环氧丙烷生产工艺进展

综述了近年来环氧丙烷合成工艺的新进展,包括对现有环氧丙烷生产工艺的革新、直接氧化法、光催化环氧化等方法,并对各种方法的特点和发展前景进行了讨论.     

Preparation of nano-sized silicon carbide powder using thermal plasma

Nano-sized silicon carbide (SiC) powder was prepared by thermal plasma process using silicon tetrachloride (SiCl₄) and methane (CH₄). The synthesized powder was characterized by X-ray diffraction pattern, scanning electron microscopy, transmission electron microscopy, FT-IR spectroscopy and particle size analyzer. The powder was dominated by β-SiC including some of α-SiC and free carbon species. The quality of the powder was varied with process conditions such as the molar ratio of H/Si and C/Si, and collecting positions. It was known that the conversion to SiC was mainly affected by the addition of hydrogen gas because it promoted the decomposition and reduction of SiCL. CH₄ was easily decomposed to carbon species for the formation of SiC as well as removal of impure oxygen, but excessive carbon suppressed the formation of crystalline SiC and resulted in the solid carbon contamination. The optimum ratio of H/Si was approx. 26 and that of C/Si was 1.1. For collecting positions, the powder collected at the vessel and filter was preferable to that at the reaction tube. The average size of the powder synthesized was estimated to be below 100 nm and uniform in distribution.     

The Chemistry of Water Treatment Processes Involving Ozone,Hydrogen Peroxide and Ultraviolet Radiation

Advanced oxidation processes are defined as those which involve the generation of hydroxyl radicals in sufficient quantity to affect water purification. The theoretical and (practical yield of OH from O₃ at high pH, 0₃/H₂0₂, O₃/UV and H₂O₂/UV systems is reviewed. New data is presented which illustrates the importance of direct photolysis in the O₃/UV process, the effect of the H₂0₂:0₃ ratio in the O₃/H₂O₂ process, and the impact of the low extinction coefficient of H₂O₂ in the H₂0₂/UV process.     

The voidage function and effective drag force for fluidized beds

Here, an experimental investigation on the effective drag force in a conventional fluidized bed is presented. Two beds of different particle size distribution belonging to group B and group B/D powders were fluidized in air in a diameter column. The drag force on a particle has been calculated based on the measurement of particle velocity and concentration during pulse gas tests, using twin-plane electrical capacitance tomography. The validity of the voidage function “correction function”, (1−ε_s)ⁿ, for the reliable estimation of the effective drag force has been investigated. The parameter n shows substantial dependence on the relative particle Reynolds number , and the spatial variation of the effective static and hydrodynamic forces. It is also illustrated that, a simple correlation for the effective drag coefficient as function of the particle Reynolds number (Re_p), expressed implicitly in terms of the interstitial gas velocity, can serve in estimating the effective drag force in a real fluidization process. Analysis shows that, the calculated drag force is comparable to the particle weight, which enables a better understanding of the particle dynamics, and the degree of spatial segregation in a multi-sized particle bed mixture. The analogy presented in this paper could be extended to obtain a generalized correlation for the effective drag coefficient in a fluidized bed in terms of Re_p and the particle physical properties.     

基于模糊层次分析法的应用性技术成果评价

针对现有应用性技术成果的评价指标体系,建立了相应的模糊层次分析法数学模型,此模型可克服传统层次分析法判断矩阵构造主观性强和一致性不易检验等缺点,为应用性技术成果的等级评价提供了一种简便合理的科学评价方法.     

青县电子机箱产业集群核心竞争力评价

根据核心竞争力理论,运用层次分析法,构建了对产业集群的核心竞争力评价体系,并用此方法对青县的的电子机箱产业进行了实证分析.研究结果表明青县电子机箱行业的核心竞争力不强,其中资源整合与控制能力,技术创新能力、组织管理能力、人力资源竞争力和企业文化聚合力较弱、在此基础上提出了相应的政策建议.     

数据挖掘技术在学生评估中的应用

近几年随着科技和现代教育的发展,数据库和网络技术得到飞速的发展和广泛的应用,智能教学系统也就大量地出现,这样就有大量的数据伴随着出现,而怎样处理这些数据使人们从中获得有用的信息变成一个热门的话题。数据挖掘技术就是将大量数据以一定的方式进行处理,得到对人们有用的信息,来帮助人们学习和预测。将数据挖掘技术引入到教学过程中学生的个人学习素质评估当中,创新性地通过决策树算法和聚类算法相结合的方法对学生数据分析,挖掘潜在的信息资源,找出影响个人综合素质的关键因素及各因素之间的关系,总结优秀学生的个人综合素质的培养方法,弥补不足,提高学生的个人综合素质。     

耐候钢连铸工艺的改进

分析耐候钢连铸出现的问题,认为凝固时应力过大和磷铜元素偏析造成晶界脆化是出现铸坯纵裂的主要原因;结晶器中喂稀土丝恶化保护渣性能,影响结晶器与坯壳间的润滑与传热,并使热流不均匀是连铸漏钢的主因。采用钙处理代喂稀土丝工艺,以及减缓连铸一、二次冷却强度,改进保护渣后,连铸缺陷获得极大改善。     

基于驱动的进程创建监控的实现

介绍了驱动开发技术背景及应用,讲述SSDTHOOK方法,实现监控NtCreateProcessEx系统服务。RING3应用程序和驱动程序的交互,RING3应用程序和驱动程序的同步实现基于驱动的进程创建监控。