中钢铁有限责任公司近年来在建材生产过程中遇到的钢筋易锈蚀、锚杆钢不圆度超标、切分轧制钢筋表面折叠等典型质量问题及其采取的解决措施。采用这些措施后,产品质量得到了很大提升。 相似文献
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工程中的岩石具有不同的含水性,研究不同含水率岩石动态力学性质的变化规律,对岩石工程的设计和建设具有很强的指导意义。为研究不同含水率对砂岩动态拉伸强度的影响,利用霍普金森压杆(SHPB)试验装置对不同含水率试样进行了一系列动态巴西劈裂试验,研究了不同含水率砂岩在不同加载率条件下的动态拉伸强度变化规律。试验结果表明:岩石的动态拉伸强度随着加载率的增加而增加,其率相关性与含水率有关,饱和试样的率相关性较强,而干燥岩石的动态强度对加载率的变化不敏感。当加载率较低时,岩石的拉伸强度随着含水率的增加而降低;当加载率较高时,由于水的Stefan效应,水对岩石裂纹产生抗力,阻碍其扩展,导致岩石强度增加,饱和试样的动态拉伸强度出现高于非饱和试样强度的现象。 相似文献
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Z.L. Wang G.F. NatererK.S. Gabriel R. GravelsinsV.N. Daggupati 《International Journal of Hydrogen Energy》2009
Copper–chlorine thermochemical cycles for hydrogen production are very promising water splitting cycles. In this paper, different types of copper–chlorine cycles with various numbers of steps are compared. The factors that determine the number and effective grouping of steps are analyzed. It is found that the water requirement in the hydrolysis step is affected by a combination of drying and hydrolysis steps. It is also found that hydrogen can be produced either from electrolysis of cuprous chloride, or from chlorination of copper by hydrogen chloride, which indicates a potential combination of disproportionation and chlorination steps. The major engineering advantages and disadvantages of these cycle variations with different amounts of steps will be analyzed and discussed. 相似文献
86.
Li Zhang Yan SongJianyong Feng Tao FangYujiao Zhong Zhaosheng LiZhigang Zou 《International Journal of Hydrogen Energy》2014
Lanthanum tantalum oxynitride (LaTaON2) powders were prepared by one-step flux method. LaTaON2 photoanodes, which are fabricated by using LaTaON2 powders, are found to exhibit photoelectrochemical activity for overall water splitting. The photocurrent for LaTaON2 photoelectrodes was ca. 120 μA cm−2 at 1.5 V vs. reversible hydrogen electrode (RHE) in 1 M NaOH aqueous solutions (pH = 13.6) under AM 1.5 G simulated sunlight irradiation (100 mW cm−2). The photocurrent of LaTaON2 photoelectrode from back-side illumination is much larger than that from front-side illumination, suggesting that the photoelectrochemical property is mainly limited by poor continuous electron transport in the bulk. Further efforts to ameliorate the electron transport in the bulk of LaTaON2 photoelectrodes are expected to significantly improve their photoelectrochemical performance. 相似文献
87.
《International Journal of Hydrogen Energy》2020,45(35):17174-17190
The study investigated the synergistic effects of rGO and Pt over TiO2 for the HER via artificial photosynthesis under UVB and visible light irradiation. The introduction of glycerol and industrial wastewater to the system as sacrificial reductants signifies that the major reaction pathway is photocatalytic partial water splitting. The material characterizations revealed successful heterojunction formation and provided insight into chemistry behind the activity of the photocatalysts. Amongst various combinations of rGO on TiO2, 1GNT exhibited an HER yield five times that of bare TiO2 under UVB light. Addition of Pt led to the formation of a strong Schottky barrier at the heterojunction and consequently boosted HER performance. 1P0.5 GT presented the highest of 28.5 mmol g−1 h−1 with glycerol and 9.6 mmol g−1 h−1 with wastewater under UVB light respectively. For both binary and ternary photocatalysts, the HER performances dwindled under visible light irradiation, accentuating the insufficient activation of the TiO2. In addition, 1PT outperformed all the other photocatalysts thereby elucidating the impression that rGO and Pt does not work well together in enhancing HER despite quenching the exciton recombination rate of TiO2 significantly. The role of pH in the synthesis and the experiments has been discussed. Finally, the underlying mechanisms in the photodeposition and photoreformation have been proposed. 相似文献
88.
Solar energy-driven photocatalytic water splitting has been investigated for decades to produce clean and renewable green hydrogen. In this paper, the cutting-edge research within the overall water splitting system is summarized from the one-step photocatalytic overall water splitting (POWS) system to the two-step system and the cocatalysts research in this field. In addition, the photocatalytic reaction engineering study is also reviewed which is crucial for future scale-up. This mini-review provides a picture of survey of recent progress of relevant overall water splitting system, with particular attention paid to material system and mechanistic breakthroughs, and highlights the challenge and opportunity of the current system. 相似文献
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