基于小波变换的超声信号自适应消噪方法研究

超声检测中，特定的缺陷回波信号一般都有一定的相关性，因而可利用自适应噪声抵消来增强缺陷回波信号。针对最小均方（LMS）算法自适应噪声抵消的缺点，提出了基于小波变换的自适应噪声抵消方法，通过Matlab软件将该算法应用于超声缺陷信号的仿真处理。结果表明，该算法大大提高了缺陷回波信号的信噪比，且具有较高的缺陷定位精度和纵向分辨率。     

Premodification of Pt/γAl2O3 with Cinchonidine for the Enantioselective Hydrogenation of Ethyl Pyruvate: Effect of Premodification Conditions on Reaction Rate and Enantioselection

The premodification of a 5 wt% Pt/-Al₂O₃ catalyst with cinchonidine (0.01 and 0.2 g g^-1 _catalyst) is described and discussed. Premodification is carried out by treating the catalyst with a solution of cinchonidine followed by solvent removal. Catalysts premodified in this way give the same ee and initial rate of reaction for the enantioselective hydrogenation of ethyl pyruvate as those using the standard in situ modification procedure. Investigations of different solvents for premodification and reaction (dichloromethane, ethanol) show that it is the solvent used for the reaction that controls the observed enantioselection. Premodified catalysts also display the initial transient behavior typically observed with in situ modified catalysts in which the ee increases with conversion in the early part of the reaction. Premodified catalysts show an enhanced rate of reaction when ethanol is used as the reaction solvent compared with in situ modified catalysts under the same conditions. Premodification using aerobic conditions gives the best results and premodified catalysts can be stored prior to use for up to a week without loss of catalytic performance.     

华润贵港5000t/d燃无烟煤生产线预分解系统的设计与工程应用

分解炉是烧成系统的关键设备，尤其是对于燃无烟煤的分解炉，既要保证无烟煤粉在炉内的充分燃烧．又要利于系统的操作控制。基于分解炉煤粉燃烧机理，并通过分析影响炉内煤粉燃烧的各种因素及依据所用无烟煤的热失重分析结果，中材国际南京水泥设计研究院开发设计出了用于华润贵港5000砌工程的喷旋管道式在线分解炉，并与高效、低阻、防堵的旋风预热系统组成了性能优异的预分解系统。从实际运行情况看，该预分解系统易于操作控制，且对物料适应性强、阻力损耗小。     

Deformation Dynamics of a Reactive Medium During Gasless Combustion

Deformation during gasless combustion of 5Ti + 3Si and Ti + C samples was studied experimentally. The dynamics of motion of the material in a gasless combustion wave was studied using highspeed video recording (500 frames/sec) with a spatial resolution of the order of 10 m. It was shown that behind the combustion front, the medium was first expanded and then compressed. The dimensions of the expansion and compression zones were determined.     

Characterization of pressure signals in a bubble column by wavelet packet transform

All experiments of pressure fluctuations were carried out in a bubble column with a moderately large column of 0.376 m ID. The recently developed technique of wavelet packet transform based on localized wavelet functions is applicable to analysis of the fluctuating signals. The time series of pressure fluctuation signals have been analyzed by means of wavelet packet transform components, decomposition through best basis algorithm and timefrequency representation. By resorting to this technique, the objects in bubbly flow regime have fine scales and frequencies than ones in churn-turbulent flow regime. Thus, this wavelet packet transform method enables us to obtain the frequency content of local complex flow behaviors in a bubble column.     

In-situ monitoring of the stabilization with hydrogen of free radicals thermally induced from coal using high pressure e.s.r., d.t.a. and p.d.a. equipment

High temperature, high pressure e.s.r. measurements of the hydrogenation reaction of Taiheiyo coal in the presence of catalysts were carried out to understand the stabilization of thermally and/or catalytically induced free radicals. A decrease in free radical concentration with increasing temperature was observed for ZnCl₂ and SnCl₂ · 2H₂O catalysts at 10MPa under hydrogen gas. High pressure modified single-cell d.t.a. and p.d.a. equipment augmented the uniquely designed high temperature, high pressure e.s.r. cell. The hydrogenation reaction was monitored under the same experimental conditions as for e.s.r. From the results of the combination of high temperature, high pressure e.s.r. with high pressure d.t.a. and p.d.a., it was established that H₂ molecules can react efficiently with free radicals from coal molecules created by the presence of ZnCl₂ and SnCl₂ · 2H₂O catalysts.     

锡槽保护气体转子流量计的示值修正和量程选择及其在900 t/d工程中的应用

从转子流量计的流量检测原理出发,结合理想气体状态方程分析,阐述转子流量计在使用中的示值修正方法.为转子流量计的设计选型、使用中的示值修正提供参考.     

Dose and enantiospecific responses of white pine cone beetles,Conophthorus coniperda,to alpha-Pinene in an eastern white pine seed orchard

The white pine cone beetle, Conophthorus coniperda, exhibited dose and enantiospecific responses to -pinene in stands of mature eastern white pine, Pinus strobus, in a seed orchard near Murphy, North Carolina, USA. (–)--Pinene significantly increased catches of cone beetles to traps baited with (± )-trans-pityol. (+)--Pinene did not increase catches of beetles to pityol-baited traps and interrupted the response of beetles to traps baited with (±)-trans-pityol and (–)--pinene. Maximal attraction of cone beetles to pityol-baited traps was obtained with lures releasing (–)--pinene at a rate of 103 mg/day at 23^°C. Lures releasing (–)--pinene at rates lower or higher than 103 mg/day resulted in reduced catches to traps baited with (±)-trans-pityol. The sex ratio in all catches was heavily male biased. Attraction of the clerid predator, Thanasimus dubius, to traps baited with (±)-trans-pityol increased significantly with the presence of -pinene, irrespective of enantiomeric composition. Maximal attraction of T. dubius to pityol-baited traps occurred with devices releasing (–)--pinene at the highest rate tested, 579 mg/d at 23^°C, a sub optimal rate for cone beetles.     

Interannual and intra-annual cycles of satellite-derived chlorophyll-a concentrations in the Caspian Sea

Variability of phytoplankton in the Caspian Sea (CS) is related to the complex orography, the variety of physical and chemical processes, and climatic indices. Here, interannual and intra-annual variability of satellite-derived chlorophyll-a concentrations (Chl-a) were studied using wavelet analysis during 2002–2019 in different regions of the CS. Self-Organizing Maps (SOM) analysis performed to classify the CS into the areas of similar variability of satellite-derived Chl-a. Wavelet spectral analysis showed that the Chl-a variability regulated by four primary periodic cycles: 0.5-year, 1-year, 2 to 2.5-year, and 3 to 5-year. The 0.5 and 1-year wavelet cycles mostly depicted the intensity of seasonality patterns. The 2–2.5-year and 3–5-year cycles of Chl-a showed non-stationary coherence with corresponding low-frequency cycles of NAO and ENSO. The 3–5-year wavelet amplitudes of Chl-a strongly correlated with NAO and ENSO in the southern CS. Weak correlations of 2–2.5-year cycle wavelet amplitudes of Chl-a with NAO and ENSO suggested that variations do not always directly translate to a biological response. A negative anomaly in the Chl-a autumn peaks observed during 2011–2016 in the middle and southern CS, when NAO phases were persistently positive. The interannual variations of summer peaks in the northern CS, and autumn peaks in the middle and southern CS were broadly related to the precipitation. SST and wind stress. Moreover, it was shown that the Volga discharge has a significant influence on Chl-a variability in the northern CS.