Photoalignment dynamics of azo dyes series with different coordination metals

There are many photoaligned azo dyes that can be used for orientation of liquid crystals in various display devices. However, the structure of these compounds needs to be optimized to increase the rate of the process of molecule photoalignment, as well as to spread the application of these compounds. The main coordination metal that presents in the molecules of azo dyes is sodium derivatives. The use of other alkali metals remains an open question. We used quantum‐chemical computation methods and reversible intermolecular bonding model to determine the effect of metal coordination on the velocity of photoalignment. The theoretical predictions were experimentally verified using sodium, potassium, lithium, and cesium salts of the model azo dye synthesized by us. We conclude that potassium azo derivatives are the fastest, ceteris paribus.     

Aggregation arrestant pheromone of the German cockroach,Blattella germanica (L.) (Dictyoptera: Blattellidae): Isolation and structure elucidation of blattellastanoside-A and -B

The aggregation pheromone of the German cockroach,Blattella germanica, consists of attractant and arrestant, which can be detected by olfactometer and choice-chamber assay, respectively. Both were extracted from the frass-contaminated filter paper being used as a shelter. They were separated by solvent partition withn-butanol and water. The arrestant from then-butanol phase was purified by open column chromatography and then successive HPLC isolated two major arrestant components. Spectral evidence from SI-MS, HR-EI-MS, and NMR experiments with pulse techniques provided possible structures as 1-(6-chloro-4,5-epoxy-5-stigmast-3-yl)--d-glucopyranoside and 1-(6-chloro-5-hydroxy-5-stigmast-3-yl)--d-glu-copyranoside, denoted as blattellastanoside-A and blattellastanoside-B, respectively. They represented arrestant activity as median effective doses (ED₅₀) at 0.044 (A) and 3.2 (B) nmol on 1.0 cm² of Whatman No. 1 filter paper.     

Piezo- and pyroelectricity in polymer blends of poly(vinylidene fluoride)/poly(methyl methacrylate)

Compatible polymer blends of poly(vinylidene fluoride) (PVDF) and poly(methyl methacrylate) (PMMA) can be used as suitable model systems for investigating the relationship between the physico-chemical structure of polymers and their piezo- and pyroelectric activity. The structure of PVDF/PMMA blends can be varied over a very wide range which can lead to a strong influence on the piezo- and pyroelectric activity and the corresponding coefficients d₃₁ and g₃. The values of d₃₁ and g₃ were found to vary over nearly five decades whereas the normalized coefficients $\text{d}{}_{31}\text{P}$ and $\text{g}{}_3\text{P}$ remain largely unaffected. This emphasizes the importance of the molecular processes causing the macroscopic polarization P during the poling procedure. For a given polarization P and a given temperature T the properties of the polymer matrix, however, are far less important for the values obtained for d₃₁ and g₃. The experimental results were compared with theoretical predictions based on models which were recently developed by Tashiro et al., Broadhurst et al. and by Mopsik et al.. Considering the appropriate scope of each model a good agreement between theory and experiment is observed and general contradictions have not been found.     

改进分区蚁群算法在Ad Hoc网络路由中的应用

本文针对当前AdHoc网络路由的特点,在AdHoc路由优化算法基础上提出一种改进的蚁群算法。该算法首先将影响蚁群算法性能的参数作为遗传算法中的染色体,通过迭代找出最优的参数组合,然后对区域节点采用动态邻域分解的同时进行并行优化计算,最后将各子区域进行邻域全局连接得到最优解,该算法体现＂分而治之＂的思想。实验仿真结果表明,改进算法有效地提高了网络传输性能和通信效率,在性能上较基本蚁群算法有更大的优势。     

基于Zigbee网络的路由算法研究

本文针对基于Zigbee网络的路由算法进行相关研究,并分析其优缺点。     

汕头市城市定位与可持续发展战略研究

城市定位就是对城市未来发展方向和发展目标的拟定,是城市规划建设的重要组成部分.文章在对城市定位的涵义理解和城市发展战略思考的基础上,分析了城市定位与城市发展战略的互动机制,提出了汕头市新时期的城市定位.同时,提出并详细探讨了基于城市定位的汕头市可持续发展战略构想.     

基于工作过程的《异步电动机运行与维护》课程改革与实践

本文按照基于工作过程的系统化课程开发方法,对《异步电动机运行与维护》课程进行了教学设计。文中系统提出了该课程的构建方法、学习情境、学习内容、实施方案和考评方法等,简要分析了改革试点实践的初步成效与不足。     

Orientation of Bi<Subscript>3.2</Subscript>La<Subscript>0.8</Subscript>Ti<Subscript>3</Subscript>O<Subscript>12</Subscript> ferroelectric thin films with different annealing schedules

Fatigue-free Bi_3.2La_0.8Ti₃O₁₂ ferroelectric thin films were successfully prepared on p-Si (100) substrates using metalorganic solution deposition process. The orientation and formation of 5-layers thin films were studied under different processing conditions using XRD. Experimental results indicate that increase in annealing time at 700 °C after preannealing for 10 min at 400 °C can remarkably increase (200)-orientation of the films derived from the precursor solutions with two contents of citric acid. Meanwhile, high content of citric acid increases the film thickness and is conducive to the a-orientation of the films with the preannealing, and low concentration of the solution is conducive to the c-orientation of the films without the preannealing.     

无线mesh网络的分析与研究

介绍了无线 mesh网络(WMN)的结构、特点和应用,分析了无线mesh网络物理层、MAC层协议、路由协议、传输层协议和应用层协议的关键技术及国内外研究现状,介绍了跨层设计的一般原则和方法,最后展望WMN的发展和研究方向.     

再论高职人才培养目标之定位

高职教育培养的是一线的技术应用性人才,即技能熟练的技术人才、运用技术的高技能人才。从服务区域经济发展、特色产业发展、工业化和现代化发展进程等方面看高职人才培养目标定位,可以而且应该是一柱多棱的。高职人才培养目标定位的实现路径,在于实践动手能力的系统和可持续发展能力的基础知识系统的构建。