基于C8051F350三线制热电阻测温仪表的设计

详细阐述了基于C8051F350片上系统的热电阻测温仪表的工作原理与校准方案,并对测量误差进行了详细的分析,从整体上简化了传统测温仪表的电路结构,降低了仪表电路成本,同时也提高了的可靠性.     

Synthesis and characterization of triclinic structural LiVPO4F as possible 4.2 V cathode materials for lithium ion batteries

A potential 4.2 V cathode material LiVPO4F for lithium batteries was prepared by two-step reaction method based on a carbon-thermal reduction （CTR） process. Firstly, V2O5, NH4H2PO4 and acetylene black are reacted under an Ar atmosphere to yield VPO4. The transition-metal reduction is facilitated by the CTR based on C→CO transition. These CTR conditions favor stabilization of the vanadium as V^3＋ as well as leaving residual carbon, which is useful in the subsequent electrode processing. Secondly, VPO4 reacts with ElF to yield LiVPO4F product. The property of the LiVPO4F was investigated by X-ray diffractometry （XRD）, scanning electron microscopy （SEM） and electrochemical measurement. XRD studies show that LiVPO4F synthesized has triclinic structure（space group p I ）, isostructural with the naturally occurring mineral tavorite, EiFePO4-OH. SEM image exhibits that the particle size is about 2μm together with homogenous distribution. Electrochemical test shows that the initial discharge capacity of LiVPO4F powder is 119 mA·h/g at the rate of 0.2C with an average discharge voltage of 4.2V （vs Ei/Li^＋）, and the capacity retains 89 mA·h/g after 30 cycles.     

燃烧离子色谱法测定α-烯烃齐聚反应体系中催化剂BF3的含量

BF₃作为α-烯烃齐聚反应催化剂,其含量控制对催化反应的调控与产品质量的把控至关重要。通过建立样品前处理方法、优化仪器测试条件与标准溶液配制方法,建立利用燃烧离子色谱测定BF₃·醇催化的α-烯烃齐聚反应体系中F元素含量,进而计算出BF₃含量的方法,并考察了方法的重复性和准确性。结果表明：利用该方法可测定BF₃质量分数范围为2.68～53.50 g/kg的样品,前处理时适量的正丁醇和白油可有效稳定和稀释样品;测定稀释样品中F元素含量的标准曲线分为2段,线性范围分别为300～2000 mg/L和2000～3000 mg/L,线性相关系数R²分别为0.9992和0.9940;测定5次BF₃质量分数结果相对标准偏差均小于5%,方法加标回收率在95.0%～105.0%之间,方法检出限取决于前处理时的取样量,当取样量为5 g时,检出限为1 mg/kg。     

Competent F18 bioglass-Biosilicate® bone graft scaffold substitutes

Biosilicate® glass-ceramic (BioS) offers an attractive choice for the manufacturing of scaffolds because of their high bioactivity, non-toxicity, bactericidal activity and biodegradability. Despite these positive properties, Biosilicate® scaffolds that have been developed so far show low fracture strength, limiting their clinical application. For this reason, our aim was to increase their strength through vacuum infiltration of F18 bioactive glass. First, we calculated the maximum attainable theoretical compressive strength of a scaffold using the Ryshkewitch and Ashby-Gibson models. We show that for a total porosity of 80 %, σ₀ = 250 MPa, and n = 5 the compressive strength estimated by both models is approximately 4.5 MPa. Afterward, the Biosilicate scaffolds were prepared using the foam replica technique and recoated several times with a F18 glass slurry to eliminate surface defects. Scanning Electron Microscopy examination showed that the F18 indeed helped to remove surface defects and partially infiltrated the hollow struts, significantly increasing their mechanical integrity. The F18-BioS scaffolds exhibited a total porosity of 82 %, an average cell size of 525 μm, and compressive strength of 3.3 ± 0.3 MPa, which is close to the predicted value and significantly higher than those of sole BioS scaffolds of a similar structure (< 0.1 MPa). These values are within the range of commercial scaffolds based on Hydroxyapatite (HA) and β-tricalcium phosphate (β-TCP), having a considerable advantage of being more osteoinductive, angiogenic, and highly bactericidal. The F18-BioS scaffolds developed in this work thus have high potential for odontology or craniofacial surgeries that do not involve high load–bearing conditions.     

Nanocrystallization of Pd74Si18Au8 metallic glass

The crystallization process of Pd₇₄Si₁₈Au₈ amorphous alloy has been investigated by transmission electron microscopy, small angle X-ray scattering and three-dimensional atom probe techniques. Although literature suggests that the alloy decomposes into two glassy phases prior to the crystallization, we found that the crystallization occurs directly from a single amorphous phase by the primary crystallization of fcc Pd–Au solid solution, followed by the polymorphous crystallization of the remaining amorphous phase to a Pd₃Si phase.     

基于PIC16F874单片机空调控制器的实现

本文介绍PICl6F874单片机在家用分体式空调上的应用，给出空调主控制板的硬件框图和软件编程流程图，并重点对空调遥控解码和编码过程做了详细的论述。     

DSP56F805和CAN总线在交流伺服系统中的应用与研究

介绍了一种面向电机控制的数字信号处理芯片DSP56F805,采用现场总线控制系统的设计思想, 设计并实现了一个基于以太网和CAN 总线的多电机的伺服控制系统.首先采用DSP56F805 来控制单个永磁同步伺服电机的运行,从而构成FCS(现场总线控制系统) 中的一个智能节点.然后利用CAN 总线把这些智能节点连接起来,构成一个含有多个永磁同步电机(PMSM)子控制系统的FCS,最后利用以太网构成远程控制系统.该系统通过PVT(位置-速度-时间)插值算法对运动曲线进行平滑处理以及运用离散PIP算法对运动过程加以控制.所设计的系统不但便于对多电机进行集中的监测和管理,而且可以实现系统中的各个PMSM间的相互通讯而达到协调工作的目的.实验结果表明,该系统控制精度高、响应速度快、低速运行平稳,同时还具有连接简单、系统可靠和易于实现等优点.     

Thermodynamic analysis and assessment of the Ce–Ni system

An optimised set of thermodynamic parameters for the Ce–Ni system has been obtained using the CALPHAD approach. A thorough thermodynamic analysis of the system has been carried out using different calorimetric techniques and the data have been used in the assessment. The free energy of the liquid phase has been described as a function of temperature and composition using a Redlich–Kister polynomial. Solid compounds have been considered as stoichiometric with the exception of the Laves phases. The phase diagram and thermodynamic quantities calculated from assessed parameters agree well with experimental data.     

基于C8051F352单片机的弹道参数测量系统设计

为提高弹道辨识精度和弹道解算速度,设计了一种基于C8051F352单片机的弹道参数测量系统.通过对弹丸飞行中动压和静压信息的采集、存储和处理,完成弹道参数(初速和射角)辨识.该系统以C8051F352单片机作为处理单元,结合差压传感器和绝压传感器设计而成,采用基于动压-静压的弹道辨识方法,有效地提高了弹道参数测量的精度.实验测试表明:该系统测量精度高,解算速度快,满足弹道辨识的设计要求.     

分子标记多位点排序的并行计算

为了对一组连锁的分子标记位点获得正确的排序进而构建生物遗传连锁图谱,提出了并行算法PMMASLH,针对F2作图群体,通过基于消息传递接口并行最大最小蚂蚁系统求解连锁的多个分子标记位点排序,使用隐马尔可夫模型计算一列有序标记位点所获得的极大似然值作为排序的目标函数。计算机模拟结果表明,该算法执行效率高、计算稳定,排序的功效优于著名的连锁作图软件Mapmaker。