Self‐assembling metal coatings from phosphated and siloxane‐modified polyurethane dispersions: An analysis of the coating–air interface

Polyurethane dispersion coatings containing phosphate and siloxane chains were evaluated for their self‐assembling properties for a single‐coating system. Dynamic contact angles (DCAs) and X‐ray photoelectron spectroscopy (XPS) were used to study the coating–air interface. The siloxane chains were the predominant species on the surfaces of the coatings. The wetting properties of the coating–air interface were reversed when the coated panels were immersed in an ionic solution, and the decrease in hydrophobicity was linear with time. Results from XPS and DCA analyses were similar. The self‐assembling properties of the coatings could be useful in the development of hydrophobic coatings from hydrophilic polymers. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 88: 893–899, 2003     

LTE小区搜索中一种新的SSS检测算法

主要研究了SSS检测, 提出一种新的SSS检测算法。该算法首先利用滑动平均窗修正接收的PSS处估计出的信道频率响应, 并用修正后的信道频率响应对接收的SSS序列进行信道补偿; 其次, 算法对信道补偿后的序列进行实数提取操作, 消除虚部数据干扰; 最后算法联合两个连续的SSS接收序列进行检测进一步提高检测性能。TDD和FFD两种模式下的仿真结果表明：该算法可以较好地实现SSS检测且比现有几种SSS检测算法在低信噪比（SNR<0 dB）条件下具有更好的检测性能。     

浅论塑料门窗行业存在的问题及解决办法

主要介绍塑钢门窗在中国的发展历史及在发展过程中存在的主要问题，分析了产生问题的原因，并从宏观角度提出了解决办法。     

Synthesis and characterization of biodegradable polyethylene by graft copolymerization of starch using glucose–Ce(IV) redox system

Graft copolymerization of low‐density polyethylene (LDPE) onto starch was carried out with glucose–cerium(IV) redox initiator in an aqueous sulfuric acid medium under nitrogen atmosphere. The graft yield was influenced by various parameters like reaction time, temperature, and concentrations of acid, glucose, polyethylene (PE), starch, and initiator. A maximum graft yield of 85.66% was obtained at a temperature of 50°C and at higher concentration of starch. Effect of grafting on crystallinity, morphology, and thermal properties of modified PE has been evaluated using X‐ray diffraction, scanning electron microscopy (SEM), differential scanning calorimetry (DSC), and thermogravimetric analysis (TGA/DTA). Biodegradability of starch‐grafted PE has been tested applying soil‐burial test. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 100: 3229–3239, 2006     

Heat Induced Structure Modifications in Polymer‐Layered Silicate Nanocomposites

Summary: The success of the use of layered silicates in polymer nanocomposites, to improve physical and chemical properties is strictly related to a deeper knowledge of the mechanistic aspects on which the final features are grounded. This work shows the temperature induced structural rearrangements of nanocomposites based on poly[ethylene‐co‐(vinyl acetate)] (EVA) intercalated‐organomodified clay (at 3–30 wt.‐% silicate addition) which occur in the range between 75 and 350 °C. In situ high temperature X‐ray diffraction (HT‐XRD) studies have been performed under both nitrogen and air to monitor the modifications of the nanocomposite structure at increasing temperatures under inert/oxidative atmosphere. Heating between 75 and 225 °C, under nitrogen or air, causes the layered silicate to migrate towards the nanocomposite surface and to increase its interlayer distance. The degradation of both the clay organomodifier and the VA units of the EVA polymer seems to play a key role in driving the evolution of the silicate phase in the low temperature range. The structural modifications of the nanocomposites in the high temperature range (250–350 °C), depended on the atmosphere, either inert or oxidizing, in which the samples were heated. Heating under nitrogen led to deintercalation and thus a decrease of the silicate interlayer space, whereas exfoliation was the main process under air leading to an increase of the silicate interlayer space.

Heat induced structural modification of EVA‐clay nanocomposite under nitrogen and air.     

纤维素酶的固体发酵

从来自国内外11株菌株的初步比较,筛选出酶活较高的康氏木霉N_2—78和瑞热埃木霉QM6a。对康氏木霉P_2和土曲霉3.3935所作的纤维素碳源试验中,发现木质纤维素较纯纤维素好,未经处理的木质纤维素比经处理的好。麸皮和稀土对康氏木霉P_2产酶作用影响较大,而对土曲霉3.3935则无明显的影响。     

1—AGO灰关联分析模型

对灰关联分析中关联系数以及关联度加以改进,给出了1—AGO关联系数以及1—AGO关联度,讨论了它们的有关性质,并建立了1—AGO灰关联分析模型,使之更具有合理性和科学性.     

卷取温度对X80管线钢析出行为与性能的影响

观察了不同卷取温度下X80管线钢中析出物的情况,并结合其组织性能对比可知：在实验情况下,480℃卷取时,有大量细小弥散的Nb、V的碳氮化物析出物,起到了较好的析出强化作用.     

基于DFT的UWB—OFDM信道估计算法

在基于OFDM技术的UWB系统中,由于信号在无线信道中传输,多径现象使得信号幅度发生衰落,相位发生偏移,为了保证通信的可靠性和有效性,接收机采用信道估计方法来预知信道的传输特性,补偿信道对超宽带信号造成的影响。在直接DFT估计方法的基础上,提出一种加窗DFT信道估计算法,用汉宁窗在时域上对信道冲激响应进行处理,有效地抑制频域响应的频谱泄漏。理论分析和仿真结果都表明在没有增加信道估计复杂度的基础上,提出的信道估计方法性能优于直接DFT估计方法。     

高职院校会计专业工学结合人才培养路径新探索

我国高职院校会计专业正处于人才培养路径的新探索时期,实施"工学结合"的培养路径是一种必然趋势。然而目前,高职会计教育的工学结合改革中存在诸多问题,文章深入分析了制约我国高职院校会计专业工学结合的因素,包括会计行业的自身局限性、实施会计专业工学结合的社会经济条件不足等,最后从高职会计教育最薄弱同时又是很重要的两个环节提出了改革建议。