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991.
Guanghui Wang Lei Huang Rong Yu Nansheng Deng 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》2008,83(5):601-608
BACKGROUND: Endocrine disruptors in the aquatic environment and their potential adverse effects are currently issues of concern. One of these endocrine disruptors is 2,2‐bis(4‐hydroxy‐3‐methylphenyl)propane (BPP). In this work the molecular recognition interaction of BPP with β‐cyclodextrin (β‐CD) was studied using IR spectroscopy and steady state fluorescence spectroscopy, and the photocatalytic degradation behaviour of BPP based on molecular recognition interaction was investigated in a TiO2/UV–visible (λmax = 365 nm) system. This might provide a new method for the treatment of some organic pollutants in wastewater. RESULTS: β‐CD reacts with BPP to form a 1:1 inclusion complex, the formation constant of which is 4.94 × 103 L mol?1. The photodegradation rate constant of BPP after molecular recognition by β‐CD showed a 1.42‐fold increase in the TiO2/UV–visible (λmax = 365 nm) system. The photodegradation of BPP depended on the concentration of β‐CD, the pH value, the gaseous medium and the initial concentration of BPP. The photodegradation efficiency of BPP with molecular recognition was higher than that without molecular recognition. After 100 min of irradiation the mineralisation efficiency of BPP after molecular recognition by β‐CD reached 94.8%, whereas the mineralisation efficiency of BPP before molecular recognition by β‐CD was only 40.6%. CONCLUSION: The photocatalytic degradation of BPP after molecular recognition by β‐CD can be enhanced in the TiO2/UV‐visible (λmax = 365 nm) system. This enhancement is dependent on the enhancement of the adsorption of BPP, the moderate inclusion depth of BPP in the β‐CD cavity and the increase in the frontier electron density of BPP after molecular recognition. Copyright © 2008 Society of Chemical Industry 相似文献
992.
Levels of aluminium in 82 different infant formulae from nine different manufacturers in Spain were determined by acid-microwave digestion and graphite furnace atomic absorption spectrophotometry. The influence of aluminium content in tap water in reconstituted powder formulae was examined and an estimate was made of the theoretical toxic aluminium intake in comparison with the provisional tolerable weekly intake (PTWI). Possible interactions between aluminium and certain essential trace elements added to infant formulations have been studied according to the type or main protein-based infant formula. In general, the infant formulae contained a higher aluminium content than that found in human milk, especially in the case of soya, preterm or hydrolysed casein-based formulae. Standard formulae gave lower aluminium intakes amounting to about 4% PTWI. Specialized and preterm formulae resulted in a moderate intake (11-12 and 8-10% PTWI, respectively) and soya formulae contributed the highest intake (15% PTWI). Aluminium exposure from drinking water used for powder formula reconstitution was not considered a potential risk. In accordance with the present state of knowledge about aluminium toxicity, it seems prudent to call for continued efforts to standardize routine quality control and reduce aluminium levels in infant formula as well as to keep the aluminium concentration under 300 μg l-1 for all infant formulae, most specifically those formulae for premature and low birth neonates. 相似文献
993.
994.
N,N′-二(β-十八酰氧基)乙基乙二胺二乙酸钠的合成及性能研究 总被引:1,自引:1,他引:0
用 N,N′-二羟乙基乙二胺、氯乙酸钠合成了 N,N′-二羟乙基乙二胺二乙酸钠(中间体),中间体再与硬脂酰氯反应制备了一种新型 Gemini 两性表面活性剂 N,N′-二(β-十八酰氧基)乙基乙二胺二乙酸钠。对产物合成条件进行了考察,优化的反应条件为:n(硬脂酰氯):n(中间体)=2.5,溶剂 V(水):V(氯仿)=1:2,pH=9.0~10.0,反应温度15~20℃,反应时间5 h。通过红外光谱和质谱分析确定了产物结构,并测试了产物的表面性能。结果表明,在25℃时,该产物的临界胶束浓度为0.24 mmol/L,临界胶束浓度下的表面张力为35.7 mN/m;即时泡沫高度为250 mm,5 min 后泡沫高度为220 mm;乳化时间为22.48 min(甲苯-水物系)和4.65 min(正己烷-水物系),亲水-亲油平衡值为5.4,等电点为 pH 3.3~6.5。 相似文献
995.
Xinsheng Zhu Hansong Xu Jianmei Lu Juying Wang Shunhua Zhou 《Journal of Polymer Research》2008,15(4):295-300
Poly(ethylene terephthalate) (PET) is of excellent mechanical properties and melt processability and is widely used as raw
material for textile fibers. However, the flame retardant properties of PET were rather poor, and both reactive and additive
phosphorus- and halogen-containing compounds have been employed to enhance the reaction-to-fire properties while the meltdripping
behaviour during burning hasn’t been handled properly with the flame retardants. In this work, fluoropolymer was blended with
both pure PET (pPET) and reactive phosphorus-containing flame retarded copolyester (fPET), and the flame retardance and char
formation and mechanical properties of the resulted pPET and fPET blends were investigated. The tensile strengths of modified
pPET samples were worsen whereas those of modified fPET samples were improved at low concentrations. The initial thermal degradation
in nitrogen was accelerated remarkably for the two polyesters with fluoropolymer. The oxygen indices of the all modified samples
were reduced while char formation and meltdripping suppression were encouraged. The apparent melt viscosity and elasticity
for the two polyesters were gained much with antidripping agent. Therefore, fluoropolymer improved char formation of the two
polyesters based on the gaseous phase mechanism while the partial suppression of meltdripping behavior and the decrease of
mechanical properties mainly originated from the increase of melt viscosity via fibrillation for pPET. 相似文献
996.
997.
Tanja Kolli Katariina Rahkamaa-Tolonen Ulla Lassi Auli Savimki Riitta L. Keiski 《Catalysis Today》2005,100(3-4):303-307
In this study, Pd/Al2O3 and Pd/BaO/Al2O3 metallic monoliths were used to investigate the effect of BaO in C2H4 and CO oxidation as well as in NO reduction. A FT-IR gas analyser was used to study the activity of the catalysts. Several activity experiments carried out with dissimilar feedstreams revealed that BaO enhances CO and C2H4 oxidation as well as NO reduction reactions in rich conditions. This effect is due to BaO, which causes a decrease in the ethene poisoning of palladium. In lean conditions BaO is present in the form of Ba(OH)2 which reacts with oxidised NO releasing water. Therefore, NO was stored during the lean reaction. 相似文献
998.
999.
SDI接口数字监视设备的设计与实现 总被引:2,自引:0,他引:2
介绍了一种对SDV(串行数字视频)信号进行解码的设备设计方案,提出了该系统的总体构架,并对该系统的硬件设计、软件设计进行了全面的论述。设计的产品具有较高的性能价格比,已进入了推广阶段。 相似文献
1000.