The properties of electroactive ruthenium oxide coatings supported by titanium-based ternary carbides

Electroactive oxide coatings on titanium, known in industrial chlorine production as dimensionally stable anodes (DSA), are of limited service life owing to the dissolution of active oxide, but also due to low corrosion stability of titanium, at high anodic potentials and elevated temperatures. In order to improve the anode stability, ternary carbide, Ti₃SiC₂, could be a promising material for the coating support, since chemical corrosion stability of Ti₃SiC₂ is significantly higher if compared to Ti. In this work, the possibility of the sol-gel preparation of RuO₂-TiO₂ coating on Ti₃SiC₂ is investigated and comparison of the basic characteristics of sol-gel processed oxide coating, Ru_0.5Ti_0.5O₂, applied onto Ti₃SiC₂ and Ti, is reported. Microscopic investigation of the coating surface showed that considerably less cracked coating is formed onto the Ti₃SiC₂ support. Slightly higher voltammetric currents are registered for Ti₃SiC₂-supported coating in H₂SO₄ and NaCl solution. The activity for chlorine evolution is higher, while the currents of oxygen evolution reaction are lower for Ru_0.5Ti_0.5O₂/Ti₃SiC₂ anode in comparison to Ru_0.5Ti_0.5O₂/Ti anode. Even though these preliminary results on the basic electrochemical properties of Ru_0.5Ti_0.5O₂/Ti₃SiC₂ anode and chemical stability of Ti₃SiC₂ are promising, the accelerated stability test in NaCl solution showed that coated Ti₃SiC₂ is not anodically stable and lasts considerably shorter than Ru_0.5Ti_0.5O₂/Ti anode prepared and tested under the same conditions.     

电子束焊接工艺文档编制与管理系统

采用面向对象编程技术开发实现了对焊接工程项目工艺流程档的计算机管理(具备对记录的检索、添加、删除、修改、复制和打印功能)以及对电子束焊接工艺数据(包括母材、焊机、焊材、接头图和焊接工艺参数等)的存储和管理。设计了电子束焊接工艺知识咨询模块，以实现整理、保存和传播电子束焊接知识的功能。系统具有友好的人机界面、良好的使用性能和较高的数据安全性及防错能力。     

高辐射耐热涂层的研制

阐述了一种具有高辐射和耐高温性能的涂层，它可用于铁路的红外轴温探测系统，以提高该系统红外线(红外热量)的辅出度。介绍了涂层的制备工艺及其指标数据的测定原理及方法，分析了影响涂层耐热性及热辐射性能的众多因素。     

浅谈化工建设项目竣工预验收程序和内容

结合作者的实际工作 ,总结了对工程建设实施“三道质量控制工序”的经验 ,强调了过程质量控制的重要性 ,较为系统地介绍了化工建设项目预验收工作的程序和内容     

XH－11型胶粘剂最佳固化工艺的研究

本文对ＸＨ－１１型胶粘剂的固化工艺参数进行了试验研究，确定了主要几个参数值，以达到最佳固化工效果。     

Modeling and global trajectory tracking control for an over-actuated MAV

This paper deals with an original micro aerial vehicle (MAV) design, the Omnicopter MAV. It has two central coaxial rotors with fixed-pitch propellers and three perimeter mounted ducted fans with servo motors performing thrust vectoring. Compared with traditional rotary wing MAVs that have inherent underactuation, the Omnicopter possesses some advantages in mobility, for example, lateral translation with zero attitude and hover with nonzero attitude. The trajectory tracking control design, global stability analysis, and control allocation are demonstrated through numerical simulation. The advantage of zero attitude translation is illustrated through experimental results.     

结合误差变换的Bouc-Wen迟滞非线性系统反步控制器设计

针对智能材料执行器中非平滑、多映射的迟滞非线性,采用Bouc-Wen模型描述迟滞,并提出了一种基于误差变换的反步控制器设计方案.首先利用Bouc-Wen模型中的变量特性,通过预设性能函数,将误差约束在预设范围内.然后通过误差变换,将一个对输出误差存在约束的跟踪问题转化为一个无约束的镇定问题.最后利用反步控制法设计迟滞系统的控制器,该控制方法保证期望的跟踪精度,并能将误差限定在设定范围内且满足预设性能,提高了系统的暂态和稳态性能.仿真结果表明设计方法的有效性.     

可逆冷带轧机速度张力多变量耦合系统的建模及分散控制

针对具有多变量、非线性、强耦合和不确定性的可逆冷带轧机速度张力系统,提出了一种基于扩张状态观测器(extended state observer,ESO)的全局积分滑模自适应反步分散控制方法.首先,采用机理建模方法,建立了相对完备的可逆冷带轧机速度张力多变量耦合系统的数学模型.其次,将各子系统的耦合项和不确定项看成外扰,通过构造的ESO对其进行动态观测,并分别引入所设计的全局积分滑模自适应反步控制器中进行补偿,速度张力系统实现了有效的动态解耦和协调控制.理论分析表明,所提出的控制方法能够保证滑模面的渐近稳定和闭环系统的渐近跟踪性能.最后,基于某1422mm可逆冷带轧机速度张力系统的实际数据进行仿真,结果验证了所提方法的有效性.     

一类内部点级联的PDE-ODE系统的边界控制

本文运用backstepping方法研究了一类偏微分方程与常微分方程(PDE-ODE)级联系统的能稳性.常见的级联系统在边界点x=0处级联,而本文所讨论的级联系统在内部点x0∈(0,1)处级联,级联点的改变使得新系统的控制问题更加复杂.针对新系统,首先,我们改进了backstepping方法中的常见变换,改进后的变换与常见变换相比,增加了变换中的核函数,且得到的是带有多个相容性条件的核方程组,给求解带来了困难.文中运用了一系列的技巧解出核函数,从而得到反馈控制器;其次,运用同样的方法找到改进变换的逆变换;最后,选择合适范数,利用变换的有界性证明得到闭环系统的稳定性.     

TREOR多晶X射线衍射图指标化程序的适用性

多晶Ｘ射线衍射图指标化的ＴＲＥＯＲ程序已被普遍采用，特别是在硅酸盐矿物等材料的晶体结构研究工作中应用很多。然而，实际上它存在着一定的缺陷，有可能得出错误的结果。本文对这一程序作了详细的检验，发现即使在理想条件下它都不适用于低对称晶系的指标化。在对程序作改进以后，该程序可适用于高对称晶系多晶衍射的指标化