Characterization of microporous-mesoporous MCM-41 silicates prepared in the presence of octyltrimethylammonium bromide

MCM-41 silicates prepared in the presence of octyltrimethylammonium bromide either by a conventional method or by post-synthesis hydrothermal treatment were characterized by nitrogen adsorption in a wide range of relative pressure from 10^-6 to 1. Hydrothermally restructured samples were found to have lower BET surface areas, lower external surface areas and thicker silica walls than the non-treated sample. More importantly, in addition to their characteristic mesopores (ca. 3 nm), they were shown to have considerable amounts of micropores. The relative amount of micropores and mesopores was shown to be dependent on the treatment conditions. Thus, it is demonstrated that the postsynthesis hydrothermal restructuring is a convenient synthesis route to MCM-41 silicates with bimodal pore size distribution involving controllable amounts of microporosity. This revised version was published online in July 2006 with corrections to the Cover Date.     

基于XC2287M的工程机械ECU设计

ECU是工程机械电控系统的核心部件,目前国内中高端ECU市场基本被国外厂商所垄断。设计了一款基于XC2287M微控制器的工程机械智能ECU,采用CODESYS软PLC作为编程平台,支持IEC 61131-3定义的5种标准PLC语言进行编程。所设计的ECU拥有丰富的I/O资源和完善的安全保护机制,能够广泛应用于各种工程机械控制系统,打破国外厂商对ECU市场的垄断。     

RECURSIVE GENERALIZED M ESTIMATES FOR AUTOREGRESSIVE MOVING-AVERAGE MODELS

Abstract. Outliers in time series seriously affect conventional parameter estimates. In this paper a robust recursive estimation procedure for the parameters of auto-regressve moving-average models with additive outliers is proposed. Using 'cleaned' residuals from an initial robust fit of an autoregression of high order as input, bounded influence regression is applied recursively. The proposal follows certain ideas of Hannan and Rissanen, who suggested a three-stage procedure for order and parameter estimation in a conventional setting.
A Monte Carlo study is performed to investigate the robustness properties of the proposed class of estimates and to compare them with various other suggestions, including least squares, M estimates, residual autocovariance and truncated residual autocovariance estimates. The results show that the recursive generalized M estimates compare favourably with them. Finally, possible modifications to master even vigourous situations are suggested.     

On a Mixture GARCH Time‐Series Model

Abstract. Recently, there has been a lot of interest in modelling real data with a heavy‐tailed distribution. A popular candidate is the so‐called generalized autoregressive conditional heteroscedastic (GARCH) model. Unfortunately, the tails of GARCH models are not thick enough in some applications. In this paper, we propose a mixture generalized autoregressive conditional heteroscedastic (MGARCH) model. The stationarity conditions and the tail behaviour of the MGARCH model are studied. It is shown that MGARCH models have tails thicker than those of the associated GARCH models. Therefore, the MGARCH models are more capable of capturing the heavy‐tailed features in real data. Some real examples illustrate the results.     

城市慢行交通网络数据建模研究

城市慢行交通系统是现代城市交通系统的重要组成部分,随着多模式城市交通发展,建立便捷和高效的城市慢行交通网络系统成为现代城市解决交通问题和提升交通运行效率的关键措施。基于此,文中应用统一建模语言（UML）和地理标识语言（GML）建立城市慢行交通网络数据模型,提出一种统一的和一致性的交通地理要素定义和性质描述方法,并阐述基于GML的城市慢行交通网络的地理要素和关系表达。研究成果促进了城市交通地理数据的组织、表达、集成、共享和操作,对建立高效的城市慢行交通网络系统具有重要的理论价值。     

Synthesis and Characterization of Al-MCM-41 and Al-MCM-48 Mesoporous Materials

A novel route in the synthesis of Al-MCM-41 and Al-MCM-48, using tetraethoxysilane (TEOS) and sodium aluminate (NaAlO₂) as Si and Al source has been obtained. The effect of surfactant nature and the synthesis conditions such as surfactant/Si ratio and hydrothermal treatment time on the formed mesostructure regularity has been studied. Different methods of template removal have also been evaluated. The samples were characterized by X-ray diffraction, nitrogen physisorption, FT-IR, and solid-state MAS NMR spectroscopy.     

PLC在碱回收蒸发工段的应用

根据碱回收蒸发工段的工艺特点和控制要求,设计了S7-300PLC控制系统.详细说明了控制系统的硬件组成、软件程序设计,工程实际运行表明,该系统控制效果良好,具有较好的经济价值.     

矩阵的Hadamard积最小特征值的下界估计

对A和B是非奇异M矩阵,利用著名的Gerschgorin圆盘定理,给出了B和A-1的Hadamard积B。A-1的最小特征值τ(BA-1)新的下界估计式,此下界估计式改进了现有的几个结果,并且这个下界估计式只涉及矩阵A和B的元素,易于计算.例证表明,所得下界估计式要比现有的下界估计式更加精确.     

SY300电解槽技术的开发与生产实践

本文通过对256台SY300(300kA)电解槽的设计和在河南豫港龙采铝业有限公司200kt/a电解系列的生产实践进行剖析，应用多模式智能控制技术和“四低一高”操作工艺。电解槽运行平糖、高效。三场设计合理．实际测试和设计值吻合。实践证明。SY300电解槽从设计到生产都已达到国际先进水平。     

MODELLING OF P/M FORMING PROCESSES BY FEM

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