Passive and transpassive behaviour of CoCrMo in simulated biological solutions

In this work, the behaviour of a CoCrMo alloy under simulated body conditions was investigated. More specifically, the electrochemical properties of the alloy and the relevant mechanisms in the passive and transpassive states were studied in detail. Electrochemical techniques such as potentiodynamic and potentiostatic polarisation, cyclic voltammetry, rotating disc electrode and electrochemical impedance spectroscopy were employed. Further, ex situ X-ray photoelectron spectroscopy analysis of the passive films was carried out. A good correlation between the results obtained from all the experimental techniques was achieved. Overall, it was found that the passive film on CoCrMo changed in composition and thickness with both potential and time. The passive behaviour of the CrCrMo alloy is due to a formation an oxide film highly enriched with Cr (≈90% Cr oxides) on the alloy surface. The passive and transpassive behaviour of the alloy is hence dominated by the alloying element Cr. In the transpassive region, strong thickening of the oxide film takes place, combined with a change in the composition of the film, and strongly increased dissolution rate. In the transpassive region, all alloying elements dissolve according to the composition of the alloy. The metal ion release is also very strongly enhanced by cyclic variation of the potential between reducing and oxidizing conditions. In this case, during activation/repassivation cycles, cobalt dissolution is greater than expected from the composition of the alloy. Therefore, active dissolution behaviour is mainly dominated by the alloying element Co.     

Corrosion of 2205 duplex stainless steel in chloride medium containing sulfate-reducing bacteria

Sulfate-reducing bacteria (SRB) play significant role in the corrosion of stainless steels exposed to marine and soil environment. Sulfate reduction by bacterial species results in the production of H₂S, which can significantly influence the anodic and cathodic processes and ultimately enhances the corrosion of materials. In the present study, 2205 type duplex stainless steel (DSS) coupons in solution-annealed condition were exposed to chloride medium containing SRB species, Desulfovibrio desulfuricans, for 40 days and examined by microscopy. Etching of the duplex structure, pitting as well as crevice attack were noticed. Similar results were obtained by microscopic studies with coupons exposed for 14 days in medium containing SRB followed by anodic polarization. SEM studies, of crevices observed after anodic polarization, indicated that the attack was initiated at the grain boundaries and slowly encroached into austenite grains. The initiation of attack was also evident from AFM studies of coupon exposed under freely corroding conditions for 7 days. ESCA studies reveal that under anaerobic conditions of SRB growth sulfidation of passive film occurs. The modified passive film found to depolarize the cathodic reactions. The nature and mechanism of SRB attack on DSS and possibility of detection at early stages were discussed.     

现场总线技术在非能动压水堆核岛中的应用

本文结合非能动压水堆核电控制系统结构,详细介绍Profibus现场总线和Modbus现场总线在非能动压水堆核电控制系统中的应用,包括两种现场总线技术的结构配置及和现场智能仪控设备的连接,并简要分析现场总线技术在核电行业应用的优点和需克服的技术问题。     

不锈钢在湿法磷酸中腐蚀行为研究

本文采用腐蚀实验和电化学测试方法对不锈钢在湿法磷酸中的腐蚀行为进行了研究，并进行钝化膜的组成与结构分析。研究表明，磷酸中加入ＳＯ４＾２＾－，ｃＬ＾－，Ｆ＾－均提高合金的维钝电流密度和致纯电流浓度，加速材料的腐蚀，这些杂质共存时腐蚀性更大。湿法磷酸中存在的Ｓｉ＾４＾＋，Ａｌ＾３＾＋，Ｍｇ＾２＾＋和Ｆｅ＾３＾＋起缓蚀作用。不锈钢纯化膜主要由Ｃｒ和Ｆｅ的氧化物组成，表面形成致密稳定的Ｃｒ２Ｏ３保护膜是提     

Passivity behavior of melt-spun Mg–Y Alloys

Several Mg–Y binary ribbons with Y content up to 17.9 at.% were fabricated by melt-spinning. X-ray diffraction (XRD) revealed that the phase structure changes with increasing Y content from extended solid solution to partially amorphous, and then fully intermetallic Mg₂₄Y₅. Anodic potentiodynamic polarization performed in 0.01 M NaCl electrolyte (pH=12) revealed improved anodic passivity behavior compared to pure Mg for all the Mg–Y alloys. X-ray photoelectron spectroscopy (XPS) revealed that the improved passivity of Mg–Y was more related to the elemental oxidation state rather than the concentration of the surface components. To study the effect of Cl⁻ ion on the passivity behavior, anodic potentiodynamic and potentiostatic polarization were performed on Mg–17.9 at.% Y in alkaline (pH=12) NaCl electrolytes containing Cl⁻ ion in the concentration range from 0.00 to 0.50 M. The passive films formed in 0.01 M NaCl electrolyte were similar to the native film, which were composed of MgO and Y₂O₃. No CO₃²⁻ and Cl⁻ ions were incorporated into the passive film. The passivity was significantly degraded in the electrolytes containing higher Cl⁻ concentration (0.1 and 0.5 M). Detailed XPS revealed that the surface films under these conditions were composed of much hydrated species Mg(OH)₂ and YOOH and/or Y(OH)₃ and CO₃²⁻ was incorporated into the surface film. The incorporation of Y₂O₃ in the passive film was given as the reason for the enhanced passivity properties of Mg–Y ribbons. The mechanism of Cl⁻ and CO₃²⁻ ions to the degradation of the passivity was discussed.     

平直节理黏结颗粒材料宏细观参数关系及细观参数的标定

为了分析平直节理黏结颗粒材料宏细观参数关系以及进行细观参数的标定,以单轴压缩、直接拉伸和双轴压缩数值试验作为宏观参数测试方法,对平直节理接触模型细观参数进行正交设计,采用多因素方差分析和回归分析研究宏细观参数之间的关系,在此基础上,建立了细观参数的标定方法。以灰岩的室内试验为基础,对其细观参数进行标定,模拟结果与试验结果相接近,验证了方法的有效性。     

主动式二维码考勤系统研究

提出了一种新型主动式考勤方式,并给出了一种结合二维码的应用方式.该方法大大节省了硬件支出成本,同时加快了考勤速度.综述了现阶段其他研究成果,并研究了主动式二维码考勤和被动式二维码考勤的区别.     

基于DSP的开关电源系统优化设计

针对开关电源系统中普遍存在损耗高、谐波含量大、体积大等问题,提出一种基于DSP控制的低损耗、低谐波、高功率因数开关电源优化设计系统。系统采用基于DSP生成的PWM波控制开关通断,主电路采用移相全桥零电压软开关技术,由改进的EMI滤波电路进行滤波,并应用平均电流控制方法控制Boost-PFC。整个设计对EMI滤波、功率因数校正、零电压开关等电路进行优化,通过仿真和实验结果表明,该设计具有损耗低、谐波含量低、体积小且输出电压稳定、控制电路简单、变压器制作难度得以简化、可靠性高等优点。     

一种新型LED驱动器的分析与设计

传统的具有功率因数校正(power factor correction,PFC)功能的DC输出LED驱动器需要在输出端用容值较大的电解电容来减小输出电流纹波。为解决电解电容的使用寿命短而造成驱动器寿命低于LED寿命的问题,采用一种新型的AC LED拓扑电路结构,理论分析了该拓扑电路结构以及参数的选取。由于该驱动器的输入电压和输出电压都是脉动的,驱动器的输入输出滤波可采用容值较小的薄膜电容,从而提高了驱动器的使用寿命。通过仿真和试验的结果表明,该拓扑电路结构是可行的,其参数的选取是正确的。     

XPS investigations of electrochemically formed passive layers on Fe/Cr-alloys in 0.5 M H2SO4

Passive layers on Fe20Cr and Fe15Cr were prepared by anodic oxidation in 0.5 M H₂SO₄ and were investigated by X-ray photoelectron spectroscopy. The preparation of the sputter-cleaned samples and their transfer to the ultrahigh vacuum was performed under protection of purified argon without any contact to the laboratory atmosphere. The prepassive layer consists of a homogeneous film with Cr(III)hydroxide and Cr(III)-sulphate with a low content of Fe(II). In the passive potential range a bilayer structure with enrichment of Cr(III)-oxides with an outer hydroxide and an inner oxide part is formed. Iron exists only in a bivalent oxidation state. In the transpassive potential range a pronounced change of the layer composition was observed: The outer part of the transpassive layer is formed predominantly by Fe(III) species whereas the inner part still contains a strong enrichment of Cr₂O₃.