Transitions from solid to liquid in isotactic polystyrene studied by thermal analysis and X-ray scattering

A three-phase model, comprising mobile amorphous fraction (MAF), rigid amorphous fraction (RAF) and crystalline fraction (C), has been applied to interpret the thermal transitions and structure of cold-crystallized isotactic polystyrene (iPS) from below the glass transition temperature, T_g, to above the melting point. Quenched amorphous iPS films were isothermally crystallized at different temperatures for 12 h. The fraction of crystalline phase, ?_c, was measured by differential scanning calorimetry (DSC), wide angle X-ray scattering and Fourier Transform infrared spectroscopy. The fraction of the mobile amorphous phase, ?_MAF, was obtained from the heat capacity increment at the glass transition temperature. In the three-phase model, the fraction of the rigid amorphous phase, ?_RAF, was found from 1−?_MAF−?_c. Specific heat capacity measurements by standard DSC confirm that the experimental baseline heat capacity conforms to a three-phase model for temperatures ranging from below T_g, up to the relaxation of RAF. The relaxation of RAF appears as a sigmoidal change in heat capacity accompanied by excess enthalpy, in which solid-like RAF is converted to an identical amount of liquid-like MAF.At temperatures above the relaxation of RAF, either one or two major crystal melting endotherms are observed in standard DSC, dependent upon crystallization temperature. However, using quasi-isothermal temperature modulated DSC, we always observed two reversing melting endotherms. The effects of annealing on iPS structure during the quasi-isothermal measurement were assessed using small angle X-ray scattering (SAXS). Combining the DSC and SAXS results, a model for the melting of iPS lamellae at low heating rates is presented.     

液压阻尼器阀试验台电气控制系统

为了保证核电装置中液压阻尼器阀安全运行,设计一种液压阻尼器阀试验台,重点介绍其电气系统的设计.     

A Thermo-Mechanical Study of Some Epoxy Adhesives Subjected to Combined Dynamic and Static Stresses

The object of the present study was to investigate the effect of superimposed dynamic and static stresses on mechanical and thermal properties of some epoxy adhesives. It was found that combinations of shear creep and torsional oscillations, applied simultaneously to adhesive joints at temperatures within the glassy range of the adhesive, led to strengthening of the joints in shear and to an increase in the glass transition temperature of the adhesive. Similar loading stresses applied at temperatures close to the T_g of the adhesive, led to opposite effects on the above mentioned properties of the joints. The width of the glassy-rubbery transition of the adhesives increased, in the whole range of temperatures used in this study and for all epoxy compositions, as a result of subjecting the joints to superimposed dynamic and static stresses. The broadening of the glass transition was interpreted as a result of the stiffening of polymer network during the combined stressing experiments. A linear relationship was found between the area of endothermal peaks in the first DSC scan of specimens subjected prior to test to superimposed dynamic and static stresses at temperatures below T_g, and the shear strength of the joints. In agreement with this observation and with literature data, a linear relationship was revealed also between the glass transition temperature of the resins (measured in the first DSC scan) and the shear strength of the joints. Based on experimental observations and on some literature information, it was suggested that the strengthening of the joint, as well as the changes in thermal properties of the adhesives, are mainly due to physical processes, such as short-range orientation of network chains and an increase in intermolecular interaction between highly polar sites of the network. The possibility that superimposed stressing led to changes in chemical crosslinking was discussed but it seems that no such reactions occurred.     

轻量级安全内存：RISC-V嵌入式微处理器安全增强

近年来,针对嵌入式设备中硬件的新型攻击不断出现,严重威胁嵌入式设备的安全.特别是随着非易失性存储器开始被配备到嵌入式设备中,就需要考虑如何保护配备非易失性存储器的嵌入式设备的安全.安全内存,就是这样一种通过保护内存来增强嵌入式设备安全性的有效手段.通过设计一种安全内存加密引擎来实现安全内存.在保证该安全内存加密引擎足够轻量、开销低的同时,将其集成到RISC-V嵌入式微处理器中,并通过FPGA对该安全内存加密引擎进行了评估.评估结果表明,安全内存加密引擎能够在提升RISC-V嵌入式微处理器安全性的同时,保证其合理的访存性能以及较小的面积开销.研究结果具有良好的参考价值和应用前景.     

有限产能下多部件设备视情维修策略与多订单批量生产联合优化研究

针对有限产能下,面对多个不同要求订单时的订单选取和多部件设备维护决策问题,提出了基于客户满意度的多部件设备视情维修策略和多订单批量生产的联合优化模型。首先,基于比例风险模型描述出各部件的具体劣化趋势,并以虚拟年龄表示各部件的健康状态;其次,根据单次批量生产结束后的实时监测结果和维修阈值,确定不同的维修方式;再次,以利润最大化为优化目标,结合有限产能批量问题模型和客户满意度模型,建立视情维修策略和多订单批量生产联合优化模型;最后,利用模拟退火算法和粒子群算法就行模型求解,并通过算例验证了模型的有效性,使模型更具有现实意义,并对模型相应参数进行了灵敏度分析。     

基于tPUF的物联网设备安全接入方案

针对现有的物联网设备安全接入方案不适用于资源受限的物联网设备的问题,提出一种基于tPUF的物联网设备安全接入方案。利用物理不可克隆函数技术（Physical Unclonable Function,PUF）,物联网设备不需要存储任何秘密信息,实现设备与认证端的双向认证以及协商会话秘钥;利用可信网络连接技术（Trusted Network Connect,TNC）,完成认证端对物联网设备的身份认证、平台身份认证、完整性认证。安全性分析表明,方案能够有效抵抗篡改、复制、物理攻击等。实验结果表明,相较于其他方案,该方案明显降低了设备的资源开销。     

客户分类下生鲜配送两级路径问题与算法研究

生活水平的提高使得消费者对生鲜产品的需求不断增长,进而促进了冷链物流行业的快速发展。将客户按重要性分为重要客户和普通客户两类,以总配送成本最小为目标,建立考虑客户分类的两级容量有限车辆路径优化模型。提出两阶段启发式算法求解该模型：第一阶段设计改进的遗传-模拟退火算法增强全局搜索能力,其中采用轮盘赌选择机制结合精英保留策略保留优秀个体,部分匹配交叉算子结合自适应交叉率维持种群多样性,Metropolis准则以一定概率接受较差解;第二阶段使用精确方法求解一级配送路径。基于Perboli的Set2算例集和Hemmelmayr的Set5算例集,共30个基准案例,分别将所提出算法与四种现有算法进行对比分析,验证了改进算法的效果,并测试了算法的收敛性。基于模拟数据进行模型分析,验证了所提出模型和算法的有效性和适用性。     

Dynamic buffering performance of the honeycomb paperboard filled with polyurethane

A new kind of composite buffering material was made by filling the voids of honeycomb paperboard with polyurethane. Drop tests were performed to evaluate the dynamic energy absorption capacity of the material. Based on the tests results, we analyzed the mechanical behaviors of the material under different conditions and obtained the inherent influencing laws of some factors on the material＇s dynamic buffering performance. It was shown that the dynamic buffering performance varied directly with impact velocity, and inversely with the void diameter, thickness and buffeting area of the composite material.     

第二代农民工市民化与中国共产党执政能力建设

第二代农民工市民化利益要求的实现有助于从阶级基础、群众基础、执政理念、执政资源和执政环境等方面加强党的执政能力建设。在第二代农民工市民化背景下,党应该强化执政为民的理念,构建利益相关制度,强化第二代农民工的工人阶级意识和主人翁意识,鼓励他们积极参与政治生活,有组织、有秩序地进行利益表达,使他们充分享受到城市经济社会发展成果,同时提高党自身的执政能力。     

析架空输电线路上倍容导线的选择

架空输电线路项目扩容改造,当采用倍容导线时,需在技术和经济上对倍容导线进行比较分析。文章对这种导线的种类、特性情况作了介绍,通过在220kV线路上对倍容导线的选择分析,为同类案例的处理提供了借鉴和参考。