Electrochemical and analytical study of corrosion inhibition on carbon steel in HCl medium by 1,12-bis(1,2,4-triazolyl)dodecane

1,12-bis(1,2,4-triazolyl)dodecane (dTC12) is an excellent corrosion inhibitor for carbon steel in deaerated 1 M HCl solution. In this work electrochemical and analytical techniques were used to study the inhibition of corrosion on carbon steel in acidic medium. The carbon steel corrosion inhibition of dTC12 was attributed to the synergistic effect between chloride anion and quaternary ammonium ion. The protective efficiency of the film was higher than 90%, indicating that corrosion of carbon steel in 1 M HCl is reduced by dTC12.The effect of dissolved oxygen on the inhibition efficiency was also investigated. The results show that the inhibition efficiency increases in early stage and decreases for a long immersion time.     

Filiform corrosion attack on pretreated aluminum alloy with tailored surface of epoxy coating

In the study, on the basis of material analysis of 6016 aluminum alloy widely used in Europe automotive industry, the influences of surface pretreatment on filiform corrosion and adhesion of epoxy coating/aluminum alloy interface were investigated, and the effect of rolling direction and coating property on filiform corrosion was also examined. The alloy surfaces were pretreated with etching solution, and then, respectively, with Aminopropyl silane solution, Aminopropyl phosphonate solution, and hexamethyldisiloxane plasma.The results showed that the susceptibility of pretreated surface to filiform corrosion was basically consistent with the distribution of intermetallic particles, and that water permeation and the tensility of coating were necessary for filament to grow. HMDSO plasma pretreatment could not only efficiently cover the matrix of 6016 aluminum alloy and cathodic intermetallic particles containing Al, Si, Mn, and Fe, but also apparently promote the adhesion of epoxy coating/aluminum alloy, as a result, the specimens with plasma pretreatment exhibited the superior performance in the filiform corrosion and peeling tests, so it was suitable to apply for the pretreatment of aluminum alloy in automotive industry.     

TEMPERATURE DEPENDENCE UPON VISCOSITY OF Ni-P ALLOY ON AMORPHOUS FORMATION

The viscous flow of amorphous alloys near T_gis closely related to the viscosity of liquid alloys.On the basis of the measured surface tension and density for Ni-P binary alloys,the correla-tion between the viscosity of the melt and viscous flow process of the amorphous alloy is inves-tigated.The relationship between viscosity and temperature for Ni-P alloys going from liquidto amorphous solid may be described by the following formula:     

Thermodynamic study of the phase equilibria in the Sn−Ti−Zn ternary system

The Sn−Ti−Zn ternary phase diagram has been constructed using the CALPHAD technique. The Ti−Zn binary system phase boundaries were determined using differential scanning calorimetry and the solid-liquid diffusion couples method. In addition, the formation energy of some stoichiometric compounds was obtained using first-principle band energy calculations. For the ternary system, some alloys were prepared by equilibration at 600 or 700 °C, and the compositions of the precipitates were analyzed using electron probe microanalysis. Thermodynamic assessment of the Ti−Zn and Sn−Ti−Zn systems was performed based on the experimental information and by adopting reported values of the thermodynamic properties of the Sn−Zn and Sn−Ti binary systems. Microstructural observation showed that Sn₃Ti₅Zn₁₂ exists in the ternary system. Seven types of invariant reaction on the Sn-rich liquidus surface of the ternary system are predicted by the phase diagram calculations. The ternary eutectic point falls at 0,0009 mass% Ti and 8.69 mass% Zn, at T=192.40°C, which is slightly lower than the calculated eutectic point of Sn−Zn binary alloy (T=192.41°C). Based on these results, a nonequilibrium solidification process using the Scheil model was simulated. This paper was presented at the International Symposium on User Aspects of Phase Diagrams, Materials Solutions Conference and Exposition, Columbus, Ohio, 18–20 October, 2004.     

8098单片机在轧机控制系统中的应用

在轧机速度控制和张力控制中采用8098单片机控制系统，使其速度控制精度和张力控制精度得到明显提高；系统还具有运行可靠、调试与维护方便、组成系统成本低等优点。     

单,双向拉伸各性能指标间的相关性研究

采用９种板料进行了单拉及液压胀形（双向拉伸）试验，分别研究了双向拉伸各性能指标间及单、双向伸各性能指标间的相关关系，得到了一系列有意义的结果。     

表面工程在装备延寿中的开发应用

在我军装备延寿中开发应用各种表面工程新技术、新工艺、新材料，不仅可以修复大量的装备零部件，而且能有效提高装备的防腐性、耐磨性、可靠性，延长装备使用寿命，降低修理费用，减少修理时间．从而提高装备完好率和战斗力。     

全军表面工程推广网表面技术应用实例

本文根据96年各表面工程推广站技术工作总结中反映的情况，整理出各站在主要表面技术：电刷镀、热喷涂和粘接粘涂方面的应用实例．反映建站以来各站在装备维修中推广应用表面工程技术的实际状况和取得的主要成绩。     

材料表面可控修饰新技术

聚合物"刷"是端接枝超薄聚合物层的形象描述,在材料表面形成聚合物"刷"是控制材料表面性质的一种有效手段.因其在材料表面结构分子设计中具有突出的优越性,近年引起了材料表面改性专家的广泛关注.介绍了表面引发可控/"活性"聚合制备可控聚合物"刷"技术,并展示了其在材料表面可控修饰中的应用.     

Effect of temperature on mechanical behavior of AZ31 magnesium alloy

Strain rate sensitivity and tension/compression asymmetry of AZ31 magnesium alloy at different temperatures and strainrates were investigated.Both of mechanical behaviors are temperature dependent.Strain rate sensitivity increases with increasingtemperature.Thermally activated slip is the source of strain rate sensitivity.At the temperature below or near 373 K,strain ratesensitivity is very little.Tension/compression asymmetry in yielding decreases with increasing temperature.Twinning is the reasonof tension/compression asymmetry.At the temperature above or near 573 K,the material shows little tension/compressionasymmetry of the flow stress.