Influence of the surface conditions on permeation in the deuterium–MANET system

The condition of the surfaces is of crucial importance for the deuterium permeation through materials. In this work a study of the surface constants for the adsorption (σk₁) and release (σk₂) of deuterium under different surface conditions on the martensitic steel DIN 1.4914 (MANET) has been carried out. The growth of an oxide surface layer (Cr₂O₃) of about 25–30 nm in a MANET sample, heat treated in an oxidizing environment, compared to the bare MANET that have a ‘natural' oxide of about 5 nm has provoked a reduction of both the permeation rate and the recombination coefficient (about 3 orders of magnitude). In addition, the permeation governing process has changed from diffusion-limited to surface-limited. The measurements of the permeation rate of deuterium were performed by a gas-phase permeation technique over the temperature range 574–746 K and for deuterium driving pressures in the range from 3 to 10⁵ Pa.     

NMR characterization of penetrants in high permeability polymers

Spectra of xenon-129 sorbed into two high permeability polymers are reported. The polymers are the copolymer of tetrafluoroethylene and 2,2-bis(trifluoromethyl)-4,5-difluoro-1,3-dioxole as well as poly(1-trimethylsilyl-1-propyne). At room temperature, the xenon-129 shifts are smaller than in conventional glassy polymers. The smaller xenon-129 shift indicates the presence of larger sorption sites in high permeability polymers relative to conventional polymers. The temperature dependence of solubility in these polymers is drastically different from the behavior in conventional polymers. There is a rapid exponential increase in solubility in high permeability polymers as temperature decreases corresponding to a large negative enthalpy change on sorption and it is this increase in solubility which leads to a large increase in shift with decreasing temperature. Pulse field gradient (PFG) determinations of the self-diffusion constant are made for xenon, propane, pentane and a decafluoropentane in the copolymer. Rapid diffusion is observed as well as a dependence of the apparent diffusion constant on the time scale of the PFG experiment. The translational mobility of smaller simpler moieties depends less on the time scale or equivalently, the length scale of observation in the PFG NMR experiment. For larger, more complex species, the interconnectedness of high free volume domains plays a role in reducing the apparent diffusion constant as the time of measurement increases.     

Degassing of molten polymers

Degassing is a key-step in polymer processing. Low-molecular-weight components are removed from a polymeric system. The transport of these components takes place by diffusion to the polymer-vapour interface. This interface can be formed by free surfaces of single-phase polymer melts or by bubbles. In this study, the transport with and without bubble nucleation is investigated independently from each other in a special designed apparatus similar to a degassing extruder.The mass transport in thin films and in rotating pools with surface renewal is measured. High surface renewal rates and thick films enhance the mass transfer for single phase flow and bubbly flow. Dimensionless mass transfer coefficients are given as a function of the surface renewal rate, the area of the free surface and the total mass of the polymer. The conditions for bubble nucleation and foam formation are investigated. The bubble nucleation is observed in the rotating pool in the area of high shear velocity.     

新技术在制盐行业设备管理中的应用

通过新设备、新技术的引进和应用。重庆索特股份有限公司加强设备管理，不管是在规范性上，还是在可操作性上，都取得了明显的效果。去年全年设备维修费用大幅度降低，经济效益明显。     

在西文DOS下汉字的一种快速显示技术

作为存储测试系统配套的信息处理软件,有一个直观的汉字界面显的非常必要,本文介绍一种在西文DOS下快速显示汉字的处理技术:由信息处理软件原程序中的汉字信息通过访问硬盘汉字库生成,由所需显示汉字点阵构成具有专用格式的专用汉字库,通过软件编程可实现对汉字库的快速访问与快速显示。从而,即节省磁盘空间,又能使信息处理软件与汉字显示很好地溶为一体。     

Enrichment of slightly concentrated tritiated water by electrolysis using a palladium cathode coated on ionic solid polymer membrane—Design and results

In nuclear installations, tritiated water is generally produced in the process of detritiation of air circulating in the glove boxes. The goal of this work concerns enrichment of this tritiated water at low concentration by electrolysis. The choice of this electrolyzer was dictated by the passivity of selected materials to the radiolysis in low-level tritiated water and the selectivity of the method avoiding further elimination of tritiated water and moisture before release in environment. According to the results, it is feasible to treat non-negligible volume of low-level tritiated water using a cathodic palladium membrane coated on an ionic solid polymer membrane. Presence of a palladium black deposit on the palladium membrane improves effectiveness. Enrichment in tritiated water depends on the isotopic separation factor, thereby the current and the permeability values.     

Does positive affect influence the effective usage of a Decision Support System?

This study examines the impact of positive mood on the effective usage of a Decision Support System (DSS). Using current cognitive theories, a theoretical argument about DSS usage is developed. This argument is then investigated via a lab experiment. The results of the lab experiment show that decision makers in positive mood used a greater number of informational cues provided by the DSS and made more accurate judgments.     

Information cut for clustering using a gradient descent approach

We introduce a new graph cut for clustering which we call the Information Cut. It is derived using Parzen windowing to estimate an information theoretic distance measure between probability density functions. We propose to optimize the Information Cut using a gradient descent-based approach. Our algorithm has several advantages compared to many other graph-based methods in terms of determining an appropriate affinity measure, computational complexity, memory requirements and coping with different data scales. We show that our method may produce clustering and image segmentation results comparable or better than the state-of-the art graph-based methods.     

Ontology-Centered Knowledge Management Using Information Retrieval Techniques

The paper argues that an effective solution to information and knowledge management (KM) needs of practitioners in the construction industry can be found in the provision of an adapted knowledge environment that makes use of user profiling and document summarization techniques based on information retrieval sciences. The conceptualization of the domain through ontology takes a pivotal role in the proposed knowledge environment and provides a semantic referential to ensure relevance, accuracy, and completeness of information. A set of KM services articulated around the selected ontology have been developed, using the Web services model, tested, and validated in real organizational settings. This provided the basis for formulating recommendations and key success factors for any KM project development.     

信息高速公路与电子信息产业

信息高速公路是信息社会的支柱，电子信息产业是信息社会中国家经济的支柱产业。本文在对信息高速公路具体内容进行了介绍的基础上，对信息高速公路技术结构进行了分析，对信息高速公路与电子信息产业及国民经济发展的重要关系进行了阐述。