甲基丙烯酸三氟乙酰氧乙酯的聚合

对甲基丙烯酸三氟乙酰氧乙酯(TFAOEMA)的阴离子聚合及原予转移自由基聚合进行了研究。常用的阴离于引发剂如丁基锂、1，1-二苯基已基锂等很难引发TFAOEMA的阴离子聚合，而碱性较弱的引发剂如三乙基铝却容易引发，且产率较高。以氯化亚铜、五甲基二乙基三胺、溴代丙酸乙酯为引发体系的TFAOEMA的本体原子转移自由基聚合符合活性聚合特征。但在四氢呋喃为溶剂的原子转移自由基聚合中却存在活性中心失活现象。以末端含卤素的聚甲基丙烯酸甲酯为大分子引发剂，引发TFAOEMA的原子转移自由基聚合，得到了含氟双嵌段聚合物。     

Influence of the Transport Properties of the Crystal/Heat Transfer Surface Interfacial on Fouling Behavior

One method to reduce fouling is to extend the induction time by a defined modification of the interfacial interactions between the heat transfer surface and the crystalline deposit. Since these interactions are a result of both molecular and mechanical forces, two approaches for fouling mitigation have been developed: (a) Modification of the energy related properties of the heat transfer surface and (b) Modification of the geometry related properties of the heat transfer surface.     

Significance of fluid regime in biological filtration

A dispersed flow model previously developed to study substrate utilization in unsaturated media was experimentally verified and its practical application was considered. For this purpose, measurements were made using tap water and a synthetic feed solution. The importance of the change in fluid regime as regards to the simultaneous transport and reaction within biological filters were demonstrated. The effect of drop formation and the breakage of liquid jets inside the filters on substrate utilization was also shown.     

Temperature Oscillation Calorimetry: Robustness analysis of different algorithms for the evaluation of the heat transfer coefficient

Applicability of different temperature oscillation calorimetry algorithms, previously proposed in the literature, for the evaluation of the heat transfer coefficient during the course of the reaction, is analysed by referring to the experimental data from a methyl methacrylate polymerisation reactor.Results are coincident in the nominal case (no errors on data), while differences appear in the elaboration of real data. The effect of uncertainty in the experimental data has been simulated in terms of error on the amplitude and on the phase of reactor and jacket temperature profiles.This approach allows to indicate algorithms having the best robustness properties and to give an explanation of phase errors in terms of a lumped parameter which accounts for different phenomena, not included in the basic hypotheses of the method. Based on this observation, a procedure to eliminate this source of errors from experimental data is proposed for the more general algorithm presented to handle oscillating temperature profiles generated by different techniques.     

Transient operation of a catalytic liquid-liquid plug flow reactor for kinetics measurements

A centrifugal partition chromatograph (CPC) was used as a liquid-liquid catalytic reactor for the isomerisation of hexen-3-ol into ethylpropylketone with a water soluble rhodium catalyst. Global mass transfer coefficients were measured and shown to depend on both the nature of the solute and the flow rate. Liquid-liquid partition isotherms were also determined with the CPC using elution chromatography. Finally, a reactor model was derived to account for the experimental results obtained both under stationary and transient (pulse) conditions. A parameter sensitivity evaluation is also presented.     

生物超微弱发光的光子计数成象方法

介绍了我们研制和设计的用于测量生物超微弱发光的光子计数成象系统，包括光子成象头，高帧频ＣＣＤ摄象机，图象采集系统和计算机，可以定量地探测出生物的发光强度分布 ，还能够显示出其发光的图象，确定发光的形状和位置，本系统的信噪比为１０：１，最小探测功率达１０＾－１６Ｗ，灵敏度高，动态范围大。     

CROSS-SPECTRAL MOMENT AND SVD METHODS ESTIMATING THE PARAMETERS OF CLOSE SINUSOIDS IN COLORED NOISE

The cross-spectral estimation methods are efficient in estimating the parameters of sinusoidal signals embedded in colored noise. But up to now, only FPT and cross-periodogram methods are used in this field, the modern auto-spectral estimation method is introduced into cross-spectral estimation in this paper, meanwhile the cross-correlation based Yule-Walker equation is proposed theoretically and the moment and singular-value decomposition (SVD)) algorithms for cross-spectral estimation have been developed. Finally, a numerical example is given for comparing the presented methods with the well-known Cadzow's SVD method.     

A bench-scale study on biodegradation and volatilization of ethylbenzoate in aquifers

Experiments were conducted to investigate the fate of ethylbenzoate and soil microorganisms in shallow aquifers. Biodegradation and volatilization have been identified as the major mechanisms in attenuating ethylbenzoate in contaminated soils. The rate of volatilization was experimentally found to be limited by gas-phase diffusion. The parameters of an available model, i.e., the maximum specific growth rate and the saturation constant, have been estimated by fitting the model to the experimental data obtained with ethylbenzoate as the carbon source; the former was 0.49 h⁻¹, and the latter was 62 mg L⁻¹. Various facets of biodegradation, including the effects of mass-transfer resistance and initial distribution of microorganisms, have been numerically analyzed on the basis of the model.     

基于i860的存储器子系统设计

微处理机系统中的存储器子系统设计对整个系统性能的高低有重要的影响，尤其当微处理器的主频越来越高时。本文结合实际例子，给出了一个基于ｉ８６０处理器（４０ＭＨｚ）的主存设计方案，讨论了实际中需仔细考虑的因素。该设计可为其它高性能ＲＩＳＣ系统设计提供参考。