离子液体催化C_5馏分中二烯烃的聚合反应

合成了多种基于1-丁基-3-甲基咪唑阳离子的离子液体,并作为裂解C5馏分中混合二烯烃聚合反应的介质。考察了离子液体种类、反应温度、反应时间和添加Lew is酸对混合二烯烃聚合反应的影响。实验结果表明,以硝酸根为阴离子的离子液体对混合二烯烃的聚合反应具有一定的阻聚作用;以六氟磷酸根为阴离子的离子液体能明显促进混合二烯烃的聚合反应,提高二聚物的含量;添加Lew is酸(质量分数为1%的ZnCl2)的离子液体对混合二烯烃的聚合反应具有更明显的促进作用,其效果仅次于酸性氯铝酸类离子液体,反应温度以30℃以下为宜,温度过高将促使二聚物进一步聚合,形成三聚物乃至多聚物,降低二聚物的含量。     

分离有机/有机混合物的PVA、CA系列膜及其渗透汽化性能研究(Ⅱ) 成膜条件对渗透汽化性能的影响

用溶剂完全蒸发法制备了PVA复合膜 .经对MTBE/MeOH混合物的分离实验得到了PVA复合膜的最佳成膜条件 ,即 :铸膜液中PVA、马来酸浓度分别为 7%、3% ,热处理温度130～ 15 0℃ .在 1%～ 2 %丙酮水溶液中浸泡处理 4～ 8h ,CTA中空纤维RO膜被改性成渗透汽化膜 .CTA中空纤维膜的分离性能优于其它醋酸纤维素系列膜 ,PVA/CA复合膜的性能优于PVA/PAN复合膜和CA/PAN复合膜     

Pseudoinverse in clustering problems

The clustering of vector observations of hyperplanes is studied. Different cases of correspondence distances are proposed and investigated, including the algebraic Jack Knife one. The efficiency, constructivity, and explicit form of formulas are provided by using the pseudoinverse technique including the pseudoinverse-perturbation theory. Results important for the application of pseudoinverse and related operators are presented. __________ Translated from Kibernetika i Sistemnyi Analiz, No. 4, pp. 73–92, July–August 2007.     

Optimal implementations of UPGMA and other common clustering algorithms

In this work we consider hierarchical clustering algorithms, such as UPGMA, which follow the closest-pair joining scheme. We survey optimal O(n²)-time implementations of such algorithms which use a ‘locally closest’ joining scheme, and specify conditions under which this relaxed joining scheme is equivalent to the original one (i.e. ‘globally closest’).     

Concealed weapon detection and visualization in a synthesized image

Images acquired by heterogeneous image sensors may provide complementary information about the scene, for instance, the visual image can provide personal identification information like the facial pattern while the infrared (IR) or millimeter wave image can detect the suspicious regions of concealed weapons. Usually, a technique, namely multiresolution pixel-level image fusion is applied to integrate the information from multi-sensor images. However, when the images are significantly different, the performance of the multiresolution fusion algorithms is not always satisfactory. In this study, a new strategy consisting of two steps is proposed. The first step is to use an unsupervised fuzzy k-means clustering to detect the concealed weapon from the IR image. The detected region is embedded in the visual image in the second step and this process is implemented with a multiresolution mosaic technique. Therefore, the synthesized image retains the quality comparable to the visual image while the region of the concealed weapon is highlighted and enhanced. The experimental results indicate the efficiency of the proposed approach.This material is based on part of the work carried out at the SPCR laboratory of Lehigh University and the work is partially supported by the U. S. Army Research Office under grant number DAAD19-00-1-0431. The content of the information does not necessarily reflect the position or the policy of the federal government, and no official endorsement should be inferred.     

氦氢混合工质单级GM型脉管制冷特性实验研究

针对80K温区，在一台单级GM型脉管制冷机中进行了氦氢二元混合工质的实验研究。实验结果表明，采用一定组分的氦氢混合工质可以提高脉管制冷机的制冷性能。     

Robust pole clustering in a good ride quality region of aircraft for matrices with structured uncertainties

This paper presents a general analysis of robust pole clustering in a good ride quality region (GRQR) of aircraft for matrices with structured uncertainties. This region is an intersection of a ring and a horizontal strip, located in the left half-plane, which is a specific non-Ω-transformable region providing good ride quality of aircraft. The paper applies the Rayleigh principle along the norm theory to analyze robust pole clustering within this region since the generalized Lyapunov theory is not valid for non-Ω-transformable regions. Concerned uncertainties are structured/parametric uncertainties, including interval matrices. The results are useful for robust control analysis and design, especially, of robust good ride quality of aircraft, shuttles, vehicles and space station, as well as some industrial systems. An example of the F-16 dynamics for which GRQR is suitable is included to illustrate the results.     

A note on a local twist estimator

For the construction of composite surfaces interpolating a given curve net a new local twist estimator was proposed recently (Farin and Hagen, 1992). Some properties of this estimator—including an explicit representation for Gaussian curvature K at the knots of the curve net—are presented in this note.     

抗几何失真的视频Hashing算法研究

文中提出了一种基于视频灰度直方图形状的Hashing算法,能有效抵抗各种常见的几何失真和视频处理操作.算法的鲁棒性原理如下:1)由于直方图的形状与像素位置无关,故基于直方图的视频Hashing算法能有效抵抗各种常见的几何攻击;2)由于在计算Hashing前对视频帧进行了平滑预处理,故算法对加噪攻击、模糊滤波、有损压缩等处理操作有很好的鲁棒性;3)由于计算Hashing前在时间轴上进行了低通滤波预处理,故算法能抵抗帧率变化、帧丢失等时域同步攻击.实验结果表明,所提出的Hashing算法有良好的唯一性和鲁棒性能.     

一种基于数据竞争的高分辨率图像的聚类分割算法

近些年,机器人技术得到了迅猛的发展,应用越来越广泛.随着机器人技术的推广和普及,对机器人使用的要求也越来越高,其中对智能机器人的要求尤显迫切.机器视觉是智能机器人研究领域的一个重要研究方向.在机器人视觉系统中,核心问题是目标提取,对目标实时、准确、快速提取的关键技术是图像分割.由于机器人感知的环境的复杂性及目标的多样性,往往导致机器人感知获得的图像数据量较大且图像本身存在不可预知的复杂性,这就对准确的目标分割和提取处理提出了挑战性问题.本文针对高分辨率图像数据集的分割处理,提出一种新的聚类算法,即根据数据点能量和的大小识别类代表点和类成员点,通过数据点间的竞争识别出最有能力成为簇成员的数据点,并将其与mean shift聚类算法有效地结合应用于彩色图像分割问题中,能够快速高效地实现高分辨率图像的目标分割,并得到较好的图像分割效果.实验结果表明,本文算法在分割效果和分割效率上明显优于传统聚类算法.