Investigation of Scale Formation in Heat Exchangers of Phosphoric Acid Evaporator Plants

The primary problem in concentrating phosphoric acid is due to fouling on the tube‐side of the heat exchangers of the evaporator units. Scaling on the heat transfer surfaces occurs because of high supersaturation of phosphoric acid liquor with respect to calcium sulphate. A review of the existing literature reveals that no information is available on heat transfer and on crystallization fouling of industrial phosphoric acid solutions. In this investigation, the solubility of different calcium sulphate types in phosphoric acid solution was studied and its dependency on acid concentration and temperature was investigated. A large number of fouling experiments were carried out in a side‐stream of a phosphoric acid plant at different flow velocities, surface temperatures and concentrations to determine the mechanisms, which control the deposition process. After identifying the effects of operational parameters on the deposition process, a model was developed for prediction of fouling resistances. The reaction of calcium sulphate crystallization followed a second order rate with respect to the supersaturation. The activation energy evaluated for the surface reaction of the deposit formation was found to be 57 kJ/mol. The predicted fouling resistances were compared with the experimental data. Quantitative and qualitative agreement between measured and predicted fouling rates is good.     

河北省张承地区风沙现状及治理对策

在分析张家口、承德地区风沙形成原因及发展趋势的基础上,提出了河北省防沙治沙工作中存在的问题,根据河北省不同类型区的自然、地理及社会经济条件,提出了风沙治理模式和建议。     

Analytic and numerical calculations of the formation of a sulphuric acid aerosol in the upper troposphere

Analytic and numerical calculations are performed on the production of sulphuric acid aerosol in conditions of a very large nucleation event observed in the upper troposphere. The numerical results feature a growing peak in the size distribution whose magnitude is reproduced well analytically, and are consistent with the observed particle number concentration at sizes greater than 25 nm (measured dry diameter), but suggest that most of the aerosol was at unobserved smaller sizes. Because of growth and coagulation, number concentrations of the aerosol rapidly become independent of the number initially nucleated, so that conclusions as to the nucleation process, either homogeneous or ion-induced nucleation, cannot easily be drawn from existing atmospheric observations. The final concentration is very insensitive to the magnitude of the SO₂ source, but, if condensation on, and coagulation with, a remnant background aerosol occurs, such nucleation events will be cut off for source magnitudes less than a specific value. Anthropogenic emissions of SO₂ which exceed this value can produce higher aerosol number concentrations in the atmosphere with consequences for the indirect effect of aerosols on the climate.     

陕北富县探区天然气藏钻井液屏蔽暂堵技术

陕北富县探区上古生界储层属低孔、低渗的致密储层,下古生界主要储集空间为溶蚀孔洞和裂缝,孔洞多为1～3 mm的小孔,裂缝宽度为0.2～7.0 mm,油气主要聚集在裂缝中.优选出了由复合暂堵剂CXD、憎水性屏蔽剂DYC和表面活性剂ABA组成的屏蔽暂堵配方,其中CXD具有架桥作用并对裂缝性储层有独特暂堵效果,DYC有浊点效应、能在井壁上快速形成阻止滤液侵入的油膜,ABA能减少水锁损害.加入暂堵剂后的钻井完井液,抑制性增强,页岩回收率在90%以上;高温高压滤失量降低,滤饼薄而韧、光滑;岩心静态渗透率恢复值大于90%;滤饼摩阻系数降低.富古6井通过使用该完井液,堵塞比和表皮系数都在轻微污染范围内,井径扩大率比其它井有不同程度的降低,表明优选出的屏蔽暂堵钻井完井液,能很好地保护陕北探区天然气藏.     

原油沥青质沉积引起储集层损害的室内评价

防止沥青质沉积造成的储集层损害是渤海稠油油藏开发生产中遇到的技术难题之一。结合渤海SZ36-1油田实际情况，使用岩心流动实验装置，建立沥青质沉积导致储集层岩心渗透率下降的室内评价方法，并应用SARA法对稠油发生沥青质沉积的可能性进行预测。评价实验结果表明，损害程度与沥青质沉积量和储集层岩心的原始渗透率有关。沉积量越大，原始渗透率越低，则损害越严重。表5参12     

川东北三叠系飞仙关组鲕滩气藏有利储集层的形成与分布

川东北地区三叠系飞仙关组鲕滩气藏是近年四川盆地碳酸盐岩天然气勘探取得重大突破的领域，目前在中国石油探区内已发现罗家寨、渡口河、铁山坡等大中型气藏。对鲕滩气藏白云岩储集层进行岩心观察、显微薄片分析，并进行微量元素、流体包裹体、X衍射、阴极发光及电子探针等分析，结果表明，白云岩化和多期溶蚀是形成优质白云岩储集层的关键因素，混合云化与埋藏云化的叠加作用是形成孔隙性白云岩储集层的基本条件。飞仙关组鲕滩气藏储集层经历了4期溶蚀作用，即同生期溶蚀作用、浅埋期溶蚀作用、深埋期溶蚀作用和抬升期溶蚀作用，形成优质白云岩储集层的主要溶蚀作用是浅埋期和深埋期的溶蚀作用。优质白云岩储集层主要分布在台缘鲕粒滩相带，纵向与亮晶鲕粒灰岩呈韵律性互层，横向主要分布在鲕粒滩坝靠近漏湖-潮坪一侧。     

榆林气田气井废弃条件的确定

榆林气田是典型的低渗透气田，要准确计算其采收率和可采储量，必需确定气井的废弃条件。传统方法对气井的废弃地层压力进行计算时，由于忽视了开发过程中产能方程的变化，造成计算结果存在一定的误差。根据气井废弃地层压力的相关理论和计算方法，考虑了对气井产能方程影响较大的参数的变化，结合榆林气田气井矿场实际，推导出了适合榆林气田计算气井任意时刻二项式方程系数的公式，进而得到气井废弃时的稳定二项式方程。根据垂直管流法计算得到废弃井底流压，从而得到可靠的气井废弃地层压力，再结合经济评价即可确定气井的废弃产量。实例计算表明，新方法实用、有效，更切合气田实际。     

用屏蔽暂堵技术封堵水平井裂缝性漏层

克拉玛依油田HW702水平井的大斜度段和水平段,将穿越纵向裂缝发育的二叠系佳木河组储层。为安全钻进和保护油层,用超细碳酸钙和磺化沥青复配后加入复合离子钻井液中成屏蔽暂堵的堵漏钻井液。室内用岩心试验,屏蔽暂堵后渗透率可降为0,暂堵深度小于3cm,可用酸化和射孔解堵。现场使用效果也很好,使HW702水平井顺利完钻,并获得工业油气流。     

机械锁定式地层测试技术研究与应用

机械锁定式测试技术操作简单，测试一次成功率高，资料录取准确全面，且测试结束后可直接进行封堵作业；解封时，机械锁紧产生一个向上的震击力，有利于解封，没有换位机构的测试阀在关井期间使管柱处于自由拉伸状态，有利于保护油管。在N阀上部管柱中加1-2根伸缩接头，便可用于海洋井测试。     

铅酸蓄电池的清洁生产

就中国铅酸蓄电池工业的可持续性发展与清洁生产问题进行了初步探讨,并就蓄电池正负极板水洗的清洁生产实例进行了介绍。