Cr12钢等温淬火马氏体-贝氏体复合组织的力学性能

Cr12钢经980℃奥氏体化后，于280℃硝盐中等温不同时间获得不同比例的马氏体一贝氏体复合组织，测定了其力学性能．并与常规淬火回火后的力学性能进行了比较。结果表明：具有马氏体-贝氏体复合组织Cr12钢与常规淬火回火的回火马氏体组织相比，除硬度有所降低外，抗弯强度、挠度、冲击韧度及耐磨性均有较大幅度的提高。经980℃加热、280℃等温5h、180℃回火后，Cr12钢具有最佳的综合力学性能。     

22Cr双相不锈钢的临界点蚀温度研究

用动电位法和恒电位法两种不同的方法研究了不同 Cl-浓度对22Cr双相不锈钢临界点蚀温度的影响.结果表明：两种方法所得的结果基本一致，22Cr双相不锈钢的临界点蚀温度随Cl-浓度的增加而降低.同时还分析了点蚀形成和发展的过程，表明温度在临界点蚀温度以下时，蚀点处于亚稳定状态，只有温度高于临界点蚀温度时才能形成稳定的点蚀.      

MICROSCOPIC CORROSION STUDIES OF DUPLEX STAINLESS STEELS

Electrochem,cal scanning tunneling microscopy and scanning electrochemical microscopy have been used for in situ monitoring of localized corrosion processes of different Duplex stainless steels (DSS) in acidic chloride solutions. The techniques allow imaging of local dissolution events with micrometer resolution, as opposed to conventional electrochemical techniques, which only give an overall view of the corrosion behavior. In addition, combined scanning Kelvin probe force microscopy and magnetic force microscopy were used for mapping the Volta potential variation over the surface of DSSs. A significant difference in Volta potential between the austenite and ferrite phases suggests galvanic interaction between the phases. A compositional gradient appears within 2 micrometers across the phase boundary, as seen with scanning Auger microscopy (SAM). In all, the studies suggest that higher alloyed DSS exhibit a more homogeneous dissolution behavior than lower alloyed DSS, due to higher and more similar corrosion resistance of the two phases, and enhanced resistance of the ferrite/austenite phase boundary regions.     

CD—4MCu合金在磷酸介质中的腐蚀磨损行为

测定了CD—4MCu合金在69％H_3PO_4,69％H_3PO_4+500ppm NaCl介质中的腐蚀率、腐蚀磨损—载荷关系及摩擦系数,还用SEM观察了磨痕,实验表明它的耐腐蚀磨损性能优于一般的304不锈钢和高耐蚀的Carpenter20Cb3合金,从CD—4MCu合金双相组织特点可知其中低Ni的面心立方γ相有较高的抗磨损能力。     

TiAl基合金双态组织的控制

研究了TiAl合金双态组织的显微组织参数对力学性能的影响 ,通过对Ti 46 5Al 2Cr 1 5Nb 1V金属间化合物进行特定的热处理 ;分别获得了具有相同晶粒大小、不同片层晶粒体积分数 ,以及相同片层晶粒体积分数、不同晶粒大小显微组织的两个系列的双态复相TiAl合金。研究结果表明 :对于双态复相组织 ,晶粒尺寸由预备热处理过程中的退火时间来控制 ;而片层晶粒体积分数则通过后续热处理温度来控制 ,不同片层晶粒含量双态组织的晶粒尺度可以通过后续热处理时间来控制     

双相不锈钢中奥氏体相内裂纹扩展路径的透射电镜原位观察

在透射电镜下原位观察了裂纹在双相不锈钢中的扩展过程。结果表明,裂纹在双相不锈钢中奥氏体晶粒内扩展时常呈较大的Z字形扩展路径。并且,在主裂纹前端奥氏体晶粒内形核的小裂纹与主裂纹有较强的交互作用,小裂纹尖端二次滑移系的选择和扩展路径为小裂纹尖端应力场和主裂纹尖端应力场共同支配。     

MICROSTRUCTURAL STUDY OF Fe-Cr-Al/Al COMPOSITE COATINGS DURING OXIDATION AND SULFIDATION AT 900 ℃

The microstructure of a composite coating system, which was composed of an inner layer of Fe-Cr-Al and an outer layer of aluminum, was studied after it was respectively oxidized and sulfurdized at elevated temperatures. Apart from the Al2O3 scale formed on the surface, the microstructure of the composite coatings exposed at 900℃ in air for 4h was a three-layer structure. The first layer consisted of a solid solution of Cr and Fe in α aluminum and an intermetallic compound FeAl3, while the second layer was a single phase of the aluminide and the third layer still remained the same appearance as the original Fe-Cr-Al coating.The microstructural observation of the specimen tested at 850-900 ℃ at low oxygen pressure and high sulfur pressure for 576h revealed that the surface coatings of the specimen had transformed into a duplex structure containing an outer layer and a thicker aluminide layer beneath. X-ray diffraction results showed that the out layer was composed of Al2S3 and Al2O3 and that AlCrFe2 was the main phase composition of the aluminide layer, with a few of Al2S3 and Al2O3 accompanied.     

镀Cu-Ni的碳纤维及其复合材料SCIEI

用连续电镀法在碳纤维表面镀Cu后再镀Ni,制备了镀覆Cu-Ni双镀层的碳纤维,研究了Cu-Ni双镀层与碳纤维的高温相容性。并用镀Cu-Ni的碳纤维制备了Cu基复合材料,测试其弯曲强度、线热膨胀系数和电阻率。结果表明,Cu-Ni双镀层在高温下转变为面心立方的Cu-Ni固溶体,克服了在高温下Cu镀层的球化缩聚行为和Ni镀层对碳纤维的催化石墨化作用,且不影响碳纤维的拉伸强度。由于在界面上形成了可溶解微量碳的Cu Ni固溶体而增加了碳纤维与基体的结合强度,复合材料的弯曲强度显著增加,断口上的碳纤维拔出长度大为减小,复合材料的界面属于溶解结合型界面。     

双相不锈钢焊接接头疲劳强度

试验对SAF2205双相不锈钢纵向角接板焊接接头的疲劳强度进行了研究，用有限元计算热点应力集中系数，分别得出了名义应力和热点应力疲劳S-N曲线；用国际焊接学会推荐的方法进行统计处理，并和相同接头形式结构钢的疲劳强度进行了比较。试验表明，双相不锈钢纵向角接板焊接接头名义应力疲劳强度试验结果为FAT136，热点应力疲劳强度试验结果为FAT163，高于相同接头形式结构钢的疲劳级别；双相不锈钢的静载强度级别对其疲劳强度设计级别没有明显的影响。