Transit smart card data mining for passenger origin information extraction

The automated fare collection(AFC) system,also known as the transit smart card(SC) system,has gained more and more popularity among transit agencies worldwide.Compared with the conventional manual fare collection system,an AFC system has its inherent advantages in low labor cost and high efficiency for fare collection and transaction data archival.Although it is possible to collect highly valuable data from transit SC transactions,substantial efforts and methodologies are needed for extracting such data because most AFC systems are not initially designed for data collection.This is true especially for the Beijing AFC system,where a passenger’s boarding stop(origin) on a flat-rate bus is not recorded on the check-in scan.To extract passengers’ origin data from recorded SC transaction information,a Markov chain based Bayesian decision tree algorithm is developed in this study.Using the time invariance property of the Markov chain,the algorithm is further optimized and simplified to have a linear computational complexity.This algorithm is verified with transit vehicles equipped with global positioning system(GPS) data loggers.Our verification results demonstrated that the proposed algorithm is effective in extracting transit passengers’ origin information from SC transactions with a relatively high accuracy.Such transit origin data are highly valuable for transit system planning and route optimization.     

基于水印技术的数字作品版权保护系统

本文基于数字水印技术提出了一种网络多媒体作品的注册和侵权收集机制,可以实现包括图像、视频和音频等网络作品的注册和非授权复制和传播行为的信息收集等功能。该机制对网络多媒体作品的版权保护具有一定的实用价值。     

基于智能垃圾桶的垃圾分类动态收运路径优化问题研究

针对城市生活垃圾分类收运过程中存在的环境二次污染和垃圾产生量不确定性等问题,提出了一种基于智能垃圾桶的动态收运车辆路径优化方法。建立以最小化碳排放成本、燃油消耗成本、固定成本和车辆延迟到达惩罚成本为目标的动态车辆路径优化模型。采用滚动时域的方式将动态问题转换为一系列静态问题,并设计两阶段算法进行求解。首先采用粒子群算法对收运车辆路径进行规划,而后在每个时域末,综合考虑待清运垃圾桶的位置和垃圾量、垃圾收运车辆的位置和装载量以动态调整现有车辆路径。研究结果表明,相较于传统的静态收运方案,动态垃圾收运方案能够在降低车辆运输成本和碳排放成本的同时,显著降低由于清运不及时造成的环境二次污染的风险。     

中医正骨复位手法信息采集系统的设计

研究中医正骨复位手法,建立虚拟信息系统,但是由于手法的使用形式繁多,实施操作方法经验性强,对操作的技巧性和力度大小要求非常高等原因,使得正骨技术在临床中的应用不易推广,影响着中医正骨复位手法的的继承和发扬。针对上述原因,提出构建虚拟正骨手法复位信息采集系统,通过LabVIEW软件、角度传感器,信息采集卡等硬件设施有机的结合,把抽象的中医骨伤手法复位操作技术用角度、位移参数值具体、直观的表示出来,并以波形图表的形式显示。为初学者认识和学习正骨手法提供了生动形象的教材,改进了传统的教学模式、教学手段和教学方法,进一步促进虚拟技术在中医正骨中的应用。     

从废旧锌锰电池中回收锌和锰的工艺研究

废旧锌锰干电池经过剖开、焙烧处理，去除汞和碳粉，再用硫酸浸取，滤液采用沉淀法分离锌和锰。锌和锰的回收率分别为94．5％和93．6％。     

Sulfamic acid functionalized slag for effective removal of organic dye and toxic metal from the aqueous samples

Surface functionalization of blast furnace slag with sulfamic acid(a zwitterion) was performed for the removal of Cr~(3+) and methylene blue dye(MB) from water samples. The slag functionalization process was optimized using Response Surface Methodology Design. Statistical analysis of the parameters that include the sulfamic acid amount(A), reaction time(B), and temperature(C) revealed that(A) increase had a negative effect on the adsorption of both pollutants by the zwitterion slag, whereas(B) and(C)increase presented a positive impact. At the optimum condition of 2 g sulfamic acid amount, 50 min reaction time and 37 °C temperature, the prepared slag showed a removal efficiency of more than 90% for both Cr~(3+) and MB. Surface characterization by SEM/EDS, FTIR, XPS and surface area analyser, showed an improvement in surface properties and the incorporation of zwitterionic NH_2~+ and S@O groups of sulfamic acid. Adsorption isotherm and kinetic studies conducted with the zwitterion slag showed the adsorption process was suited to Freundlich isotherm model and pseudo-second-order kinetic model.The thermodynamic study conducted revealed the spontaneity of the process based on the calculated negative DG(Gibb's free energy) values. The prepared zwitterion slag offered easy regeneration with dilute HCl solution and showed a considerable removal(Cr3+: 65% and MB: 80%) for both pollutants even after 3 cycles of usage.     

Optimization and evaluation of reduced graphene oxide hydrogel composite as a demulsifier for heavy crude oil-in-water emulsion

The rising production of produced water from oilfields had been proven to bring detrimental environmental effects. In this study, an efficient, recyclable, and environmental-friendly reduced graphene oxide immobilized κ-Carrageenan hydrogel composite(κCa GO) was fabricated as an alternative sorbent for crude oil-in-water demulsification. Polyethyleneimine(PEI) was employed to form a stable hydrogel composite. The conditions for the immobilization of graphene oxide(GO) on PEI-modified κ-Carrageenan(κC) beads were optimized appropriately. An immobilization yield of 77% was attained at 2% PEI, 2 h immobilization activation time, and p H6.5. Moreover, the synthesized κCa GO is capable of demulsification with an average demulsification efficiency of 70%. It was found that the demulsification efficiency increases with salinity and κCa GO dosage, and it deteriorates under alkaline condition. These phenomena can be attributed to the interfacial interactions between κCa GO and the emulsion. Furthermore, the κCa GO can be recycled to use for up to six cycles without significant leaching and degradation. As such, the synthesized κCa GO could be further developed as a potential sorbent substitute for the separation of crude oil from produced water.     

In-depth investigation on the factors affecting the performance of high oil-absorption resin by response surface method

A series of high oil-absorption resins with low cross-linking degree were synthesized by suspension polymerization using stearyl methacrylate(SMA), 2-Ethylhexyl methacrylate(EHMA), and styrene(St) as monomers.Response surface methodology(RSM) with central composite design(CCD) was also applied to determine the optimal parameters that are mainly known to affect their synthesis. Thus, the effects of the monomer mass ratio(EHMA:SMA), the rigid monomer(St) dosage, the porous agent(acetone) dosage, and their pairwise interaction on the resin's oil-absorption capacity were analyzed, highlighting PSES-R_2 as the resin with the optimum performance. The pure oil-absorption rates of PSES-R2 for gasoline, diesel, and kerosene were 11.19 g·g~(-1),16.25 g·g~(-1), and 14.84 g·g~(-1), respectively, while the oil removal rates from oily wastewater were 98.82%,65.11%, and 99.63%, respectively.     

Effect of supports on the redox performance of pyrite cinder in chemical looping combustion

Chemical looping combustion (CLC) is a clean and efficient flame-free combustion technology,which combust the fuels by lattice oxygen from a solid oxygen carrier with inherent CO2 capture.The develop-ment of oxygen carriers with low cost and high redox performance is crucial to the whole efficiency of CLC process.As the solid by-product from the sulfuric acid production,pyrite cinder presented excellent redox performance as an oxygen carrier in CLC process.The main components in pyrite cinder are Fe2O3,CaSO4,Al2O3 and SiO2 in which Fe2O3 is the active component to provide lattice oxygen.In order to sys-tematic investigate the functions of supports (CaSO4,Al2O3 and SiO2) in pyrite cinder,three oxygen car-riers (Fe2O3-CaSO4,Fe2O3-Al2O3 and Fe2O3-SiO2) were prepared and evaluated in this study.The results showed that Fe2O3-CaSO4 displayed high redox activity and cycling stability in the multiple redox cycles.However,both Fe2O3-Al2O3 and Fe2O3-SiO2 experienced serious deactivation during redox reactions.It indicated that the inert Fe-Si solid solution (Fe2SiO4) was formed in the spent Fe2O3-SiO2 sample,which decreased the oxygen carrying capacity of this sample.The XPS results showed that the oxygen species on the surface of Fe2O3-CaSO4 could be fully recovered after the 20 redox cycles.It can be concluded that CaSO4 is the key to the high redox activity and cycling stability of pyrite cinder.     

Stability of protective oxide films in waste incineration environment—solubility measurement of oxides in molten chlorides

Solubility measurements of several oxides in molten NaCl-KCl and NaCl-KCl-Na₂SO₄-K₂SO₄ were conducted in three different levels of basicity. The dissolution behavior of the oxides showed almost the same tendency as that shown by the dissolution behavior of the oxides in molten Na₂SO₄ in literature. In a waste incineration environment, a protective Cr₂O₃ film easily dissolves in molten chlorides as CrO₄²⁻ because pO²⁻ of the molten chlorides tends to have a small value due to the effect of water vapor contained in the combustion gas. From the result of the solubility measurement, the addition of molybdenum and/or silicon was expected to improve the corrosion resistance of alloys. Laboratory corrosion tests confirmed this expectation. However, the scale analysis suggested that the effect of molybdenum could not be explained completely by only the mechanism derived from the result of the solubility measurement.