Hydrolytic stability and protective properties of polyurethane oligomers based on polyester/ether/polyols

The present study deals with effect of the type and chemical character of incorporated polyester/polyether blocks on the hydrolytic stability of crosslinked polyurethane oligomers. Diffusion parameters of the investigated polyurethane oligomers, giving information concerning chemical changes taking place in neutral, basic and acidic aqueous environments, have also been determined.     

On the improvement of detection characteristics of trans-stilbene crystals by improving crystal perfection

Organic molecular scintillating crystals are noted for their good timing and particle discrimination process. Trans-stilbene is one such candidate noted for its good particle detection characteristics for the past five decades. Progressive strengthening of detection characteristics of trans-stilbene has been attempted by improving crystal perfection. A series of timing resolution studies have been carried out for the Bridgman grown trans-stilbene crystals under different experimental conditions. The results were compared with the previously reported values. Pulse shape discrimination process has been carried out for ²⁴¹Am and ²⁵²Cf sources and good discrimination has been obtained for gamma-alpha and gamma-neutron sources from the grown organic phosphor crystal. Electronic Publication     

从头算法对甲基磺酸拉曼光谱振动频率指认

对液态的甲基磺酸进行了拉曼光谱测定。采取从头算法用各种不同的基组 (最大的基组为MP2 / 6 -311+G( 2d ,2 p) )对甲基磺酸的结构和光谱进行了计算 ,得到了甲基磺酸的结构参数及稳定构象信息。采用一个具有Ci 对称的二聚体模型解释了甲基磺酸的液态光谱。对单体和二聚体的甲基磺酸进行了简正坐标计算 ,结果表明二聚体结构是液态甲基磺酸聚积态分子的合理模型。     

On using peak amplitude and rise time for AE source characterization

Acoustic Emission (AE) signals, which are electrical version of acoustic emissions, are usually analysed using a set of signal parameters. The major objective of signal analysis is to study the characteristics of the sources of emissions. Peak amplitude(P _a ) and rise time(R _t ) are two such parameters used for source characterization. In this paper, we theoretically investigate the efficiency ofP _a andR _t to classify and characterize AE sources by modelling the input stress pulse and transducer. Analytical expressions obtained forP _a andR _t clearly indicate their use and efficiency for source characterization. It is believed that these results may be of use to investigators in areas like control systems and signal processing also     

A time aggregation approach to Markov decision processes

We propose a time aggregation approach for the solution of infinite horizon average cost Markov decision processes via policy iteration. In this approach, policy update is only carried out when the process visits a subset of the state space. As in state aggregation, this approach leads to a reduced state space, which may lead to a substantial reduction in computational and storage requirements, especially for problems with certain structural properties. However, in contrast to state aggregation, which generally results in an approximate model due to the loss of Markov property, time aggregation suffers no loss of accuracy, because the Markov property is preserved. Single sample path-based estimation algorithms are developed that allow the time aggregation approach to be implemented on-line for practical systems. Some numerical and simulation examples are presented to illustrate the ideas and potential computational savings.     

电转化法转化钝顶螺旋藻转化条件的研究

确定了电转化法转化钝项螺旋藻S6-4的转化条件。无论受体是藻丝还是单细胞／藻丝段，钝项螺旋藻S6-4在对数生长期内，半致死电场强度无显著差别。实验表明以对数中期的螺旋藻用于转化为宜。当脉冲时间是5．0ms时，藻丝受体和单细胞／藻丝段受体的半致死电场强度分别是3．75—5．0kV／cm和3．1—4．4kV／cm，而电击缓冲液分别是1．0mmol／L HEPES(pH7．5)缓冲液和含有0．5mol／L蔗糖的1．0mmol／L HEP—ES(pH7．5)缓冲液。本文的研究结果为螺旋藻转化及外源基因表达提供了实验基础。     

提高储层预测精度技术思路与对策

采用地质、地震、测井人员协同一体化作业，对地下地质目标进行综合预测与评价，可提高储层预测精度，降低预测结果的多解性。主要方法是针对不同的区块，采用不同的方法和对策，首先从单井储层划分对比入手，建立储层沉积模式，同时对地震数据目的层段进行精细解释，建立地层构造模式，用沉积、构造等地质规律来指导和约束反演；利用测井资料对地震资料进行精细标定，建立各井的单井波阻抗模型，建立井数据和地震数据沟通的桥梁；在严格的测井约束、地质模型约束、层位控制下进行储层反演；充分利用地质、地震反演结果、地震参数提取及分析结果、测井、测试和分析化验等资料对储层预测结果进行综合分析与评价。该方法应用于长庆、大庆、准噶尔等实际区块，取得了较好的效果。     

Calorimetric determination of the enthalpy change for the binding of methyl orange to poly(vinylpyrrolidone) in aqueous solution

Thermodynamic parameters have been determined for the interaction of methyl orange and poly(vinylpyrrolidone) in aqueous solutions containing tris, tris and hydrochloric acid, or water only. Enthalpy changes were determined by use of a flow microcalorimeter. Free energy changes were calculated from the results of equilbrium dialysis studies. The results are interpreted in terms of the behaviour of poly(vinylpyrrolidone) in these systems. Analysis of data shows that the hydrophobic interactions in the systems are in the order: tris > wateronly > tris-HC1.     

A study on time schemes for DRBEM analysis of elastic impact wave

 The precise integration and differential quadrature methods are two new unconditionally stable numerical schemes to approximate time derivative with more than the second order accuracy. Recent studies showed that compared with the Houbolt and Newmark methods, they produced more accurate solutions with large time step for the problems where response is primarily dominated by low and intermediate frequency modes. This paper aims to investigate these time schemes in the context of the dual reciprocity BEM (DRBEM) formulation of various shock-excited scalar elastic wave problems, where high modes have important affect on traction response. The Houbolt method was widely recommended in many literatures for such DRBEM dynamic formulations. However, this study found that the damped Newmark algorithm was the most efficient and accurate for impact traction analysis in conjunction with the DRBEM. The precise integration and differential quadrature methods are shown inapplicable for such shock-excited problems due to the absence of numerical damping. On the other hand, we also found that to achieve the same order of accuracy, the differential quadrature method required much less computing effort than the precise integration method due to the use of the Bartels–Stewart algorithm solving the resulting Lyapunov matrix analogization equation. Received 6 November 2000     

舞钢扁钢锭咬边参数的确定

本文根据我公司自产的11.7t及13.34t扁钢锭在4200mm轧机生产过程中,运用正交试验方法,合理应用咬边参数的轧制方案,以此降低金属消耗。此方案使“咬入返回轧制”及“留尾轧制”新技术进一步得到完善,板形更加矩形,使锭一材成材率提高2％左右。