Underground Mining of Kimberlite Pipes under Alluvia

The scheme is proposed for underground mining of kimberlite pipe under alluvia 80-100 m in thickness. The main features of the technology are the refusal to carry out filling operations and use ore vibration discharge ensuring its simultaneous flow over the pipe cross-section.     

Electrical contacts for II-VI semiconducting devices

High resistivity II-VI semiconductors in general and CdTe and its associated materials like CdZnTe and CdMnTe in particular are suffering from ohmic contacting problem due to their high electron affinity and consequently large work function. Ni, Au, Pt and Pd have large work function and have possibility to match with the above materials. However, except Ni other materials have problems in large-scale commercial applications. In order to overcome the ohmic contacting problem to these semiconductors the following studies has been conducted in the text of the present paper. These are: (i) Work function engineering to modulate the work function through combination materials like, Cu, Au, Mo, W and Co. (ii) Introduction of a charge diluting intermediate semiconducting layer media in between the metal and CdTe to neutralize the bound polarized charges. These two aspects were applied in case of thin film CdTe-CdS solar cells to evaluate their contacting performances and their influences in solar cell parameters. Both cell performances and the contact characteristics of these contacting technologies were studied at depth and indicated their applicability in semiconducting devices.     

POD基炭薄膜形成过程的研究

制备出了ＰＯＤ（聚恶二唑）薄膜，测定了ＰＯＤ薄膜试样在热解炭化期间的化学结构和重量变化，研究了ＰＯＤ薄膜的炭行为。随着热解温度的提高，ＰＯＤ大分子在氧二氮茂环处发生断裂，形成具有共轭腈基苯的化合物。新生成的〉Ｃ＝Ｎ－和－Ｎ＝Ｃ＝Ｏ基团继续进行反应，其中－Ｎ＝Ｃ＝Ｏ基团通过耦合反应生成炭化二亚胺（－Ｎ＝Ｃ＝Ｎ－）；再经分子链环化转变成具有吡啶型大共轭结构的多环化合物，继而稠环芳构化生成类石墨芳香族六     

地层压力下降对指数式产能方程的影响分析

随着地层压力的下降，与指数式产能方程流动系数密切相关的参数，如天然气偏差系数、天然气粘度、气层渗透率、有效厚度等都是变化的。气层渗透率、有效厚度的变化甚微，相比之下可以忽略不计；而天然气偏差系数和粘度的变化却不容忽视，两者之乘积不断变小，由此引起指数式产能方程流动系数不断增大。通过分析，给出了指数式产能方程流动系数随天然气偏差系数和粘度对应变化的关系式。当已知气井某一时刻的指数式产能方程后，便可确定任意地层压力下的气井产能，从而更准确地指导气井开采，避免重复试井工作。     

The influence of latex blend composition on crosslinking and mechanical properties

Model reactive latices were synthesized by semicontinuous emulsion copolymerization of n‐butyl methacrylate and acetoacetoxyethyl methacrylate or dimethylaminoethyl methacrylate. The two functional latices were then blended in various ratios to study the influence of blend composition on crosslinking and mechanical properties of the resulting films. Crosslinking was quantified through swelling measurements. It was found that the crosslink density increased with increasing amounts of acetoacetoxy‐functional polymer. In addition, the crosslink density exhibited two maxima, at 30/70 and 70/30 (acetoacetoxy‐functional latex/amino‐functional latex) blend compositions. The mechanical properties of the films were quantified by dynamic mechanical analysis (DMA). It was shown that optimal mechanical properties occurred when the particles packed most efficiently at the 30/70 and 70/30 blend compositions. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 104: 3774–3779, 2007     

Shift catalysts in biomass generated synthesis gas

One of the CHRISGAS project objectives is to study the shift catalysts in biomass-generated synthesis gas. The water gas shift reaction is ruled by equilibrium, and the state of the gas can for a given H₂/CO ratio be shifted by addition/removal of water, CO₂ and/or by a change in the temperature. Stability area in respect to gas composition, sulphur content, pressure and temperature for FeCr shift catalyst has been investigated by thermodynamic equilibrium calculations. The calculations show that carbide formation is favourable in the “Normal water” case without sulphur in the gas. If sulphur is present in the gas, the situation improves due to sulphide formation.     

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南海西部石油公司在其管辖的莺歌海、琼东南盆地中深层勘探中遇到高温高压储层，在中外专家的协助下于１９９４年７月在水深１１５ｍ的崖２１－１构造上钻成深度４６８８ｍ的探井，经测试地层压力为１０５．１５ＭＰａ，地层温度２０６℃，获得齐全准确的各项数据。在半潜式钻井平台上进行高温高压井测试是世界石油界探讨和努力解决的难题。防止意外井喷事故是测试的先决条件。对地面设备、井下工具和工艺方法的选取一切应以安全为前     

厚壁不锈钢弯头扩径推弯成型的新方法

厚壁不锈钢弯头的扩径推弯成型是管件生产的难点。提出了一种近似超塑变形的扩径推弯成型方法，并成功地用于厚壁不锈钢弯头的生产。还介绍了该成型方法的相关工艺参数。     

示烃成岩矿物与油气成藏的关系——以东营凹陷为例

示烃成岩矿物是指与烃类活动具有成因关系的成岩矿物.通过综合利用地质、矿物岩石和地球化学方法,识别出了铁白云石、铁方解石、高岭石和黄铁矿4种示烃成岩矿物.对东营凹陷示烃成岩矿物在研究区不同层系中的分布和发育特征的分析结果表明,对示烃成岩矿物的研究可以在研究区流体输导体系中再现流体运动的过程及规律,分析其中控制物质演变和能量再分配的主导因素,揭示沉积盆地的油气生成、运移和成藏过程与成矿作用的对应关系,并对深部成岩作用以及油气运聚成藏在埋藏阶段的成岩响应进行评估.该研究成果对油气勘探开发具有较高的理论和应用价值.