Interpenetrating polymer networks based on polyol modified castor oil polyurethane and poly(2‐ethoxyethyl methacrylate): Synthesis,chemical, mechanical,thermal properties,and morphology

Interpenetrating polymer networks (IPNs) of glycerol modified castor oil polyurethane (GC‐PU) and poly(2‐ethoxyethyl methacrylate) poly(2‐EOEMA) were synthesized using benzoyl peroxide as initiator and ethylene glycol dimethacrylate (EGDM) as crosslinker. GC‐PU/poly (2‐EOEMA) interpenetrating polymer networks were obtained by transfer molding. The novel GC‐PU/poly (2‐EOEMA) IPNs are found to be tough films. These IPNs are characterized in terms of their resistance to chemical reagents thermal behavior (DSC, TGA) and mechanical behavior, including tensile strength, Young's modulus, shore A hardness, and elongation. The morphological behavior was studied by scanning electron microscopy. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 94: 1029–1034, 2004     

基于RTX的工程飞行模拟器数据采集与存储系统设计

在一些仿真应用中,由于Windows操作系统较差的实时性,从而给许多半物理仿真试验带来了一些不确定的因素.在充分论证的基础上,引入了Ardence公司的基于Windows的硬实时解决方案RTX（Real-Time eXtension）,并结合某型号飞行器仿真课题总结出了Windows环境下RTX实时应用系统的设计方法与开发流程以及RTX下硬件板卡驱动程序的编写,最后将这种设计方法成功应用在某型号飞行器飞行仿真系统中.实验证明该仿真系统是可靠的、稳定的,整个实验过程中飞行器的飞行数据没有丢失,仿真周期确定,结果正确,RTX仿真程序能够满足系统对实时性和确定性的要求.     

城市轨道交通车站通过能力仿真模型研究

以城市轨道交通站前接轨站和站后折返站为例分析了列车在车站的详细作业过程,提出了车站的抽象模型.基于车站模型设计了列车进路搜索算法,开发了车站列车运行过程仿真系统.该系统可以对城市轨道交通车站进行仿真建模,仿真列车在车站的作业过程,并进行车站通过能力的分析计算.     

基于近似弧长参数化的机器人轨迹规划

主要研究了采用近似弧长参数化的插值方法进行关节式工业机器人的轨迹规划.运用近似弧长参数化的插值方法将机器人末端轨迹参数曲线离散为等弧长的插值点序列,通过机器人逆向运动学求解各关节的位移点序列,采用极限的方法进行各关节速度和加速度规划.这种轨迹规划方法可以避免关节空间的插值计算和雅克比矩阵的计算.在 matlab7.8平台上,对近似弧长参数化的插值方法、轨迹规划及可行性验证进行了实例仿真,仿真结果表明该轨迹规划方法是可行的.     

Graft copolymerization of 2‐acrylamido‐2‐methyl‐1‐propanesulfonic acid onto carboxymethylcellulose (sodium salt) by H2O2/Fe+2 redox pair

The effect of the reaction conditions on the grafting parameters during grafting of 2‐acrylamido‐2‐methyl‐1‐propanesulfonic acid onto sodium carboxymethylcellulose using H₂O₂/Fe⁺² redox pair are studied at 30°C. The grafting ratio, add on, and conversion initially increase with the H₂O₂ concentration in the range of (10.0–15.0) × 10^?2 mol dm^?3. Thereafter, these parameters decrease with the H₂O₂ concentration. The grafting ratio, add on, and conversion increase when increasing the ferrous ion concentration from (0.5 to 4.0) × 10^?2 mol dm^?3 and decrease with a further increase in the concentration. It is observed that the grafting ratio and add on increase with the monomer concentration, whereas the conversion decrease. The hydrogen ions seem to be facilitating the grafting reaction up to a certain concentration and after this concentration seem to be retarding the process. The grafting ratio, add on, and conversion decrease with the sodium carboxymethylcellulose concentration. When increasing the time period from 60 to 90 min, the grafting parameters increase but decrease thereafter. Similarly, when increasing the temperature from 25 to 30°C, the grafting parameters increase and decrease thereafter. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 100: 4819–4825, 2006     

New anion exchanger organic–inorganic hybrid materials and membranes from a copolymerof glycidylmethacrylate and γ‐methacryloxypropyl trimethoxy silane

Organic–inorganic hybrid materials and mem branes were prepared through coating on Teflon plate or dip‐coating on microporous alumina substrates with the solution of glycidylmethacrylate (GMA) and γ‐methacryloxypropyl trimethoxy silane (γ‐MPS) copolymer, followed by ring‐opening of the GMA moiety with trimethylamine hydrochloric and sol–gel reaction of the γ‐MPS moiety. Composition of the GMA and γ‐MPS copolymer was varied by changing the feed ratio of GMA to γ‐MPS during the copolymerization. So the thermal stability, hydrophilicity, electrical properties, etc. of the hybrid materials and membranes were varied. Results showed that as the γ‐MPS amount increased in the copolymer, T_d (the temperature on thermogram at 5% weight loss) value of the hybrid materials and water contact angle of the hybrid membrane generally increased, while the anion exchange capacity, water uptake (W_R) and pure water flux decreased. The charge transition point of the hybrid membranes deduced from their streaming potential behavior decreased from pH > 12 to pH = 7–8 as the γ‐MPS amount increased. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 102: 3580–3589, 2006     

模糊逻辑在模拟演练系统智能体设计中的应用

根据模拟演练系统对智能体智能程度的要求为模拟演练系统添加模糊推理机,以增加演练系统的逼真程度及适应性. 本文以模糊逻辑理论为基础,以模拟演练系统为背景,对一个具体的应用实例进行数学建模,阐述了如何运用模糊逻辑来解决问题,并设计了模糊逻辑模块,通过应用实例演示验证了设计的可行性.     

高校教师业务管理系统

本文设计并实现了基于J2EE的高校教师业务管理系统．文章详细讨论了系统实现的业务模型、功能模型等需求分析过程,以及系统架构、通用查询框架、基于角色访问控制策略的“用户一角色．功能模块”的权限管理系统设计与实现等关键技术．     

Synthesis,characterization, and thermal behavior study of methyl methacrylate polymers containing 4‐carbazole substitutes

A new polymerizable monomer, [4‐(9‐ethyl)carbazolyl]methyl methacrylate ( 2 ), was synthesized by reacting of methacrylic acid and 4‐hydroxymethyl‐9‐ethyl carbazole ( 1 ) by esterification procedure in the presence of N,N′‐dicyclohexylcarbodiimide. The resulting monomer was then polymerized free‐radically to form the poly(methyl methacrylate) containing 4‐(9‐ethyl)carbazolyl pend ent groups. Also, copolymerization of monomer 2 with various acrylic monomers such as methyl methacrylate, ethyl methacrylate, methyl acrylate, ethyl acrylate, and n‐butyl acrylate by azobisisobutyronitrile as a free radical polymerization initiator gave the related copolymers in high yields. The structure of all the resulted compounds was characterized and confirmed by FTIR and ¹H NMR spectroscopic techniques. The average molecular weight of the obtained polymers was determined by gel permeation chromatography using tetrahydrofurane as the solvent. The thermal gravimetric analysis and differential scanning calorimeter instruments were used for studying of thermal properties of polymers. It was found that, with the incorporation of bulky 4‐(9‐ethyl)carbazolyl substitutes in side chains of methyl methacrylate polymers, thermal stability and glass transition temperature of polymers are increased. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 102: 4989–4995, 2006     

Synthesis and kinetic studies of UV‐curable urethane‐acrylates

The UV‐curable urethane‐acrylates based on 2‐hydroxyethyl methacrylate (HEMA)‐terminated polyurethane (PU) for lithographic and coating applications are investigated in this study. Series of PU prepolymers were made from 4,4‐diphenyl methane diisocyanate (MDI), poly(propylene oxide) glycol (PPG 400), poly(butylene adipate)glycol (PBA 500), or poly(tetramethylene oxide) glycol (PTMO 1000) and are terminated with HEMA. The 2,2‐azobisisobutyronitrile (AIBN) was used as a UV‐initiator under air atmosphere. The curing kinetics of HEMA‐terminated PU film were studied. The curing analysis, using FTIR and reaction kinetics, indicate the reaction rate equation correlates well with the film thickness [T], initiator concentration [I], unreacted double bond concentration [C?C], and exposed energy [E] of the reaction system. The kinetic rate equation for the UV‐curable reaction can be written as © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 91: 3162–3166, 2004