高碳钢盘条SWRH82BCr试制

为了满足出口用户的要求,进行了高碳钢盘条SWRH82BCr的生产试制。介绍了该盘条的试制过程,对采用200mm×200mm连铸坯直接轧制的盘条实物质量进行了检验,给出了试制结果。针对首次试制的盘条中心网状碳化物级别、中心马氏体级别偏高的问题,进行了斯太尔摩风机风量的调整,稳定了盘条的出厂性能。试制结果表明:该钢种试制工艺路线合理,优化后的高线斯太尔摩控冷工艺得到固化,盘条的中心网状碳化物、中心马氏体级别均不大于0.77级,索氏体体积分数不小于90%,断面收缩率不小于42.5%。     

机载SAR有源干扰分析与比较

机载合成孔径雷达的干扰是当前电子对抗领域关注的焦点问题.在首先介绍了几种常用的SAR有源干扰方法的基础上,重点阐述了相干干扰的工作原理.然后,从压制系数出发,推算出了达到SAR压制系数条件下,不同干扰方式的功率表达式.结合仿真结果,对不同干扰方法的干扰性能进行了评估和比较.最后,针对各种干扰方法的性能优缺点,提出了综合运用多种方法对机载SAR进行有源干扰的作战策略.对机载SAR有源压制干扰的作战应用具备一定的指导意义.     

大桥斜拉索制造关键技术研究

大桥用镀锌钢丝必须同时满足扭转≥8次,松弛率≤2.5%,抗拉强度≥1 670 MPa。介绍大桥斜拉索用镀锌钢丝和斜拉索制作工艺。选用宝钢B82MnQL盘条生产7.0 mm镀锌钢丝,锌层面质量≥300 g/m2。镀锌钢丝生产过程中应提高钢丝表面质量、直线度及镦头性能。降低斜拉索索体扭转的方法:改进绞制与挤塑工序牵引方式;改进绞制弯道以保持斜拉索绞制节距稳定;改进索体绕包张力。对新型斜拉索密封体系进行研发。斜拉索疲劳性能改进措施:提高镀锌钢丝表面质量均匀性、直线性和直径精度。生产的镀锌钢丝斜拉索经检验和使用,能够满足用户的特殊要求。     

X82B盘条放线脆断原因分析

针对X82B盘条在使用过程中出现的脆断现象,对断裂样品形貌、金相组织、力学性能等进行分析检测,得出断裂原因:(1)X82B盘条放线脆断大都为局部缺陷所致。(2)擦伤、刮伤等表面缺陷和心部马氏体、表面网状渗碳体等不良组织会导致盘条发生脆断。(3)连铸过程的拉速不稳或润滑不良都会造成盘条的局部裂纹并导致脆断。(4)盘条轧制后期的吐丝、辊道运输、集卷、打捆等环节也易造成盘条的局部裂纹并导致脆断。在盘条生产和后续加工过程中,严格过程控制可有效降低盘条发生脆断的几率。     

A jet-stirred reactor and kinetic modeling study of ethyl propanoate oxidation

A jet-stirred reactor study of ethyl propanoate, a model biodiesel molecule, has been carried out at 10 atm pressure, using 0.1% fuel at equivalence ratios of 0.3, 0.6, 1.0 and 2.0 and at temperatures in the range 750-1100 K with a constant residence time of 0.7 seconds. Concentration profiles of ethyl propanoate were measured together with those of major intermediates, ethylene, propanoic acid, methane and formaldehyde, and major products, water, carbon dioxide and carbon monoxide. This data was used to further validate a previously published detailed chemical kinetic mechanism, containing 139 species and 790 reversible reactions. It was found that this mechanism required a significant increase in the rate constant of the six-centered unimolecular elimination reaction which produces ethylene and propanoic acid in order to correctly reproduce the measured concentrations of propanoic acid. The revised mechanism was then used to re-simulate shock tube ignition delay data with good agreement observed. Rate of production and sensitivity analyses were carried out under the experimental conditions, highlighting the importance that ethylene chemistry has on the overall reactivity of the system.     

塔中82井区原油的特征及成因

通过对塔中I号坡折带塔中82井区原油进行地球化学分析（包括分子筛合除去正构烷烃分析）来探讨其特征和成因,结果表明：原油族组成中饱和烃占绝对优势,而饱和烃中以低碳数正构烷烃为主,C _21-/C ₂₂₊ 值达1.4~5.4,生物标志物的含量极低;甾烷C₂₇-C₂₈-C₂₉呈“V”字型分布,重排甾烷的含量较高;萜烷中三环萜的含量较高而五环萜含量极低,且三环萜以C₂₀或C₂₃为主峰;芳烃中三芳甾烷的含量很低,三芴系列化合物中硫芴含量较高;原油碳同位素较轻,其饱和烃的碳同位素值δ¹³C<-32.8‰（这些特征有别于塔东2井的寒武系原油）;原油的成熟度R_O值为0.8%左右。推断塔中82井区的原油可能并非是有机质在高成熟阶段生成的凝析油,而是中等成熟的中-上奥陶统源岩生成的正常原油在成藏后由于寒武系天然气的注入,发生了蒸发分馏作用并运移至目前的储层中再次成藏。     

Experimental and chemical kinetic modeling study of small methyl esters oxidation: Methyl (E)-2-butenoate and methyl butanoate

This study examines the effect of unsaturation on the combustion of fatty acid methyl esters (FAME). New experimental results were obtained for the oxidation of methyl (E)-2-butenoate (MC, unsaturated C₄ FAME) and methyl butanoate (MB, saturated C₄ FAME) in a jet-stirred reactor (JSR) at atmospheric pressure under dilute conditions over the temperature range 850-1400 K, and two equivalence ratios (Φ=0.375,0.75) with a residence time of 0.07 s. The results consist of concentration profiles of the reactants, stable intermediates, and final products, measured by probe sampling followed by on-line and off-line gas chromatography analyses. The oxidation of MC and MB in the JSR and under counterflow diffusion flame conditions was modeled using a new detailed chemical kinetic reaction mechanism (301 species and 1516 reactions) derived from previous schemes proposed in the literature. The laminar counterflow flame and JSR (for ?=1.13) experimental results used were from a previous study on the comparison of the combustion of both compounds. Sensitivity analyses and reaction path analyses, based on rates of reaction, were used to interpret the results. The data and the model show that MC has reaction pathways analogous to that of MB under the present conditions. The model of MC oxidation provides a better understanding of the effect of the ester function on combustion, and the effect of unsaturation on the combustion of fatty acid methyl ester compounds typically found in biodiesel.     

SWRH82B钢变形抗力影响因素研究

以线材SWRH82B为研究对象,采用GLEEBLI-2000热模拟试验机对金属塑性变形抗力进行实验研究。通过实测数据,分析了不同变形温度、变形速率和变形程度与变形抗力的关系,确定了金属塑性变形抗力的数学模型。结果表明,变形抗力随温度的升高而降低,当变形程度超过发生动态再结晶的临界应变量ε时,变形抗力下降趋于平稳。变形速率越快,变形抗力越低。     

BNi82CrSiB钎料真空钎焊FeCrAl合金接头界面组织

采用BNi82CrSiB带状钎料在1070℃/10min工艺条件下对FeCrAl合金箔带制成的多孔圆形器件进行了真空钎焊实验,并对钎焊接头界面组织和相组成进行了分析。实验结果表明:多孔圆形器件焊后表面无宏观缺陷,钎焊接头致密完整,试样中99%(总共约有8000个)的钎焊接头实现连接。钎缝组织由-γNi基固溶体、金属间化合物和共晶组织构成。钎缝中物相有-γNi,FeNi3,AlNi3,CrB,Ni17Si3。钎焊接头中含有较多的硼化物相。     

企业信息门户关键技术研究

详细介绍了作为企业信息门户关键技术的两个规范,它们是JSR 168和远程Portlets Web服务（Web Services for Remote Portlets,WSRP）,并对两者的关系作了阐释。这两个规范使基于不同平台的门户能够无缝地互操作成为了可能,同时使大范围内基于用户的信息集成更加快速安全。