数字化煤场与配煤掺烧技术的实施要点初论

优化配置不同种类、不同性质的煤炭,将其掺配成在综合性能上呈最佳状态的新煤种,满足锅炉在不同条件下的各种需要;开发数字化煤场,实现煤场的数字化动态管理。主要分析、研究了数字化煤场和配煤掺烧技术的实施要点。     

复合型导电塑料的研究进展

介绍了复合型导电塑料的种类。特性与应用，讨论了它们的导电机理及影响导电性的因素。着重全叙述了国内外对添加抗静电剂、导电填料以及共混复合型导电塑料的研究现状与发展趋势。     

PBT共混改性研究最新进展

综述了最近几年国内外聚对苯二甲酸丁二醇酯(PBT)共混改性的研究进展,分类介绍PBT/聚烯烃、PBT/同系聚酯、PBT/液晶、PBT/弹性体、PBT/聚碳酸酯等不同共混体系,讨论了各体系中的相行为、相容性、热稳定性、力学性能等,并对该类共混物的发展趋势作了简要的分析。     

异氰酸酯对聚乳酸/热塑性聚氨酯共混物性能的影响

以4,4^′-二苯基甲烷二异氰酸酯（MDI）为反应增容剂，采用熔融共混法制备了不同MDI含量的聚乳酸/热塑性聚氨酯（PLA/TPU）共混物，采用傅里叶变换红外光谱仪（FTIR）、万能试验机、冲击试验机、扫描电子显微镜（SEM）、差示扫描量热仪（DSC）和旋转流变仪对共混物力学性能、微观形态、热性能和流变性能进行了研究。结果表明：MDI可以有效改善共混物的力学性能，当MDI质量分数为1%时，共混物力学性能最佳，缺口冲击强度为40.0kJ/m²，断裂伸长率为214.1%，与未加MDI的共混物相比，分别增加了4.3倍和5.8倍，拉伸强度稍有下降（47.6MPa）；SEM表明，MDI的加入提高了共混物的相容性，加入MDI后，共混物的断面由海-岛结构变为核-壳包覆结构，相界面作用力增强；DSC测试表明，共混物的玻璃化转变温度、冷结晶温度和熔融温度随着MDI含量的增加而升高；流变测试表明，MDI质量分数的增加，共混物呈现更显著的剪切变稀行为，推测共混反应机理为：MDI质量分数的增加，体系内依次发生PLA的扩链、支化和TPU的交联。     

Use of natural rubber‐g‐polystyrene as a compatibilizer in casting natural rubber/polystyrene blend films

Natural rubber/polystyrene (NR/PS) blend films with weight ratios of 70/30, 60/40, and 50/50 were prepared using polystyrene grafted natural rubber copolymers (NR‐g‐PS) as the compatibilizer. Copolymers with molar ratios of 90/10, 80/20, and 70/30 were synthesized via emulsion copolymerization using tert‐butyl hydroperoxide/tetraethylene pentamine as an initiator. The copolymers were subsequently added into the blends at 0, 5, 10, 15, 20, 25, and 30 phr. The mixtures were cast into films by the solution‐casting method using toluene as the casting solvent. Mechanical and morphological properties of the prepared films were investigated. The film prepared from 80/20 NR‐g‐PS showed higher tensile and tear strength, as well as finer domain size of the dispersed phase, than those prepared from 90/10 and 70/30 NR‐g‐PS. However, the mechanical properties of the films were decreased at high loading of the copolymers. In addition, themogravimetric analysis revealed that weight loss was decreased upon introduction of the compatibilizer. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 95: 826–831, 2005     

面泊松融合结合色彩变换的无缝纹理辐射处理

目的：消除三维模型纹理接缝上的辐射差异,实现接缝处色彩的自然、连续的过渡。方法：本文在标准的泊松融合（Poisson Blending）基础上,结合色彩变换技术（Color Transfer）,提出了一种新的以面为基元的泊松融合无缝纹理辐射处理方法。首先以影像上的纹理三角形为处理单元,以色彩变换参数为未知数,根据模型的三角网边邻接拓扑关系建立泊松方程组,然后全局最小二乘解求局部色彩变换参数,最后进行全局最优解下的局部色彩变换。结果：既保证了色彩的均匀过渡,又能更好的改正影像间的整体色差。结论：相比使用标准的像素级泊松融合方法进行无缝纹理处理,本文的方法拥有计算上的优势,更适合于复杂模型的处理,且有更好的整体色差改正与过渡效果。理论分析和大量试验证明了本文方法的优越性。     

Reactive blending of polyamide with polyethylene: pull-out of in situ-formed graft copolymers and its application for high-temperature materials

Reactive blending of polyamide 6 (PA) with polyethylene (PE) having reactive sites, maleic anhydride (MAH content=0.1 wt%),and glycidyl methacrylate (GMA content=3-12 wt%), was carried out at 70/30 and 65/35 (PA/PE) blend ratios. Blend morphology evolved by reactive blending was analyzed by light scattering and transmission electron microscopy. The blends were then irradiated by electron beam. The degree of crosslinking was estimated by measuring the dynamic storage modulus at a temperature above melting point of PA. It was found that surface-to-surface interparticle distance τ was significantly reduced by the micelle formation via pull-out of in situ-formed graft copolymers. The blend with shorter τ was crosslinked by electron-beam irradiation at the lower dose level. A blend having the minimum τ (∼0.2 μm) was nicely crosslinked at a low dose level same as for PE, and even for the PA matrix system.     

Rheological behavior of reactive blending of epoxidized natural rubber with cassava starch and epoxidized natural rubber with natural rubber and cassava starch

Epoxidized natural rubbers (ENR‐25 and ENR‐45) were prepared using the performic epoxidation method. Two‐component (ENR–cassava starch) and three‐component (ENR–NR–cassava starch) blends were prepared. ENR‐25 and ENR‐45 were blended with various quantities of gelatinized cassava starch in the latex state. The pure ENR exhibited lower shear stress and shear viscosity than those of the blends with cassava starch. Furthermore, the shear stress and shear viscosity were increased with an increase in the cassava starch concentration. The chemical interaction between the epoxide groups in the ENR and the hydroxyl groups in the cassava starch molecules might be the reason for the increasing trends of the shear stress and shear viscosity. The blends are classified as compatible blends because of the strong chemical bonding between different phases. SEM micrographs were used to clarify the compatibility. Power law behavior with pluglike flow profiles was observed for all sets of ENR–NR–cassava starch blends. Very low power law index values (<0.34) and highly pseudoplastic fluid behavior were also observed. The log additive rule was applied to plots of zero shear viscosity (consistency index) and the shear viscosity versus the concentration of ENR‐25. Positive deviation blending was observed, which indicates compatible blends. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 91: 1752–1762, 2004     

配贫瘦煤炼焦的探讨与实践

介绍了在生产性实验中配加不同比例的贫瘦煤炼焦对焦炭强度的影响 ,最经济合理的配煤比可使焦炭的强度有一定改善。     

LLDPE／LDPE共混物熔体挤出胀大行为的研究

应用毛细管流变仪，考察了实验条件下线性低密度聚乙烯与低密度聚乙烯共混物（ＬＬＤＰＥ／ＬＤＰＥ）熔体挤出胀大行为及其影响因素。结果表明，挤出胀大比Ｂ与剪切应力近似呈幂律关系，而随口型长径比的增加呈指数衰减，当共混比为５０／５０时，Ｂ产生局部极涉值现象。