二甲基二烯丙基氯化铵(DMDAAC)及其聚合物研究新进展

二甲基二烯丙基氯化胺 ( DMDAAC)是一种水溶性阳离子单体 ,其均聚物和共聚物 ,高效价廉 ,可广泛应用于油田、造纸、水处理、医药等领域 ,引起了化学工作者的普遍关注。综述了近五年来DMDAAC单体的合成、聚合方法以及均聚物和共聚物研究应用新进展 ,并对今后的研究重点提出一些建议     

含氮杂环季铵盐缓蚀剂在CO2-3%NaCl溶液体系中的电化学行为

为控制CO2腐蚀，合成了含氮杂环季铵盐缓蚀剂9912-1，通过电化学实验，研究了该缓蚀剂在CO2-3％NaCl-H2O体系中对碳钢于25℃和90℃下的缓蚀行为。实验结果与挂片失重法测试的结果基本一致。低温下缓蚀效果优于高温下的缓蚀效果。而且该缓蚀剂与硫脲有很好的协同效应。Tafel曲线表明，该缓蚀过程是以控制阴极腐蚀为主，并对其缓蚀机理进行了初步探讨。     

硫酸铵-氯化亚锡-孔雀绿体系浮选分离铂

研究了在盐酸介质中硫酸铵存在下氯化亚锡—孔雀绿—水体系浮选分离铂的方法。在最佳实验条件下，铂的浮选率可达100．0％，并与常见贱金属完全分离。     

Long-chain fatty ammonium quaternaries in papermaking

A series of long-chain quaternary ammonium halogen esters (UKK-chemicals), quaternary dimethyl tallow epoxypropyl ammonium halogens (EPK1), quaternary ditallow methyl epoxypropyl ammonium halogens (EPK2), and EPK2 oligomers (EPK2P) were synthesized. At acidic, neutral, or slightly basic conditions, EPK1-, EPK2-, EPK2P-, and UKK-chemicals operate as cationic chemicals. They can be used, for example, as stock sizings, surface sizings, or fixatives. Stock sizing, surface sizing, and fixative experiments indicate that EPK1-, EPK2-, EPK2P-, and UKK-chemicals function at least as well as or better than the corresponding synthetic chemicals used in papermaking.     

十六烷基辛基二甲基溴化铵和十六烷基癸基二甲基溴化铵的合成

合成了十六烷基辛基二甲基溴化铵和十六烷基癸基二甲基溴化铵两个新型杀生剂。用元素定量分析和红外光谱核磁共振谱等方法进行分析和结构鉴定。评定了两个化合物对硫酸盐还原菌的杀生作用。结果表明，两个化合物有很好的杀生效果。     

Pyrolysis-field ionization mass spectrometry of modified bagasse fractions

The fractions obtained from bagasse after activation with 17.5% NaOH, alternative alkylation with quarternary ammonium groups and extraction with 80% ethanol, water and 5% NaOH, were analyzed using pyrolysis-field ionization mass spectrometry (Py-FIMS). The proposed degradation products from lignin were mostly symmetric fragments containing two aromatic rings while the compounds formed from polysaccharides were the result of dehydration reactions. From the temperature-resolved Py-FIMS it could be seen that ethanol-lignin starts to degrade at temperatures lower than 180°C before the degradation of the hemicellulose fraction. The lignin markers are eliminated from hemicellulose fractions before the polysaccharide gasification starts. The quarternary ammonium groups are cleaved from the fractions at temperatures lower than 200°C.     

Ni-Mo-O催化剂中协同作用对丙烷氧化脱氢的影响

在 Ni-Mo-O体系中 ,加入 Mo O3 能极大地提高丙烷氧化脱氢制丙烯的反应活性。选用固混法、沉淀法、柠檬酸法制备了 Mo O3 过量 1 5 % (摩尔分数 )的α -Ni Mo O4催化剂 ,其中用沉淀法制得催化剂在 5 0 0℃ ,V( C3 H8) /V ( O2 ) /V ( N2 ) =1 0 /1 0 /5 0 ,反应气流量为 70 m L/min的条件下丙烷转化率可达 38.7% ,丙烯选择性达 70 .1 4 %。经 XRD,XPS,TPR表征说明 ,在含有过量 Mo O3 的催化剂中 ,α -Ni Mo O4与 Mo O3 两种晶体之间可产生微小的相互吸引 ;从而发挥协同作用 ,是提高催化剂活性     

Chirality-antimicrobial relationship of quaternary ammonium cationics

Optically active and racemic quaternary ammonium cationics containing a chiral alkyl group, such as N,N-dimethyl-N-(1-phenylethyl)alkylammonium bromides were prepared and showed excellent antimicrobial properties against Gram positive and negative bacteria, with some exceptions, and against fungi. The influence of optical isomerism on their antimicrobial properties showed that the antimicrobial properties between racemic and optically active cationics were obscure. The order of activity of substituted alkyl groups was tetradecyl > dodecyl ° hexadecyl.     

钼酸铵生产中杂质的分离方法

简要地介绍了钼酸铵生产中有害杂质的各种分离方达及应用情况，并就各种方法的利弊作了对比说明。     

应用硫酸铵提高乌拉嗄金矿石浮选回收率试验研究

经试验发现应用一种化学肥料硫酸铵可以显著提高乌拉嘎金矿石的浮选回收率。闭路试验尾矿工艺矿物学鉴定证明，以硫酸铵作为调整剂的浮选过程中，微细粒单体金和金与石英边生体被有效回收。