Macroscopic model for multispecies ion-exchange kinetics

A model for multispecies ion-exchange kinetics based on the Nernst-Planck equation is suggested. It is analyzed in comparison with the “locally-determinate” model described by Hwang and Helfferich [1]. The model makes possible simple computation. The conditions for the occurrence of unusual kinetic curves with a maximum are clarified. The proposed model is developed for different types of kinetic problems and verified by the experimental investigation of a kinetics in ternary systems.     

局部特征表征的6D位姿估计算法

为解决有纹理模型在遮挡条件下6D位姿估计精确度不高的问题,提出了一种局部特征表征的端到端6D位姿估计算法。首先为了得到准确的定位信息,提出了一个空间—坐标注意力机制（spatial and coordinate attention）,通过在YOLOv5网络中加入空间—坐标注意力机制和加权双向特征金字塔网络（bidirectional feature pyramid network）,YOLOv5-CBE算法的精确度（precision）、召回率（recall）、平均精度均值（mAP@0.5）分别提升了3.6%、2.8%、2.5%,局部特征中心点坐标误差最高提升了25%;然后用 YOLOv5-CBE算法检测局部特征关键点,结合3D Harris关键点通过奇异值分解法（singular value decomposition）计算模型的6D位姿,最高遮挡70%的情况下仍然可以保证二维重投影精度（2D reprojection accuracy）和ADD度量精度（ADD accuracy）在95%以上,具有较强的鲁棒性。     

Correlation of high-pressure thermal conductivity,viscosity, and diffusion coefficients for n-alkanes

Thermal conductivity, viscosity, and self-diffusion coefficient data for liquid n-alkanes are satisfactorily correlated simultaneously by a method based on the hard-sphere theory of transport properties. Universal curves are developed for the reduced transport properties ^*, ^*, and D ^* as a function of the reduced volume. A consistent set of equations is derived for the characteristic volume and for the parameters R , R , and R _D, introduced to account for the nonsphericity and roughness of the molecules. The temperature range of the above scheme extends from 110 to 370 K, and the pressure range up to 650 MPa.     

An implicit enthalpy scheme for one-phase Stefan problems

A compact finite-difference scheme to solve one-phase Stefan problems in one dimension is described. Numerical experiments indicate that the moving interface is obtained withO(t) accuracy when 3–4 iterations per time step are used to solve the nonlinear implicit scheme. The scheme can be adapted to ADI methods in higher dimensions.     

On the determination of the thermal diffusion factor from column measurements

A new method for experimental determination of the thermal diffusion factor _T for binary gas mixtures with a thermal diffusion column (TDC) is developed, based on A. M. Rozen's equation of TDC. The experimental results for _T are obtained in a reduced form in this approximation. An experimental reference point, determined in the same TDC with a standard gas mixture, is used for the transformation of the results for _T in absolute units. The proposed method is applicable for arbitrary gas mixtures, irrespective of the mass difference of the components.     

Nondestructive characterization of the mechanical strength of diffusion bonds. II. Application of a quasi-static spring model

It has been shown that the acoustic response of imperfect interfaces may be described by a quasi-static spring model. In the present paper, experimental data on the geometry of the contacts between two diffusion-bonded blocks have been used to determine the spring stiffness of such interfaces which have been correlated with experimentally determined ultrasonic reflection coefficients. The correlation between the theoretical reflection coefficient and the spring stiffness was found to be in excellent agreement with experimentally-observed values, if the disbonds are of infinitesimally small thickness. For disbonds of finite thickness, the agreement is less satisfactory. Reasons for the discrepancy in the latter case are unknown at the present time.     

Electrical conductivity,self-diffusion,and volume expansion of alkali halides at the melting point

In an earlier paper, Heisenberg's uncertainty principle was invoked at the melting point T _m of crystalline solids to provide fundamental justification for Lindemann's melting law and to compute diffusion coefficients of several alkali halides. The uncertainty principle defines breakdown of Debye zone boundary (ZB) phonons as valid collective excitations when phonon energies and line widths due to anharmonicity become comparable at T _m. Upon breakdown, random, high-frequency single-particle motion or partial decoupling of crystal ions sets in. Lifetimes of these single-particle ZB motions are determined from the minimum-uncertainty product inequality by assuming that it becomes an equality at T _m for ZB phonons. The present paper addresses improved formulation of that work and extended application to ionic electrical conductivities of 18 molten alkali halides at T _m. It is shown that use of the Debye model produces an approximate lower bound to the mean free time, not the unconstrained direct estimate previouslu implied. This feature is generally reflected in results for ionic conductivities and alkali halide diffusion coefficients for which comparison experimental data were found. However, in spite of this lower-bound formulation and the simple nature of the computation, the results compare favorably with experiment. A model of random single-particle harmonic motion superimposed on the lower-frequency collective motion is proposed to account for volume expansion accompanying the partial decoupling for hard-sphere ions. Experimental comparisons for 15 alkali halides show the decoupling volume change to account largely for the total volume change of melting (in the hard-sphere approximation), yielding a closer agreement with experiment than recent calculations aimed explicitly at the total volume change.Paper presented at the Tenth Symposium on Thermophysical Properties, June 20–23, 1988, Gaithersburg, Maryland, U.S.A.     

Correlation and prediction of dense fluid transport coefficients. I. n-alkanes

Recent accurate measurements of the self-diffusion coefficient for n-hexadecane and n-octane and of the viscosity coefficient for n-heptane, n-nonane, and n-undecane over wide pressure ranges have been used to provide a critical test of a previously described method, based on consideration of hard-sphere theory, for the correlation of transport coefficient data. It is found that changes are required to the universal curve for the reduced viscosity coefficient as a function of reduced volume and, also, to the parameters R _D, R , and R which were introduced to account for effects of nonspherical molecular shape. The scheme now accounts most satisfactorily for the self-diffusion, viscosity, and thermal conductivity coefficient data for all n-alkanes from methane to hexadecane at densities greater than the critical density.     

基于人类视觉模型的各向异性扩散滤波方法

针对各向异性扩散模型中扩散系数的梯度阈值确定问题进行了研究,提出了一种基于人类视觉模型的各向异性扩散滤波器。首先在PM方程的基础上研究了各向异性扩散系数中梯度阈值的取值问题。根据仿生学原理,分析了韦伯比曲线,将图像根据背景亮度划分为不同的区域,分别采用不同的公式计算梯度阈值。然后讨论了改进后算法在8邻域内的离散实现问题。仿真结果表明,与传统的恒常梯度阈值扩散模型相比,改进后的算法在有效保留图像重要信息的同时对噪声的抑制效果更为理想。