Measurement of O2-N2 binary sorption on 5A zeolite by isotope tracer and perturbation chromatography

Isotope tracer chromatography allows to extract simply and quickly multi component adsorption data and is demonstrated for single component and binary adsorption equilibria for O₂ and N₂ on 5A zeolite as an example. In this modification of conventional tracer chromatography, a small pulse of an isotope tracer is injected in an adsorbable carrier gas (pure or multicomponent mixture) flowing through a column filled with adsorbent and is designed to operate at almost uniform pressure. Isotherm parameters are readily extracted by fitting measurements of residence times at various pressures and carrier composition. The isotherms were in excellent agreement with volumetric measurements. Isotope tracer chromatography is shown to be superior to perturbation chromatography since the influence of the injection volume on the carrier gas composition is substantially smaller for tracer experiments. Unfortunately, this new improved gas chromatographic technique requires rather expensive isotopes. The strength of this new approach lies in the advantage of working with small adsorbent samples (1 g) making a rapid screening of newly developed materials possible.Nomenclature K _exp,tr,i experimental tracer adsorption constant (mol/kg pure adsorbent/Pa) - K _i Henry adsorption equilibrium constant (mol/kg pure adsorbent/Pa) - K _i,part partition coefficient - K _pert composite Henry constant (mol/kg pure adsorbent/Pa) - L column length (m) - L _i Langmuir adsorption constant (1/Pa) - n _i amount adsorbed on the solid (mol/kg adsorbent) - N _i adsorbent loading (Pa) - p total pressure (Pa) - p _i partial pressure of component i (Pa) - p _in column inlet pressure (Pa) - p _out column outlet pressure (Pa) - q _i amount of component i in the micropores (Pa) - R gas constant (J/mol/K) - t time (s) - T temperature (K) - v _f superficial velocity in adsorbent column (m/s) - v _out velocity at the outlet of the column (m/s) - V _inlet volumetric flow rate at inlet conditions (ml/s) - x molar fraction of tracer - y molar fraction of component i in the carrier gas - z axial coordinate (m) Greek letters _ext bed voidage, external porosity - _macr macropore porosity [_macr= _p (1–_ext)] - _micr micropore porosity - _tot total porosity - _p pellet porosity - volume fraction of binder material - _d dead time (s) - _tracer tracer residence time (s) - _pert perturbation residence time (s) - _crys crystal density (kg/m³)     

边坡锚固工程分析中的水平条分法

对目前中国规范推荐用于边坡加固计算的垂直条分传递系数法进行研究,发现将该方法用于边坡锚固受力分析时,不仅存在垂直条块与加固结构体（锚杆和锚索）相互交叉,而且计算得出的锚固力与加固体的实际锚固力存在偏差等缺陷。在相关资料提出的、用于加筋土稳定性分析的水平条分法基础上,结合边坡锚固工程的特点,将该水平条分法做进一步拓展,使其能适用于锚杆和锚索等边坡锚固工程的稳定性计算,并通过工程实例对拓展后的水平条分法进行了验证。     

模块化免疫神经网络平衡态检测模型*

基于神经网络原理、免疫系统和遗传算法的相关机理,构造了一个网络安全平衡器。该平衡器建立了抗原与抗体平衡态检测的数学模型、抗原与抗体的促进和抑制函数,提出了安全平衡态的概念,给出了抗原与抗体浓度的计算公式和模块化多层分类处理模型,利用促进、抑制函数和遗传算法适应度函数使已受攻击的网络再次达到一种新的安全平衡状态,这为网络安全提供了一个新的途径。理论证明网络安全方案是有效的。     

一类高阶非线性差分方程的吸引性

在文献[1-2]的基础上,研究了非线性差分方程xn+1=a-bxpn-k/A-x2n的全局稳定性和正解的周期性,其中a,A为非负实数,b为正实数,k,p∈{1,2,…},p≥2.证明了该方程的一个正平衡点是一个全局吸引子,并给出了相应的吸引域.     

捕食者有常数投入的n＋1次系统的极限环

主要对一类n＋1次系统dxdt=x（a0＋a1x-a2x2＋a3yn）＋hdydt=y（b1x2-b2）（a0,a1,a2,b1,b2,h＆gt;0,a3为不定号,n≥1,n∈N）进行研究.利用微分方程定性理论,给出该系统平衡点的渐近性态,得到局部性质.找出闭轨线不存在性的充分条件,并给出极限环的存在性和唯一性的条件.     

具有隔离接种且传染率为非线性的传染病模型的稳定性

研究一类具有预防接种、隔离且传染率依赖于易感人口的SIQRS传染病模型,给出确定疾病消亡和持续生存的基本再生数σ．在一定条件下证明无病平衡点的全局稳定性,得到唯一地方病平衡点的存在性和局部渐近稳定条件．     

一类有理差分方程的全局渐近稳定性

研究差分方程xn＋1=fgh＋f＋g＋h＋a/fg＋gh＋hf＋1＋a（n=0,1,…）的全局渐近稳定性,其中a∈（1,＋∞）,f=f（x-r1,…,x-rk）∈C（（0,＋∞）^k,（0,＋∞））,g=g（xn-m1,…,xn-ml）∈C（（0,＋∞）^l,（0,＋∞））,h=h（xn-s1,…,xn-sσ）∈C（（0,＋∞）^σ,（0,＋∞））,k,lσ∈{1,2,…},0≤r1〈…〈rk,0≤m1〈…〈ml,0≤s1〈…〈sσ,并且初值为正实数．给出了该方程关于唯一正平衡点=↑x=1的全局稳定的充分条件,推广了参考文献[5]-[7]中的一些结果．     

Evolutionarily Cooperative Stable of Science ＆ Technology Alliance Under Self-organized Organization

The cooperative evolutionary stability under self-organized organization is discussed in this paper. The differences between the objects studied by cooperative game theory and the ones studied by cooperative game in science & technology alliance are analyzed. The mutant probability of agent’s utility under endogenous technical factor condition is analyzed. By clarifying the connotation of Pareto-dominate institution in cooperative game, the efficient and feasible managerial definition of Pareto-dominate Ins...     

KKM映射和KKM型定理及其相关结果

简要介绍古典的KKM映射的演变过程和KKM理论的发展历史,并给出利用KKM型定理得到的最近的一些重要研究成果,以进一步了解和掌握并研究KKM理论．     

污泥吸附动力学与平衡模型的实验研究

采用好氧和厌氧污泥进行污泥的生物吸附实验,研究好氧与厌氧污泥吸附动力学和吸附平衡模型。研究表明:好氧和厌氧污泥的吸附过程中,颗粒内扩散是污泥吸附的主要限速阶段,但它不是唯一的限速因素。好氧和厌氧污泥的假二级反应模型比一级、二级反应模型更能描述污泥的吸附过程。Langmuir和Freundlich的吸附平衡方程都适合描述厌氧和好氧污泥的吸附平衡过程。