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61.
N. JostJ. Karger-Kocsis 《Polymer》2002,43(4):1383-1389
Curing kinetics of a vinylester-urethane hybrid (VEUH) resin consisting of vinylester resin (VE) diluted in styrene and novolac type polyisocyanate (NPI) have been studied by differential scanning calorimetry (DSC). As VEUH is crosslinked via free radical polymerisation between the vinyl functions of styrene and VE, and polyaddition reaction between the secondary -OH groups of VE and -NCO of NPI, it was necessary to study these reactions separately. This was achieved by studying the curing with and without incorporating the NPI. The curing reaction was monitored by measuring the heat of reaction under isothermal and dynamic temperature conditions. Models describing the curing were developed, which are in good agreement with the experiments. A comparison between the curing of the VEUH and the VE resin without NPI leads to the conclusion that the curing of the VEUH as accessed by DSC is dominated by the radical polymerisation of styrene with VE although the two reactions are not time separated. 相似文献
62.
Lanthanum doped nickel and YSZ composite anode (LaNi–YSZ) exhibited a greatly reduced polarization resistance and high performance for electrochemical oxidation of hydrogen and methane, which resulted from a fine anode structure with a high dispersion of nickel catalyst and a high catalytic activity towards methane. 相似文献
63.
Calcining of the mixture of BaCO3 and TiO2 with a ratio 1:4 at different temperatures was carried out to synthesize BaTi4O9 powders. Phase evolution of the samples was studied using the differential thermal analysis (DTA) and X-ray diffractometry
(XRD). Both techniques confirmed that the formation of BaTi4O9 started around 1000 °C. The XRD peaks showed that BaTi4O9 was most pronounced at 1250 °C. X-ray line broadening methods were employed to study the variation of particle size and microstrain
of the BaTi4O9 powders. The Voigt function in a single line and the pseudo-Voigt function in the variance methods were used in our case.
We found that both functions resulted in the same trends, i.e., the particle size increased with the temperature with the
biggest size of 180 and 160 nm, whilst the microstrain yielded the opposite trend with the lowest values of 6.2 × 10–3 and 1.1 × 10–3. The scanning electron microscopy (SEM) study revealed the size of the large particles formed, due to agglomeration, to be
about 0.5–1.9 μm. Furthermore, it was shown that irregular shapes of BaTi4O9 powders necked to each other appeared at 1000 °C and grew into ellipse and rod shapes at 1250 °C.
Electronic Publication 相似文献
64.
65.
《Chemical engineering science》2002,57(18):3831-3838
A semi-batch extraction process of anthocyanins was studied in a packed bed. Methanol was used as solvent and the raw material studied consisted of skins of the tempranillo grape, which was obtained from the pomace from red wine vinification. The results show large diffusional effects due to strong control from the mass transfer. The best results were obtained using a high temperature and a high flow rate. A penetration model is proposed in terms of a bed of spherical particles. The model provides a value for the diffusion coefficient of the solute within the solid matrix. It can be seen that the adjustment of the model is satisfactory and that it is able to predict, to a reasonable extent, the yield of the extraction process. 相似文献
66.
The objective of this work is to simulate the gas flow across a concrete wall of a nuclear power plant internal enclosure. In the laboratory, permeability measurements are generally made on cylindrical samples (15 cm diameter×5 cm height: ∅ 15×5 cm) with a steady-state experiment. To be able to predict structural behaviour, we studied size effect and steady-state time with a modified CEMBUREAU permeability test. A statistical approach showed that there is no size effect on concrete permeability. Laboratory results found on cylindrical samples can be applied to tests in situ, where concrete specimens are thicker. A model based on the mass balance relation provided times to reach steady state and reproduced experimental flow kinetics for uniform water content across specimens. 相似文献
67.
T. Caillot P. Glin J. Dailly G. Gauthier C. Cayron J. Laurencin 《Catalysis Today》2007,128(3-4):264-268
La0.8Sr0.2CrO3 based Ru catalysts were studied as potential new anodic materials for Solid Oxide Fuel Cells directly fed with methane and operating at intermediate temperature under water deficient conditions. Two kinds of materials very close in composition were obtained following two different preparation procedures. Catalyst samples were characterized by physicochemical methods (XRD, SEM, BET and Chemical Analysis) and studied in methane steam reforming under water deficient conditions. Carbon formation during catalytic testing was studied by temperature programmed oxidation (TPO). Both types of catalysts were found very active and resistant to carbon formation. The unusual oscillatory behavior of the catalytic activity observed for one type of catalyst was discussed. 相似文献
68.
用VBA编程生成螺纹三维实体模型 总被引:1,自引:0,他引:1
阐述了在AutoCAD中用VBA编写的,造型螺纹三维实体模型的程序的理论依据和算法。介绍了该程序的使用方法,列出了程序框图和重要部分的程序清单。 相似文献
69.
Ti1−xVxO2 solid solution film photoelectrodes were prepared by the dip-coating sol–gel method. X-ray diffraction and X-ray photoelectron spectroscopy were employed to ensure the formation of the solid solution and their composition. Obvious photoresponses were observed in the visible region for the solid solution film electrodes with x0.05 and the red shift of the photoresponse was enhanced with increasing x. Moreover, the solid solution film electrodes were found to be photoelectrochemically stable. However, the onset potential of photocurrent shifted positively with increasing x. Band model of the solid solution was suggested to explain the effects of the vanadium incorporation on the photoelectrochemical properties. 相似文献
70.
Thermal shock and thermal fatigue study of ceramic materials on a newly developed ascending thermal shock test equipment 总被引:1,自引:0,他引:1
P. K. Panda T. S. Kannan J. Dubois C. Olagnon G. Fantozzi 《Science and Technology of Advanced Materials》2002,3(4):44
A test equipment was designed to study thermal shock and thermal fatigue of ceramic materials subjected to fast heating (ascending). The equipment was designed to generate thermal stress in a test specimen by heating one surface of it by an oxy-hydrogen flame while cooling the opposite surface. The sample cracked when thermal stress exceeded its mechanical strength. The in situ crack formation was detected by an acoustic emission system coupled to the set up. The hot zone temperature was measured by an infra red pyrometer. The equipment was also designed to run thermal fatigue test cycles in automatic mode between two selected temperatures. The temperature and thermal stress distribution in the test specimen were modelled using finite element software. The effect of temperature distribution of the top and bottom surfaces on thermal stresses was studied. It was observed that the thermal stress is very sensitive to the temperature distribution on the top surface and maximum near the periphery of the top surface. This was in agreement with the experimental results in which the cracks were originated from the periphery of top surface. It was also observed that the failure temperature was higher for thicker samples. 相似文献