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51.
刘跃委 《石油化工安全环保技术》2002,18(4):26-28,31
重质糠醛精制装置设备腐蚀严重与糠醛氧化变质有关,通过分析装置设备腐蚀机理和糠醛氧化、变质的原因,提出了用N_2汽提回收和原料脱水等改进措施。 相似文献
52.
53.
The objective of the present study is to develop multi-functioned coating to the components, which are made of copper with electroplated Ni and are widely used for steel making industry. In this paper, we report the mechanical and thermal properties of Ni based superalloys with carbide sprayed by high velocity oxygen fuel (HVOF), and the detailed effects of sprayed material, spraying conditions, and initial powder structure on these properties. It was found that, among commercial Ni self-fluxing alloys (without fusing treatment), coating with a carbon content of 0.58 mass% had the most preferable properties, with a good balance of the hardness, strength, and thermal shock resistance. The thermal shock resistance depended not only on the strength of the coating but also on the volume contraction when tested at high temperatures. For the several developed Ni based superalloys with carbide, Ni20Cr8Mo5Fe–WC and Ni16Cr15Mo3–WC demonstrated the prominent adhesion strength and thermal shock resistance with high Galvanic corrosion resistance through optimized spraying condition. Also, 20 mass% NiCr–Cr3C2 coating sprayed by using employed relatively small primary particle succeeded in achieving the multi-superior properties; high adhesion strength, high corrosion resistance and thermal shock resistance. 相似文献
54.
Impact of specification changes on chloride-induced corrosion service life of bridge decks 总被引:1,自引:0,他引:1
Trevor J KirkpatrickRichard E Weyers Michael M SprinkelChristine M Anderson-Cook 《Cement and Concrete Research》2002,32(8):1189-1197
A model was developed to determine the time to first repair and to subsequently rehabilitate concrete bridge decks exposed to chloride deicer salts. Said model incorporates the statistical nature of factors affecting the corrosion process. The time to first repair and rehabilitate was predicted for 10 bridge decks built in Virginia between 1981 and 1994.The model was validated using historical service life data for 129 bridge decks built in Virginia between 1968 and 1972. The time for rehabilitation predicted for the newer set of bridge decks was approximately 13 years longer than the normalized time for rehabilitation projected for the older bridge decks. The increase in time for rehabilitation for the newer set of bridge decks was attributed to a reduction in the specified maximum water/cement ratio and increase in clear cover depth. The probabilistic model is shown to be an advancement over the deterministic model currently in use. 相似文献
55.
Adsorption and inhibitive properties of benzimidazole derivatives in acid mild steel corrosion 总被引:1,自引:0,他引:1
Eight diazoles were investigated as corrosion inhibitors of mild steel in 1 M hydrochloric acid using gravimetric and polarization techniques. It was found that the inhibition efficiency increased with the increase of organic substrate concentration, while the adsorption followed the Frumkin isotherm. A correlation between the electronic parameters (induction and mesomeric effects of the substituents, ionization potential values) as well as those of the chemical structure (molecular area) of diazoles molecules and their inhibiting properties was looked for. The results obtained show that a definite interdependence exists but it is not as simple and straightforward as might be expected. 相似文献
56.
In order to study the influence of cerium ion implantation on the aqueous corrosion behavior of zircaloy-4, specimens were implanted by cerium ions with a fluence range from 1×1016 to 1×1017 ions/cm2 at maximum 150°C, using MEVVA source at an extracted voltage of 40 kV. The valence and elements penetration distribution of the surface layer were analyzed by X-ray photoelectron spectroscopy (XPS) and auger electron spectroscopy (AES) respectively. Glancing angle X-ray diffraction (GAXRD) was employed to examine the phase transformation due to the cerium ion implantation in the oxide films. Three-sweep potentiodynamic polarization measurement was employed to value the aqueous corrosion resistance of zircaloy-4 in a 1 N H2SO4 solution. It was found that a significant improvement in the aqueous corrosion behavior of zircaloy-4 implanted with cerium ions compared with that of the as-received zircaloy-4. The improvement effect will declined with raising the implantation fluence. The bigger is the fluence, the less is the improvement. Finally, the mechanism of the corrosion behavior of the cerium-implanted zircaloy-4 is discussed. 相似文献
57.
The hydration phase and pore structure formation in the blends of sulfoaluminate-belite cement with Portland cement 总被引:1,自引:0,他引:1
Sulfoaluminate-belite (SAB) cements are an attractive class of low-energy cements from the viewpoint of saving energy and releasing less CO2 into the atmosphere during their production. Their hydraulic activity, however, does not match that of the ordinary Portland cement (PC) and needs improvement before they can be used on their own. However, SAB cements when blended with PC have the potential to be used effectively in traditional applications as shown by this study. Mortars made with blends of SAB cements and PC, and a cement-to-sand ratio of 1:3 by weight and a water-to-cement ratio of 0.5, indicate a superior protection against corrosion of steel to those made with blends of PC and blast-furnace slag (BFSPC). The prepared mortars were stored at 20 °C for 90 days under either a 60% relative humidity (RH)-dry air, or 100% RH-wet air conditions. With further improvement in the SAB cement quality through better understanding of their characteristics, a genuine competition between SAB/PC and BFSPC can be expected in practice. 相似文献
58.
Ya. Unigovski A. Eliezer E. Abramov Y. Snir E. M. Gutman 《Materials Science and Engineering: A》2003,360(1-2):132-139
Corrosion fatigue tests were carried out on extruded AZ31 (3% Al, 1% Zn, 0.3% Mn, Mg—the rest), AM50 (5% Al, 0.4% Mn, Mg—the rest) and ZK60 (5% Zn, 0.5% Zr, Mg—the rest) Mg alloys in air, NaCl-based and borate solutions. Nsol/Nair ratios (the relative fatigue life) were used for the analysis of the corrosion fatigue behavior of Mg alloys in various environments, where Nsol and Nair are the numbers of cycles to failure in the solution and in air, respectively. Extruded ZK60 alloy reveals very high fatigue and corrosion fatigue properties in comparison with other alloys. However, it has the lowest relative fatigue life (Nsol/Nair 10−3–10−2) or the highest sensitivity to the action of NaCl-based solutions in comparison with that of AM50 and AZ31 alloys (Nsol/Nair 10−2–10−1). Under the same stress, the corrosion fatigue life of extruded alloys is significantly longer than that of die-cast alloys (Nsol for extruded AM50 in NaCl is two to three times longer than that of die-cast AM50). 相似文献
59.
When freshly etched samples of various types of copper were exposed in moderately acid, aerated chloride solutions, two phenomena were observed. First the corrosion potential and the pH of the solution decreased over a shorter time, then the potential increased over a long period (600-1500 min), following an s-shaped pattern. Increase in pH during the second stage was avoided using a pH-stat. The corrosion rate increased little or not at all over the entire period. A tentative interpretation of the short-term behaviour is presented with some reservation. The long-term development of the potential suggests phase formation or transformation following the Avrami pattern. By suitable derivations it was possible to fit the development of potentials to the Avrami equation. Subsequent examinations by Auger spectroscopy proved the presence of thin layers of Cu2O on the copper surfaces, increasing in thickness with exposure time. The dissolution kinetics can be described in terms of two parallel electrochemical reactions and a simultaneous non-electrochemical dissolution reaction. 相似文献
60.
针对辽河油田高凝油区块注高温热水(85—95℃)引起的腐蚀、结垢,开展了室内和现场缓蚀、阻垢试验;分析了不同温度下注水的腐蚀情况,对比、考察了不同的缓蚀剂、阻垢剂及其复配物,得出了如下认识:在注高温热水条件下直接采用常温下使用的防腐蚀、防垢方法是不可行的,必须有针对性地进行高温条件下防腐蚀、防垢的实验研究工作。 相似文献