Surface physico-chemistry study of an austenitic stainless steel: Effect of simple cold rolling treatment on surface contamination

The surface physico-chemistry properties of stainless steel and the effects of a cold rolling treatment were investigated. X-ray photoelectron spectroscopy (XPS) analyses were carried out on rolled surfaces at different rates. Thus, by characterizing passive film chemistry and contamination layer, the modifications due to this treatment were quantified, in particular an increase of the ratio (Fe/Cr)_oxide is evidenced with the level of the cold rolling treatment. Moreover, based on an angle resolved analysis, a new model where the contamination layer is represented as isolated parts was developed in order to describe the geometry of this carbon contamination. XPS experiments show an iron enrichment of the passive film during the cold rolling treatment, which seems to be explained by a surface heating during the mechanical treatment. Therefore, the new island model puts in evidence the effects of ageing time and surface condition on the geometry of carbon contamination. Hence, cold rolling increases the thickness and the recovery of carbon contamination on the stainless steel surface.     

Preparation of a two-dimensional polymer film on passivated iron by modification of a carboxylate ion self-assembled monolayer with alkyltriethoxysilanes for preventing passive film breakdown

The effect of an ultrathin, regularly arranged polymer film on prevention of passive film breakdown on iron in the presence of chloride ion was investigated. The film of two-dimensional polymer was prepared by modification of a 16-hydroxyhexadecanoate ion self-assembled monolayer adsorbed on a passivated iron electrode with 1,2-bis(triethoxysilyl)ethane(C₂H₅O)₃Si(CH₂)₂Si(OC₂H₅)₃ and octyltriethoxysilane C₈H₁₇Si(OC₂H₅)₃. The pitting potentials of the passivated electrodes bare and covered with the polymer film were determined by anodic polarization measurements in a borate buffer solution containing 0.1 M of Cl⁻. The pitting potential of the coated electrode was higher than that of the uncoated one, indicating prevention of passive film breakdown. No breakdown was observed over the potential range in the passive and transpassive regions by covering the passive film with the well-arranged two-dimensional polymer film. The film was characterized by X-ray photoelectron and FTIR reflection spectroscopies and measurement of the contact angle with a drop of water.     

电化学改性不锈钢钝化膜的XPS/SERS研究

应用Ｘ射线光电子能谱（ＸＰＳ）和表面增强拉曼光谱（ＳＥＲＳ）考察１８－８不锈钢表面电化学改性钝化膜各层次的化学组成。ＸＰＳ的结果表明电化学改性处理可使钝化膜老化。膜层中含大量的ＣｒＯ３,但未检测到ＣｒＯ４＾２－,在膜的各个层次均发生铬的富集,而在最外层铬的含量并非最大。表明在改性处理过程中,铬优先溶解,铁在膜的以存在Ｆｅ（Ⅱ）和ＦｅⅡ两种氧化态,同时有利于非晶态结构的形成。原位ＳＥＲＳ测试的结果指     

A study of the passive films on chromium by capacitance measurement

Using capacitance measurement and Mott-Schottky analysis, the semiconducting properties of passive films formed on chromium within the passive potential range under different conditions were investigated. The study reveals a p-type behavior of the passive layers. Two semiconductive parameters, i.e., the acceptor density (N_A) and the flatband potential (E_FB), which are mainly related to composition and surface charges of the passive films, have been measured. The effect of film formation potential, passivation time, pH and composition of solutions on the parameters are discussed. N_A increases either with lowering film formation potentials or with prolonging passivation times. This is attributed to the transformation of a less hydrated oxide film into a more hydrated form. The changes of E_FB are discussed as a function of adsorptive anions and pH values of electrolyte solution.     

NASA系列雪参数反演算法在单像元内的时间序列验证与分析

NASA系列算法(Chang,NASA96和Foster算法)是被动微波遥感反演雪深、雪水当量的简单、实用的经验算法,并经过了很多学者大范围的算法验证和改进。为了进一步评价NASA系列算法在东北地区的时空适用性,于长春净月潭区域选定了一个以农田和森林为主的10km×10km被动微波遥感混合像元,在时间上连续观测整个干雪期(2014年12月至次年2月)的积雪参数和气象数据,结合FY3B卫星搭载的微波成像仪(MWRI)亮温数据,对NASA系列算法精度进行了评价分析。结果表明:对于雪深的反演,Chang算法和NASA 96算法前期反演效果较好,后期随着时间的推进高估雪深的趋势愈加明显。由于考虑了森林覆盖率的影响,NASA 96算法的反演精度更高。两种算法最大高估值分别是24.46和14.62cm,这是因为期间雪性质不断变化,尤其是雪粒径不断增大的缘故。Foster算法也严重高估了雪水当量,可能是由于积雪类型的分类系统未必适合于东北地区的积雪特征。本文的积雪连续观测数据为认识东北地区的积雪特性奠定了基础,对算法的时间序列验证与分析为雪参数反演算法的进一步改进提供了可靠依据。     

X射线衍射仪3kW高频高压电源设计

提出了一种适用于X射线衍射仪的高频高压电源的设计方法。该电源系统采用高频技术,克服了传统工频电源设备笨重、体积大、效率低等缺陷;采用脉宽调制技术(PWM)对系统进行控制和保护,使信号稳定;采用功率因数校正(PFC)技术使系统的功率因数达到了0.9。     

一种基于Link606带无源PFC电路的开关电源

本文介绍一种带无源PFC的开关电源的实现方法,并将其与不带PFC功能的传统开关电源进行比较,阐述其工作原理,进一步从细节上分析其实现PFC作用的方式。选择PI公司的LINK606系列芯片,与该无源PFC电路组合,设计了一款开关电源,使该电源输出恒流。本文还给出了相关原理图、波形和实验数据。     

浅析广电数字双向网络改造中的EPON技术应用

以太无源先网络是一个专门应用于接入网的技术.采用点到多点的网络拓扑结构,在一芯光纤上利用上下行两个波传输数据,下行数据采用广播方式的时分复用方式,上行数据采用时分多址接入的方式,达到利用光纤实现数据、语音和视频多种业务接入的目的.     

Low-valence ion addition induced more compact passive films on nickel-copper nano-coatings

Ni-Cu nano-coatings were prepared by pulsed electroplating technique in the baths containing various amount of boric acid. Their microstructure, morphologies and corrosion resistance were characterized in detail. The addition of boric acid strongly influences on the microstructure of the Ni-Cu coatings. The coating with a grain size of 130 nm, obtained from the bath containing 35 g L⁻¹ boric acid, shows the highest corrosion resistance. This is attributed to the low-valence Cu ion (Cu⁺) additions in nickel oxide, which could significantly decrease the oxygen ion vacancy density in the passive film to form a more compact passive film. The higher Cu⁺ additions and the lower diffusivity of point defects (D₀) are responsible for the formation of more compact passive film on the coating obtained from the bath with 35 g L⁻¹ boric acid.     

Development of a tundra-specific snow water equivalent retrieval algorithm for satellite passive microwave data

Airborne and satellite brightness temperature (T_B) measurements were combined with intensive field observations of sub-Arctic tundra snow cover to develop the framework for a new tundra-specific passive microwave snow water equivalent (SWE) retrieval algorithm. The dense snowpack and high sub-grid lake fraction across the tundra mean that conventional brightness temperature difference approaches (such as the commonly used 37 GHz-19 GHz) are not appropriate across the sub-Arctic. Airborne radiometer measurements (with footprint dimensions of approximately 70 × 120 m) acquired across sub-Arctic Canada during three field campaigns during the 2008 winter season were utilized to illustrate a slope reversal in the 37 GHz T_B versus SWE relationship. Scattering by the tundra snowpack drives a negative relationship until a threshold SWE value is reached near 130 mm at which point emission from the snowpack creates a positive but noisier relationship between 37 GHz T_B and SWE.The change from snowpack scattering to emission was also evident in the temporal evolution of 37 GHz T_B observed from satellite measurements. AMSR-E brightness temperatures (2002/03-2006/07) consistently exhibited decreases through the winter before reaching a minimum in February or March, followed by an increase for weeks or months before melt. The cumulative absolute change (Σ|Δ37V|) in vertically polarized 37 GHz T_B was computed at both monthly and pentad intervals from a January 1 start date and compared to ground measured SWE from intensive and regional snow survey campaigns, and climate station observations. A greater (lower) cumulative change in |Δ37V| was significantly related to greater (lower) ground measured SWE (r² = 0.77 with monthly averages; r² = 0.67 with pentad averages). Σ|Δ37V| was only weakly correlated with lake fraction: monthly r² values calculated for January through April 2003-2007 were largely less than 0.2. These results indicate that this is a computationally straightforward and viable algorithmic framework for producing tundra-specific SWE datasets from the complete satellite passive microwave record (1979 to present).