从苏皖凹凸棒石粘土制备纯凹凸棒石

通过扫描电镜、透射电镜、XRD等手段分析了来自苏皖的12个凹凸棒石牯土矿床的组分,表明按凹凸棒石主要矿物组合可划分成6种矿石类型,并根据分析结果选择了凹凸棒石型矿石来制取纯样。提纯是用EDTA络合、碳酸钠洗涤、离心及微孔滤膜过滤等步骤相继除去矿石中的碳酸盐、非晶蛋白石、石英等。所得样品纯度经XRD和透射电镜检验评价,纯度大于98％。     

Preparation and characterization of antibacterial silver-dispersed activated carbon aerogels

Silver-dispersed carbon aerogels (CAs) were obtained by direct immersion of organic aerogels prepared by ambient pressure drying technique in AgNO₃ aqueous solution and then carbonization. The effect of preparation conditions such as the resorcinol/catalyst ratio, the feed AgNO₃ concentration, the ratio of aerogel mass/solution volume, immersion time and carbonization temperature on the bulk density and silver content as well as the BET surface area of the dispersed CAs was studied. The dispersion and structure of silver nanoparticles in obtained materials were investigated by means of scanning electron microscopy, transmission electron microscopy and X-ray diffraction. The Ag-dispersed CAs prepared exhibit strong and long-term antibacterial activity.     

A TDS study of D adsorption on terraces and terrace edges of graphite (0 0 0 1) surfaces

Adsorption of thermal (2000 K) D atoms on (0 0 0 1) surfaces of various highly oriented pyrolytic graphite (HOPG) and natural graphite substrates was studied under ultra high vacuum (UHV) conditions with thermal desorption spectroscopy (TDS). D chemisorption on terrace and terrace edge sites of graphite (0 0 0 1) surfaces was identified. Recombinative desorption of D adsorbed on terraces was observed between 400 and 600 K. The analysis of TD spectra from various graphite surfaces reveals the existence of three desorption states intrinsic to graphite (0 0 0 1), and proposed as being due to adsorbate structures composed of one (monomer) and two neighbouring (dimer) chemisorbed D atoms, and aggregates thereof (mixed). The dimer structure is supposed to exhibit higher stability than the monomer. Reaction of D with terrace edges leads to the formation of CD, CD₂ and CD₃-groups at edge C atoms. These groups decompose during heating between 790 and 1300 K via release of gaseous D₂ and CD_x, C₂D_x and C₃D_x-hydrocarbons.     

Structural analysis of pyrolytic carbon deposits on a planar cordierite substrate

Pyrolytic carbon deposits were produced by chemical vapor deposition on a planar substrate of cordierite using methane as a source gas. The structure of the deposits was characterized by light microscopy, scanning electron microscopy (SEM) and transmission electron microscopy (TEM) combined with electron-energy-loss spectroscopy (EELS). The surface morphology is characterized by a cell structure induced by grains elongated perpendicular to the substrate surface. Energetic shift and intensity fluctuation of plasmon peaks in EELS spectra taken from cell and interface regions between the cells correlate with an alteration of the SEM image contrast observed on freshly fractured surfaces. This correlation suggests the presence of a mixture of two materials exhibiting different crystallization degrees. The material located at the interface is more amorphous-like in comparison to the graphite-like material located within cells.     

Effective photopolymerization of C60 films under simultaneous deposition and UV light irradiation: Spectroscopy and morphology study

An effective method for uniform photopolymerization of C₆₀ films using simultaneous deposition and irradiation with ultraviolet (UV) light is described. The photopolymerization process was monitored as a function of irradiation time using Raman and infrared (IR) spectroscopy. New features appeared in the Raman (near the pentagonal pinch A_g(2) mode) and IR spectra (400-1500 cm⁻¹) after more than 20 h of UV irradiation testifying to the transformation of pristine C₆₀ to polymerized C₆₀ phases. Band shape analysis of the vibrational data revealed: (i) the degree of photopolymerization to be ∼90% after 20 h of irradiation, and (ii) the presence of orthorhombic, tetragonal, and rhombohedral phases in the photopolymerized films. Electron microscopy and diffraction studies revealed the amorphous nature of the photopolymerized films which comprised of crystals with a linear dimension of ∼40-60 nm. No evidence for cracks in the surface of the polymerized film was found. The proposed route for photopolymerization provides an opportunity to prepare extended polymeric C₆₀ films suitable for technological applications.     

Carbon nanotubes based on anodic aluminum oxide nano-template

The effect of reaction gas and catalyst on the growth of carbon nanotubes (CNTs) in the anodic aluminum oxide (AAO) nano-template was investigated. A mechanism of CNT growth was proposed, which involves the competitive catalytic carbon deposition between on the Co catalyst particles electrodeposited at the bottom of the pores and on the AAO template itself. Presence of H₂ in the reacting gas mixture significantly affected the morphology and the wall structure of synthesized CNTs: CNTs of high crystallinity grew out of pores with H₂ while no CNTs overgrew in the absence of H₂. CNT synthesis by CO disproportionation showed a lower growth rate and a higher degree of ordering than those grown by C₂H₂ pyrolysis. The unified mechanism of CNT growth on AAO template is also proposed.     

Fabrication of carbon nanotube field effect transistors by AC dielectrophoresis method

Single wall carbon nanotubes (SWNTs) suspended in isopropyl alcohol have been placed between two electrodes by AC dielectrophoresis method. The number of SWNTs bridging the two electrodes is controlled by SWNT concentration of the suspension and deposition time. Through selectively burning off the metallic SWNTs by current induced oxidation, the back-gate carbon nanotube field effect transistors (CNTFETs) with a channel current on-off ratio of up to 7 × 10⁵ have been successfully fabricated. The success rate of the CNTFETs in 20 samples is 60%. These results suggest that AC dielectrophoresis placement method is an efficient technique to fabricate CNTFETs with some flexibilities of controlling CNT reconnection, length and orientation.