The Structure of the Irreversibly Bound Adhesion Promoter-Substrate Interfacial Layer of γ-Aminopropylsilanetriol on Crystalline Si, as Measured by XPS and FTIR

The irreversibly bound interfacial layer deposited by the γ-aminopropysilanetriol adhesion promoter onto a crystalline silicon substrate, which remains even after profuse washing, was found by XPS to have resulted from the fragmentation and rearrangement of the original γ-aminopropylsilanetriol molecule. A mechanism is proposed, involving the homolytic scission of the terminal N-C bond. One of the subsequent reactions is believed to involve hydrogen loss by abstraction and the formation of a terminal vinyl group, which bonds to the substrate. Support for this mechanism is found in IR spectroscopy of this layer.     

Boundary layer model for char combustion and gasification

A non-steady boundary layer model is developed for numerical simulation of combustion and gasification of a single shrinking char particle. The model considers mass and energy conservation coupled with heterogeneous char reactions producing CO and homogeneous oxidation of CO to CO₂ in the boundary layer surrounding the char particle. Mass conservation includes accumulation, molecular diffusion, Stefan flow and generation by chemical reaction. Energy conservation includes radiation transfer at the particle surface and heat accumulation within the particle. Simulation results predict experimentally measured conversion and temperature profiles of a burning Spherocarb particle in a laminar flow reactor. Effects of bulk oxygen concentration and particle size on the combustion process are addressed. Predicted particle temperature is significantly affected by boundary layer combustion of CO to CO₂. With increasing particle size, char gasification to char combustion ratio increases, resulting in decreasing particle temperature and increasing peak boundary layer temperature.     

K_2O－CaO－Al_2O_3－SiO_2系统自释釉瓷化学组成的研究

本文从酸度系数着手，证实了Ｋ２Ｏ－ＣａＯ－Ａｌ４Ｏ久－ＳｉＯ２系统中存在自释釉组成，限定了其组成范围，０．６７％＜Ｋ２Ｏ＜１．２８％，１０．６４％＜ＣａＯ＜１３．６２％，１１．５３％＜Ａｌ４Ｏ３＜１５．３２％，７２．７３％＜ＳｉＯ２＜７４．０４％，并讨论了自释釉瓷的性能。     

MATHEMATICAL MODELING OF THROUGH-HOLE-PLATING IN ELECTROCHEMICAL MICROFABRICATION II. AXISYMMETRIC TWO-DIMENSIONAL CONVECTIVE MASS TRANSFER

Axisymmetrical, two dimensional mass transfer in a tube and a through-hole was studied. The elliptic convective-diffusion equation was solved numerically by taking into account both the axial and radial diffusion in the entrance region of an infinite tube. The whole mass-transfer region in a tube of finite length was also studied by dividing the domain into several regions according to different mass-transfer mechanisms. A similar analysis is then conducted for a through-hole geometry by assuming a modified Hagen-Poiseuille fluid pattern. Results show that mass-transfer rate in a through-hole is larger than that in a tube by approximately 10%. This is due primarily to faster fluid flow within the concentration boundary layer in a through-hole.     

关于控制氯代烃的政策选择

本文分析了氯代烃的生产所引起的环境问题,并提出了减少氯代烃环境影响的政策选择的基本原则。     

壁湍流周期性吹吸减阻的实验研究

为了研究局部周期性吹吸小扰动对湍流边界层的影响和湍流相干结构减阻控制机理,用实验方法研究了局部周期性吹吸小扰动与湍流边界层的相互作用.采用热线测速技术精细测量了施加吹扰动前后平板湍流边界层不同法向位置的流向、法向和展向速度分量的时间序列信号;通过测量扰动源下游近壁区域平均速度剖面的变化,发现在扰动下游一定空间范围内,粘性底层增厚和壁面减阻;通过对湍流度变化的分析,发现扰动影响猝发的发生;此外通过对展向平均涡量变化的分析发现,在扰动下游形成了2个定常的、强度相似的、大尺度的展向涡,它们起到流体滚动轴承的作用,减小了壁面摩擦阻力.     

铝—钢双金属复合轧制层厚比及轧制力的研究

用实验方法研究了铝－钢双金属复合轧制时层厚比的变化规律。给出了双金属复合时轧制力的计算式。     

表面氧化层对TiMn1.25Cr0.25储氢合金活化性能的影响

通过TiMn1.25Cr0.25合金粉活化前在空气中暴露不同的时间,探讨了表面氧化层的形成对其活化性能的影响。活化测试结果表明：合金的活化难度随着合金在空气中暴露时间的延长而加大。俄歇电子能谱(AES)结果表明,在空气中暴露后的合金表面形成了一层大约6nm-10nm厚的表面氧化层,正是这层氧化层的形成加大了合金的活化难度。扫描电镜(SEM)结果表明合金的活化过程与合金的碎化有着密切的联系。     

在AE中合成流动的血细胞

在实际应用领域,通常需要模拟血细胞在血液中流动的场景,从而产生某种视觉效果。为此,借助After Effects软件技术及其特效插件完成了这一场景的模拟制作。实现过程主要涉及到了粒子、玻璃透视（CC Glass）、表达式、空层（Null Object）、调节层、摄影机动画制作等内容与方法。     

无线Mesh网络入侵检测关键技术研究

本文研究了无线Mesh网络的结构和特点,以及入侵检测系统(IDS)在构建安全WMN中不可替代的作用。深入分析了AdHoc网络IDS、跨层和网络故障检测技术特点以及无线Mesh网络自身的安全需求。在此基础上,本文结合网络故障检测与跨层技术提出了一种基于代理的非对称分布式协作IDS结构,对代理模块设计原则进行了详细分析。最后以MAC自私行为攻击为例对该结构进行了模拟。结果显示,该结构能够很好地适应无线Mesh网络。