Pretreatment with Ozone for Gold and Silver Recovery from Refractory Ores

In this work ozonization was studied as pretreatment for two Mexican refractory ores in order to increase the gold and silver extraction. Two methods for contacting ozone with the mineral were studied (indirect and direct). The indirect method did not change the precious metals recoveries for mineral sample A, but increased those of mineral B (from 53 to 88% for gold and from 26 to 78% for silver). The direct pretreatment, only tested in mineral A, did not affect gold and silver recoveries but decreased the extraction time from 40 to 24 hours for maximum metal recovery.     

耐火材料声发射源信号的盲反卷恢复

声发射信号是表征材料内部损伤状态的重要指标。由于源信号无法直接获取,研究的通常是传播一段距离后已失真的信号,这对材料损伤状态的准确判断带来了影响。为了降低传播路径对声发射源信号的衰减和失真带来的不利影响,假设声发射信号在耐火材料的传递路径为线性系统,对传递通道的冲击响应函数进行了估计,并设计了反卷滤波器。与实验结果对比发现,该方法很好的辨识了传递通道未知的系统,并能一定程度地恢复声发射源信号,为材料损伤状态的准确判断提供参考。     

Recycled granulate obtained from waste alumina-rich refractory powder by the cold bonding process

Within the scope of the present study the cold-bonding process was used for the recycling of waste filter powder which was mixed with two different binders in different concentrations; alumino-silicate cement and potassium water glass, and combinations of these two materials, and hardened at room temperature. Selected samples were also fired at 1200 °C. Tests to determine tensile and compressive strength, density and porosity, as well as dilatometry and SEM analyses, were performed. As expected, compressive strength increased as a function of the concentration of the potassium water glass. When combinations of both binders were used, compressive strengths were higher, but a significant increase in strength was also achieved by firing the samples. The compressive strengths of the non-fired samples were in the range from 0.8 to 2.4 MPa, whereas after firing strengths of up to 36 MPa were obtained. During the firing density increased, and porosity was reduced, while the average pore size increased. The results of dilatometric analysis showed that the granulate produced with cement shrink upon firing up to 300 °C, but then start slowly to expand, whereas the granulate produced by water glass first expanded on firing up to 800 °C, and then began to shrink swiftly. In the case of combinations of the two binders, shrinkage as well as expansion on firing was less pronounced. Selected granulate prepared using potassium water glass were also tested in a refractory concrete matrix in order to verify their usability.     

获各琦铜矿铜Ⅱ矿体选矿捕收剂方案探索

针对获各琦铜矿铜Ⅱ矿体赋存特点为沉积变质矿床,具有层位控矿及岩性控矿的特点,铜矿体赋存在石英岩中,并由多条矿体组成,存在较大的选矿难度。笔者通过不同药剂制度下进行了选矿指标必选,获得了较优的选矿指标,可提高Cu回收率3%-5%。     

JN2000 系列 800t·d-1 活性石灰回转窑介绍

详细介绍了中冶焦耐工程技术有限公司自主开发的JN2000系列800t·d^-1活性石灰回转窑的技术参数及特点。该种窑已投入使用,其各项技术指标均达到设计要求。     

延长顶吹炉炉期的有效途径

顶吹炉的“一炉三段”直接炼铅工艺技术不仅资源利用效果良好,而且节能、环保,在国际上居领先水平。先进的工艺需要低成本的支撑,炉衬的成本在顶吹炉运行成本中占有举足轻重的地位。如果炉衬使用寿命短,导致炉期缩短,运行成本必然增加,影响到“一炉三段”的产业化应用。因此,改进顶吹炉的布料方式,保护炉衬,延长炉期,从而减少维修成本,提高成本效益,以达到延长炉寿的目的,顶吹炉综合效益才能充分体现出来。本文主要介绍了延长顶吹炉炉期的技术改造方法和实际运用的效果。     

Interactions of refractory materials with molten gasifier slags

The current study focuses on the analysis of sessile-drop interfacial reactions between two synthetic slags (based on average ash chemistries of coal and petcoke feedstock) and two refractory materials (90 wt% Cr₂O₃-10 wt% Al₂O₃ and 100 wt% Al₂O₃), using a Confocal Scanning Laser Microscope (CSLM). Ground slag samples (less than 325 mesh) were placed at specific microstructure locations on refractory substrates and heated to 1500 °C in an atmosphere of CO/CO₂ gas mixture (volume ratio = 1.8), using a gold-image heating chamber. Cross-sections of the slag/refractory interface indicated unique slag penetration into preferred areas of the refractory and grain dissolution into the slag which promoted spalling of the refractory. Initially, the slag attacked both grain boundaries and fine microstructure areas, freeing alumina grains into the slag. The formation of VO_x-based crystalline material in the petcoke slag was found to alter the liquid composition. Chemical spalling of Cr-containing crystal layer also facilitated degradation of the refractory.     

宝钢的生产发展及对耐材的要求

宝钢在建的三期工程和三期后的改造、配套项目，采用了许多新技术，与此相应对所使用的耐火材料在品种和质量上也提出了许多新要求。     

Fungal pretreatment of sulfides in refractory gold ores

This study assessed the capability of the fungus, Phanerochaete chrysosporium, to decompose pyrite, arsenopyrite and a sulfide-containing flotation concentrate in an effort to develop a microbial process for pretreating refractory gold ores. The extent of biotransformation was monitored by analyzing for iron, sulfur and arsenic in incubation solutions, and for sulfide sulfur in the residual solids. The results were then expressed as percentages of the initial weights. For arsenopyrite, 1.5 wt.%, 7.2 wt.% and 10.3 wt.% of iron, arsenic and sulfur respectively were present as soluble constituents in the incubation solution within 21 days of fungal treatment, whereas for pyrite, there was 1.2 wt.% iron and 6.0 wt.% sulfur. For the same processing period in the case of the flotation concentrate, 1.8 wt.%, 6.1 wt.% and 10.7 wt.% respectively of iron, arsenic and sulfur remained in solution. Overall, the decomposition of sulfide sulfur in the samples was 15 wt.%, 35 wt.% and 57 wt.% respectively for pyrite, arsenopyrite and the flotation concentrate. Changes in sulfide sulfur concentration and the formation of oxide phases during fungal treatment were confirmed using Raman spectroscopy and X-ray diffraction analysis. These results suggest that P. chrysosporium is a potential microorganism for oxidative decomposition of metal sulfides associated with refractory gold ores.     

高耐热强度低合金耐火H型钢的研究

在试验室50kg真空感应炉冶炼了低碳低合金化耐火H型钢。结果表明，成分为（%）；0.11C,1.30Mn,0.45Cr,0.48Mo,0.026Nb耐火H型钢的600℃σ8可达306MPa，并具有良好的室温综合机械性能。