The role of La2O3 loading in Pd/Al2O3-La2O3 prepared by sol–gel on the catalytic properties in the NO reduction with H2 was studied. The catalysts were characterized by N2 physisorption, temperature-programmed reduction, differential thermal analysis, temperature-programmed oxidation and temperature-programmed desorption of NO.
The physicochemical properties of Pd catalysts as well as the catalytic activity and selectivity are modified by La2O3 inclusion. The selectivity depends on the NO/H2 molar ratio (GHSV = 72,000 h−1) and the extent of interaction between Pd and La2O3. At NO/H2 = 0.5, the catalysts show high N2 selectivity (60–75%) at temperatures lower than 250 °C. For NO/H2 = 1, the N2 selectivity is almost 100% mainly for high temperatures, and even in the presence of 10% H2O vapor. The high N2 selectivity indicates a high capability of the catalysts to dissociate NO upon adsorption. This property is attributed to the creation of new adsorption sites through the formation of a surface PdOx phase interacting with La2O3. The formation of this phase is favored by the spreading of PdO promoted by La2O3. DTA shows that the phase transformation takes place at temperatures of 280–350 °C, while TPO indicates that this phase transformation is related to the oxidation process of PdO: in the case of Pd/Al2O3 the O2 uptake is consistent with the oxidation of PdO to PdO2, and when La2O3 is present the O2 uptake exceeds that amount (1.5 times). La2O3 in Pd catalysts promotes also the oxidation of Pd and dissociative adsorption of NO mainly at low temperatures (<250 °C) favoring the formation of N2. 相似文献
This paper discusses optimal binary codes and pure binary quantum codes created using Steane construction. First, a local search algorithm for a special subclass of quasi-cyclic codes is proposed, then five binary quasi-cyclic codes are built. Second, three classical construction methods are generalized for new codes from old such that they are suitable for constructing binary self-orthogonal codes, and 62 binary codes and six subcode chains of obtained self-orthogonal codes are designed. Third, six pure binary quantum codes are constructed from the code pairs obtained through Steane construction. There are 66 good binary codes that include 12 optimal linear codes, 45 known optimal linear codes, and nine known optimal self-orthogonal codes. The six pure binary quantum codes all achieve the performance of their additive counterparts constructed by quaternary construction and thus are known optimal codes. 相似文献
A novel network model of multiple source fountain coding is developed and a novel class of generic multiple source fountain codes with unequal error protection(UEP)property is proposed.The And–Or tree analysis technique is generalized to analyze the asymptotic performance of the proposed codes and a joint optimization method employing both linear and nonlinear programs is developed to optimize the degree distributions.Furthermore,we propose three basic methods to achieve UEP property and the performance of each method is discussed.We employ these analytical results and optimization method to design and discuss several UEP codes with two and four sources for different application scenarios.Simulation results verify that the proposed codes can be applied to the networks with any number of sources and can provide strong UEP property in various ways based on the proposed three basic methods. 相似文献