全文获取类型
收费全文 | 556篇 |
免费 | 8篇 |
国内免费 | 5篇 |
专业分类
电工技术 | 4篇 |
综合类 | 14篇 |
化学工业 | 314篇 |
机械仪表 | 15篇 |
建筑科学 | 9篇 |
矿业工程 | 11篇 |
能源动力 | 52篇 |
轻工业 | 22篇 |
水利工程 | 5篇 |
石油天然气 | 12篇 |
无线电 | 15篇 |
一般工业技术 | 48篇 |
冶金工业 | 4篇 |
原子能技术 | 3篇 |
自动化技术 | 41篇 |
出版年
2024年 | 3篇 |
2023年 | 6篇 |
2022年 | 24篇 |
2021年 | 9篇 |
2020年 | 12篇 |
2019年 | 11篇 |
2018年 | 7篇 |
2017年 | 11篇 |
2016年 | 11篇 |
2015年 | 7篇 |
2014年 | 22篇 |
2013年 | 29篇 |
2012年 | 18篇 |
2011年 | 45篇 |
2010年 | 21篇 |
2009年 | 30篇 |
2008年 | 35篇 |
2007年 | 36篇 |
2006年 | 19篇 |
2005年 | 22篇 |
2004年 | 19篇 |
2003年 | 27篇 |
2002年 | 17篇 |
2001年 | 27篇 |
2000年 | 17篇 |
1999年 | 14篇 |
1998年 | 11篇 |
1997年 | 14篇 |
1996年 | 7篇 |
1995年 | 8篇 |
1994年 | 11篇 |
1993年 | 2篇 |
1992年 | 2篇 |
1991年 | 3篇 |
1990年 | 1篇 |
1989年 | 3篇 |
1988年 | 2篇 |
1987年 | 2篇 |
1986年 | 2篇 |
1985年 | 1篇 |
1984年 | 1篇 |
排序方式: 共有569条查询结果,搜索用时 187 毫秒
101.
Rafael Luque Sushanta K. Badamali James H. Clark Macarena Fleming Duncan J. Macquarrie 《Applied Catalysis A: General》2008,341(1-2):154-159
A smart and greener microwave approach to the selective oxidation of cyclohexene is reported whereby, depending on the reaction conditions, the epoxide (65% conversion, 75% selectivity), the enol (70% conversion, 80% selectivity) or the enone (>99% conversion, 89% selectivity) can be obtained in a short period of time ranging from 1 to 20 min. A cobalt-salen-SBA-15 material was employed as catalyst. The reported solventless microwave protocol was simple, greener and more efficient compared to any other reported cyclohexene oxidations. 相似文献
102.
The investigation of Al2O3 etch characteristics in the BCl3/Ar inductively coupled plasma was carried out in terms of effects of input process parameters (gas pressure, input power, bias power) on etch rate and etch selectivity over poly-Si and photoresist. It was found that, with the changes in gas pressure and input power, the Al2O3 etch rate follows the behavior of ion current density while the process rate is noticeably contributed by the chemical etch pathway. The influence of input power on the etch threshold may be connected with the concurrence of chemical and physical etch pathways in ion-assisted chemical reaction. 相似文献
103.
104.
涤纶织物渗透碱减量工艺的探讨 总被引:1,自引:0,他引:1
本文主要介绍适宜在YH400、600、800型液汉式自动碱减量机上进行涤纶织物渗透碱减量加工工艺。通过对桃皮绒、卡丹绒、水洗绒、华达呢等10种织物的碱减量试验,筛选了适应涤纶减量的渗透剂,获得了各种织物碱减量试验数据,以指导实际生产。 相似文献
105.
本文对纯棉及棉/亚麻交织布实施高效短流程前处理工艺进行了讨论,采用正交设计法从6只国产稳定剂中优选出新型高效的非硅双氧水漂白稳定剂AR-750,并在不同前处理设备上进行生产性应用试验,获得了理想的结果。 相似文献
106.
Attainable regions of reactive distillation—Part III. Complex reaction scheme: Van de Vusse reaction
Vinay Amte Sriharsha Nistala Ranjan Malik Sanjay Mahajani 《Chemical engineering science》2011,66(11):166
The main underlying principle behind the application of reactive distillation (RD) for selectivity enhancement is to facilitate the separation of selected components and favorably manipulate the composition profiles in the reactive zone to expedite the desired reaction. In this paper, a geometric approach of attainable region (AR), which is already developed for conventional reactor network, is extended further to include few representative RD configurations. We define new RD building blocks and the corresponding composition vectors that indicate a need of networking of RD units among themselves and with conventional reactors to enlarge the set of attainable compositions. A model reaction scheme of van de Vusse type ) is studied as an illustrative example and an algorithm is developed to obtain the attainable region for the given kinetics, feed composition and relative volatilities. In almost all the different cases, which are studied by varying the kinetics and volatility pattern, network consisting of RD units performs better than the conventional reactor network. 相似文献
107.
The methanol permeability, proton conductivity, water uptake and power densities of direct methanol fuel cells (DMFCs) at room temperature are reported for sulfonated hydrocarbon (sHC) and perfluorinated (PFSA) membranes from Fumatech®, and compared to Nafion® membranes. The sHC membranes exhibit lower proton conductivity (25–40 mS cm−1 vs. ∼95–40 mS cm−1 for Nafion®) as well as lower methanol permeability (1.8–3.9 × 10−7 cm2 s−1 vs. 2.4–3.4 × 10−6 cm2 s−1 for Nafion®). Water uptake was similar for all membranes (18–25 wt%), except for the PFSA membrane (14 wt%). Methanol uptake varied from 67 wt% for Nafion® to 17 wt% for PFSA. The power density of Nafion® in DMFCs at room temperature decreases with membrane thickness from 26 mW cm−2 for Nafion® 117 to 12.5 mW cm−2 for Nafion® 112. The maximum power density of the Fumatech® membranes ranges from 4 to 13 mW cm−1. Conventional transport parameters such as membrane selectivity fail to predict membrane performance in DMFCs. Reliable and easily interpretable results are obtained when the power density is plotted as a function of the transport factor (TF), which is the product of proton concentration in the swollen membrane and the methanol flux. At low TF values, cell performance is limited by low proton conductivity, whereas at high TF values it decreases due to methanol crossover. The highest maximum power density corresponds to intermediate values of TF. 相似文献
108.
Wen-Sheng Wang Yan-Bin Li Bao-Jiao Gao Xiao-Wei Huang Yong-Qi Zhang Yang Xu Fu-Qiang An 《Chemical Engineering Research and Design》2013
Rare earth is a very important resource. But, impurities, such as Fe2+, have great influence on the properties of rare earth material. In this paper, a novel Fe2+-ionic imprinted polyamine functionalized silica gel adsorbent was prepared by a surface imprinting technique for selective adsorption of Fe2+ from rare earth solution. Firstly, functional macromolecule polyethyleneimine (PEI) was grafted onto the surfaces of silica gel particles, and the PEI/SiO2 was formed. Secondly, the ionic imprinting process was carried out using Fe2+ ion as a template, and Cr3+ ionic imprinting polyamine IIP-PEI/SiO2 was prepared. The adsorption and recognition properties of IIP-PEI/SiO2 for Fe2+ were studied in detail, and the effects of main imprinting conditions, such as the amount of crosslinking agent and reaction time, on the adsorption property of the imprinted material IIP-PEI/SiO2 were examined. The experimental results showed that the IIP-PEI/SiO2 possesses strong adsorption affinity, specific recognition ability, and excellent selectivity for Fe2+. The adsorption capacity could reach to 0.334 mmol g−1, and relative selectivity coefficients to Pr3+ and Ce3+ are 23.25 and 18.42, respectively. Besides, the IIP-PEI/SiO2 was regenerated easily using diluted hydrochloric acid solution as eluent and IIP-PEI/SiO2 possesses better reusability. 相似文献
109.
Stephen A. Wise 《Polycyclic Aromatic Compounds》2013,33(3-4):197-230
In 1981 the National Bureau of Standards, now the National Institute of Standards and Technology (NIST), issued the first natural matrix Standard Reference Material (SRM) for the determination of polycyclic aromatic compounds (PACs), SRM 1580 Organics in Shale Oil. In the next 10 years, additional natural matrix SRMs were developed including air and diesel particulate matter, petroleum crude oil, coal tar, sediment, and mussel tissue. The SRMs represented the "first generation" of natural matrix SRMs for the determination of PACs. The SRMs had "certified" values for only 5 to 12 PACs; however, their development established the foundation for the implementation of the "two or more independent analytical techniques" approach for certification of individual PACs in environmental matrices. The requirement for use of different analytical techniques spurred the development of both gas chromatography (GC) and liquid chromatography (LC) approaches for the determination of PACs. Since the mid-1990s, the "second generation" of natural matrix SRMs has been issued by NIST with certified values for over 20 PACs in each material. The greater number of certified values in these SRMs was the result of the combination of measurements using reversed-phase LC with fluorescence detection, multidimensional LC, and GC with mass spectrometric detection using two or more stationary phases with different selectivity for polycyclic aromatic hydrocarbon (PAH) separations. This article discusses the significant developments in analytical methods and chromatographic separation of PAHs during the past 20 years that have resulted in the certification of over 25 SRMs, which are now used worldwide for the validation of analytical methods for the measurement of PACs in environmental matrices. 相似文献
110.
Catherine Branger Walid Meouche André Margaillan 《Reactive and Functional Polymers》2013,73(6):859-875
Selective recognition of metal ions is a real challenge for a large range of applications in the analytical field (from extraction to detection and quantification). For that purpose, ion-imprinted polymers (IIPs) have been increasingly developed during the last 15 years on the principle of molecularly imprinted polymers (MIPs). Those imprinted materials are designed to mimic the binding sites of biological entities and assure an improved recognition of the template species. The aim of this review is to give the current state of the art in the conception of IIPs from the components to the polymerization process. Some applications of those materials will be also discussed. 相似文献