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31.
Based upon a new conception that the solid compressive pressure on a cake surface is not null, almost of all solid-liquid
separation operations have been re-examined. For cake filtration, the phenomenon caused by the solid compressive pressure
on a cake surface is discussed for thin cake. New expression and hindered sed-imentation theories are developed by above new
conception using Darcy’s equation. Application of the new conception to centrifugal filtration and tangential filtration is
also discussed. Above results lead to the conclusion that cake filtration, expression, hindered sedimentation, centrifugal
filtration and tangential filtration can be described with a unified theory, and the main difference between the operations
is only the boundary condition of cake. 相似文献
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Novel polypyrrole (PPy)/polydimethylsiloxane (PDMS) composite membrane was prepared by interfacial polymerization to make a very effective gas separation membrane. We found that Polymerized PPy films as thin as ~200 nm could be chemically synthesized as freestanding membranes by using the interfacial polymerization technique. Additionally, we show that difference morphology of PPys films was obtained by controlling polymerization rate and more dense films were formed at low polymerization rate. Wide X-ray diffraction study showed the d spacing value of the PPy film decreased from 4.89 å to 3.67 å by the rate of polymerization decreases. According to d spacing value decrease, selectivity of a PPy composite membrane was increased dramatically and permeability was reduced gradually. This high selectivity was derived from d spacing closed to the kinetic diameter of nitrogen. These results indicated that the permeability is controlled by the diffusion coefficient, reflecting the packed structure of the PPy film. The highest selectivity value of composite membrane that was prepared by interfacial polymerization was O2/N2=17.2 and permeability for O2 was 40.2 barrer. 相似文献
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基于分级型模数转换器AD7884对分离脱落电连接器的分离力进行测量,采用8位单片机W77E58与之接口,进行数据处理并通过485串口传输到上位机。实现了对分离脱落电连接器的分离力进行测量,系统运行稳定,且与上位机数据交互简单、可靠。 相似文献
37.
研究一类不完全转移率信息的Markov跳变奇异系统的H∞控制问题,提出连续Markov跳变奇异系统的新型有界实引理,并将其推广到不完全转移率条件.进一步设计H∞状态反馈控制器,使得闭环系统在转移率部分未知的条件下随机可容许,且满足H∞性能H.所得结论涵盖了奇异矩阵模态依赖情形,且表示为严格线性矩阵不等式形式,利于工程实现.最后,通过仿真算例表明了所提出方法的有效性和优越性. 相似文献
38.
A new and effective liquid membrane process to achieve both separation and enrichment simultaneously of weak organic acids or bases was developed. The process utilizes effectively the difference in the apparent partition coefficient of the constituent species between the aqueous and organic phases, and uses the change of the apparent partition coefficients with the hydrogen ion concentration of the aqueous phase. For such a fundamental model apparatus as a diaphragm diffusion cell being operated batch wise, the effects of pK value of solutes, permeability of solutes through the membrane, volume ratio of liquids in two aqueous phases, and pH value of aqueous phase on enrichment factor and selectivity for the solute to be concentrated were discussed analytically. Separation and enrichment were demonstrated using aqueous mixed solutions of fumaric acid and L-malic acid. The results were in good agreement with the theoretical predictions. 相似文献
39.
Yong?An?Jung Du?Young?Choi Seung?Bum?Hong Kyung?Ho?RowEmail author 《Korean Journal of Chemical Engineering》2003,20(4):705-708
Reversed-phase high-performance liquid chromatography was successfully developed for the simultaneous and rapid separation for the main whey proteins, α-Lactalbumin and β-Lactoglobulin. This method consisted of a linear gradient of the two mobile phases of 0.1% trifluoroacetic acid in water and 0.1% trifluoroacetic acid in acetonitrile. The total run time for this separation was approximately 30 min, and α-Lactalbumin was eluted followed byβ- Lactoglobulin. The injection volume was fixed at 20 μl and the flow rate was 1 ml 1/min. The optimum mobile phase composition and gradient conditions to separate α-Lactalbumin and β-Lactoglobulin (A+B) were experimentally obtained at the 15 μm particle with a pore size of 300 Å on the linear-gradient mode. 相似文献
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