ZrC含量对TiC基金属陶瓷组织和性能的影响

真空烧结制备了TiC-ZrC-Co-Ni系金属陶瓷,研究了ZrC对TiC基金属陶瓷显微组织和室温力学性能的影响。结果表明:未加ZrC的TiC基金属陶瓷的显微组织表现为经典的黑芯-灰壳组织,硬质相形状多为球形;而加入ZrC后的金属陶瓷随着ZrC加入量的增多,组织逐渐细化,硬质相形状大多数为方形,硬质相与粘结相界面呈现直线,在黑芯周围出现白色球状(Ti,Zr)C固溶体。由于Co、Ni对ZrC的润湿性不理想,金属陶瓷的致密度随着ZrC含量的增加而下降,室温力学性能(抗弯强度、硬度、断裂韧性)也随之降低。     

NiAl－Fe金属间化合物合金的正电子寿命谱

测量了塑性金属间化合物合金Ｎｉ（５０）Ａｌ（３０）Ｆｅ（２０），Ｎｉ（５０）Ａｌ（２０）Ｆｅ（３０）和Ｎｉ（６０）Ａｌ（２０）Ｆｅ（２０）单晶和多晶的正电子寿命谱．基于正电子寿命谱的特征参数引入了正电子双区域捕获模型，并讨论了这些合金微观结构与力学性能之间的关系．     

Gr（C）纤维增强镁基复合材料的界面结构

采用真空—压力浸渗工艺制备Ｇｒ（Ｃ）／Ｍｇ复合材料，Ｇｒ／Ｍｇ材料界面上无化学反应迹象，有析出物γ相（Ｍｇ１７Ａｌ１２），该析出物形状、大小与制备工艺条件，主要是纤维预制件温度有关。Ｃ／Ｍｇ复合材料界面Ａｌ含量较基体高出２倍多，文中分析了可能的原因     

Influence of the stress,strain, and temperature on the surface roughness of an AlSl 52100 steel due to an orthogonal cut

In recent years, the finite element method (FEM) has become the main tool for simulating the metal cutting process because research based on trial and error is time consuming and requires high investment. Early studies were done by different investigators. In this research AISI 52100, hardened steel (62 HRC) was selected for an orthogonal machining process as well as metal cutting simulation using the software DEFORM-2D. This software is based on a forging process and has been adapted to an orthogonal machining process. The results of simulated cutting forces were compared with experimental cutting force data to validate the orthogonal cut simulation. Also, the surface roughness was measured, and the influence of the stress, strain, and temperature on the surface roughness was studied.     

Influence of process parameters on thermal-rate treatment of ZA42 alloy

Sand casting process and directional solidification technique combining thermal-rate treatment(TRT) were used. The influence of process parameters on TRT was investigated according to the values of impact toughness. At the same time, the mechanism of TRT was discussed. The results showed that TRT can improve the impact toughness of this alloy, while the hardness is basically constant. The time of heat preservation should not be more than 5min. Different forms of cooling intensification additive have different effects among which the zinc ingot solidified in graphite mold is the best one that can improve impact toughness of samples by more than 80%. With increasing the cooling temperature, the value of α(Al) crystal lattice constant increases. The element Sb has negative effect on TRT.     

4-methoxy-2,6-bis(3,5-dimethylpyrazoyl)-1,3,5-triazine modified carbon paste electrode for trace Cu(Ⅱ) determination by differential pulse volt-ammetry

A differential pulse voltammetric method was developed for the sensitive and selective determination of Cu(Ⅱ) at 4-methoxy-2,6-bis(3,5-dimethylpyrazoyl)-l,3,5-triazine modified carbon paste electrode in 0.05 mol/L KHC8H4O4 solution (pH = 4.02). The oxidation peak of Cu(Ⅱ) was observed at 0.065 V(vs Ag/AgCl) by scanning the potential in positive direc-tion. The analysis procedure consisted of an open circuit accumulation step in stirred sample solution. It was followed by medium exchange to a clean solution and subsequently an anodic potential scan was affected to obtain the voltammetric peak. The current was proportional to the concentration of the Cu(Ⅱ) ion in a range of 1× 10-7-1×10-4 mol/L for 6 min accumulation; the most of metal ions did not interfere with the determination. The developed method was applied to Cu(Ⅱ) determination in coal-ash sample, the results agreed with that of atomic adsorption spectroscopy(AAS).     

Cu-Al-Be形状记忆合金的应力腐蚀性能

用恒载荷法和慢应变速率法及SEM研究了Cu-Al-Be形 状记忆合金在甘油、海水和氨介质中的应力腐蚀性能.结果表明，Cu-Al-Be合金具有良 好的抗海水应力腐蚀性能和较低的氨介质应力腐蚀倾向.单相马氏体有较 好的耐海水腐蚀能力，可减少腐蚀引起的裂纹源；外应力下马氏体的孪晶变形和变体间的界 面迁移，则有利于松弛应力集中，阻碍和延缓腐蚀裂纹源的扩展，从而提高Cu-Al-Be合金的 应力腐蚀能力.     

Determination of heavy metals and volatile aromatic compounds in used engine oils and sludges

Assessment of contaminant releases during utilization of used oils is essential for the determination of environmental acceptability. These paper reports the results of the study examining a toxic metal leachability from used engine oil and sludge samples employing leaching test (TCLP). The leaching test indicated that lead in oil samples exceeded 5-ppm concentration level what qualified them as a toxic waste. The samples of contaminated sludge were found to contain high concentration of total lead, barium and chromium, but the leaching test showed concentration below regulatory limit. The total content of benzene, ethylbenzene, toluene, and xylenes (BETX), and naphthalene in used oil and sludge samples was also determined and was found not to be a significant factor to contamination.     

Gas—Liquid Mass Transfer Coefficient in Stirred Tank Reactors

Volumetric gas—liquid mass transfer coefficient (k_La) data available in the literature for larger tanks (T = 0.39 m to 2.7 m) have been analyzed on the basis of relative dispersion parameter, N/N_cd. It was observed that at a given superficial gas velocity (V_G), k_La values were approximately the same irrespective of geometric configuration (size of the tank, type and size of the impellers, type of the sparger, etc.) at a particular N/N_cd. A single correlation based on N/N_cd is presented which shows satisfactory agreement with the k_La data of different workers.     

螺旋藻多糖铁配合物制备、抗氧化及淋巴细胞增殖活性分析

以三氯化铁为原料,通过络合反应,对螺旋藻多糖(SP)进行结构修饰,制得有机铁化合物〔螺旋藻多糖铁(Ⅲ)配合物SP-Fe(Ⅲ)〕。采用FTIR、DSC、TGA、XRD和SEM对其结构进行了表征,采用DPPH(1,1-二苯基-2-三硝基苯肼)自由基法、羟自由基法等5种方法和MTT(四唑盐)法分析了SP和SP-Fe(Ⅲ)的抗氧化活性和淋巴细胞增殖活性的影响。制备的SP-Fe(Ⅲ)中Fe(Ⅲ)质量分数为16.42%±1.17%。采用5轴蛛网图对SP-Fe(Ⅲ)的抗氧化活性进行了综合评价。结果表明,SP-Fe(Ⅲ)相比SP具有较高的抗氧化活性。在模拟人工胃液消化后,随着消化时间的延长,在pH=6.8的人工肠液中释放出的Fe(Ⅲ)质量分数达到83.64%;在31.25×10–3 g/L的质量浓度下,与SP相比,SP-Fe(Ⅲ)配合物对淋巴细胞增殖提高了44.35%。