LOCAL EQUILIBRIUM THEORY FOR THE DYNAMICS OF NONISOTHERMAL MIXED GAS ADSORPTION OF HIGH-CONCENTRATION COMPONENTS

A local equilibrium theory for nonisothermal gas adsorption is developed which accounts for variations in interstitial gas velocity induced by adsorption. Also presented are expressions describing the entropy admissibility criterion. A solution is developed for a Riemann's problem involving adiabatic gas-phase adsorption where there is no inert diluent and where Langmuir isotherms apply.     

工业酚水稀释的RBF神经网络预测控制

针对酚水稀释过程中酚水流量不便测量的工程情况,提出了一种基于RBF（径向基）神经网络的预测控制方法.在酚水罐每个液位变化周期内使用计算机定时测量液位高度,并将这些高度值作为目标输出,在每个循环结束时训练RBF网络,利用RBF网络的逼近能力来实时预测酚水流量,从而控制清水的配比,实现酚水质量浓度的稳定.该方法可避免测量误差带来的干扰,提高控制精度.     

二氰基取代的四硫富瓦烯硫杂冠醚衍生物的合成及性质研究

在甲苯溶液中,在亚磷酸三乙酯存在下,采取高度稀释的方法,使4,5-二氰基-1,3-二硫杂环戊二烯-2-酮分别和多缩硫杂冠醚进行交叉偶联反应,成功地得到了不对称的2,3-二氰基四硫富瓦烯衍生物。用1HNMR、MSI、R和EA表征了其结构,并用循环伏安法研究了它们的电化学性质,用1HNMR初步评价了衍生物对钠离子的配合性能。     

A reverse osmosis desalting plant operated by gas turbines

Power plants in Kuwait use gas turbines (GT) only for a few hours to produce power at peak load times. Peak loadoccurs in the summer due to the air-conditioning load. As an example, the average number of operating hours for six gas turbines in the Doha East power plant was 16 in the summer of 2001. There is little concern about efficiency of these GT since they work for a very short time during the year. However, a recent increase in desalted seawater demand suggests the use of these GT to operate reverse osmosis (RO) desalting systems all year around. The summer outside design temperature in Kuwait for air-conditioning calculations is 48°C dry bulb temperature (DBT), and 28°C wet bulb temperature (WBT); but the ambient temperature can easily reach 60°C. Gas turbine power output and efficiency are drastically reduced by the increase in temperature of intake air to the gas turbine's compressor, especially during harsh Kuwaiti summer conditions. Thus, it is essential to investigate cooling of air intake to the GT compressor. The performance of a typical GT unit and its ability to produce desalted waterby a RO desalting system at different ambient temperatures are presented. Calculation of needed capacities for the cooling of intake air to the GT compressor was performed for evaporative cooling, single and multiple mechanical vapor compression cycles, and combined indirect evaporation cooling with the refrigeration system. The improvements of power output and efficiency due to the cooling of air intake of the GT and the resulting increase in desalted water are also presented.     

Calculation of single adsorption isotherms from gravimetrically measured binary gas mixture adsorption isotherms on activated carbon at high pressures

A method is developed for the calculation of single-component adsorption isotherms from gravimetrically measured binary gas mixture adsorption isotherms at high pressures, at two temperatures and for different mole fractions of the gas phase. The adsorption of nitrogen/methane on active carbon Norit R1 is taken as an experimental example.     

Deformation transition of intact coal induced by gas injection

Gas migration in coal bed is a multiple-physical process, of which not only includes gas desorption/diffusion through coal matrix and gas Darcy flow through the cleat system, but also results in deform...     

抽真空截止点的位置对压铸件气孔的影响

在真空压铸中 ,抽真空截止点的确定对压铸件的品质影响很大 ,过早和过迟将影响压铸的连续生产和不利于减少铸件的气孔。抽真空截止点应设在冲头快压射前 15～ 2 0mm处 ,真空压铸可以提高铸件的密度 1%以上。     

一种新型气硬冷芯盒树脂砂工艺试验及其在生产中的应用

原砂加入2．5％水溶性酚醛树脂，固化剂为甲酸甲脂，加入量占树脂的30％～40％。先把甲酸甲脂在气体发生器中气化，然后再与40％的压缩空气混合，吹气硬化制芯，最高抗拉强度1．2MPa，抗压强度0．32MPa，发气量12mL／g。生产浇注试验表明：砂芯表面光洁，轮廓清晰，尺寸精确，铸件缺陷少，无毒或低毒，和一般冷硬树脂砂比较，成本降低30％。     

天然气长输管道燃驱机组控制系统优化技术

燃气轮机驱动的压缩机组被广泛地应用在天然气长输管道,其控制系统优化技术的大范围深度应用在管道行业尚数首次,及时消除生产瓶颈的同时,也为涉及燃机的控制专业同行提供了技术借鉴,更重要的是为管道行业燃机运行提供了安全保障。