Synthesis and properties of novel amphiphilic sulfated ionomers by the ring‐opening reaction of an epoxidized styrene–butadiene–styrene triblock copolymer

A method for the synthesis of novel sulfated ionomer of styrene–butadiene–styrene triblock copolymer (SBS) was developed. SBS was first epoxidized by performic acid in the presence of a phase‐transfer catalyst; this was followed by a ring‐opening reaction with an aqueous solution of alkali salt of bisulfate. The optimum conditions for the ring‐opening reaction of the epoxidized SBS with an aqueous solution of KHSO₄ were studied. During the ring‐opening reaction, both phase‐transfer catalyst and ring‐opening catalyst were necessary to enhance the conversion of epoxy groups to ionic groups. The products were characterized with Fourier transform infrared spectrophotometry and transmission electron microscopy (TEM). After the potassium ions of the ionomer were substituted with lead ions, the lead sulfated ionomer exhibited dark spots under TEM. Some properties of the sulfated ionomer were studied. With increasing ionic groups or ionic potential of the cations, the water absorbency and emulsifying volume of the ionomer and the intrinsic viscosity of the ionomer solution increased, whereas the oil absorbency decreased. The sulfated ionomer possessed excellent emulsifying properties compared with the sulfonated SBS ionomer. The sodium sulfated ionomers in the presence of 10% zinc stearate showed better mechanical properties than the original SBS. When the ionomer was blended with crystalline polypropylene, a synergistic effect occurred with respect to the tensile strength. The ionomer behaved as a compatibilizer for blending equal amounts of SBS and oil‐resistant chlorohydrin rubber. In the presence of 3% ionomer, the blend exhibited much better mechanical properties and solvent resistance than the blend without the ionomer. SEM photographs indicated improved compatibility between the two components of the blend in the presence of the ionomer. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci, 2008     

影响带锯机锯切质量的原因及处理措施

通过对锯切装置的改进，提高了锯切性能，降低了锯条成本，保证了锯切质量，使设备更加高效、安全的工作。     

江苏复杂断块高含水单元改善水驱效果的技术对策

在分析高含水开发单元特点的基础上,针对该阶段剩余油的品位、分布和油水关系极为复杂、挖潜难度大的技术难点,提出了适合江苏复杂断块油田高含水开发单元改善水驱开发效果的思路和工作程序、技术对策,并在真武油田高含水开发单元进行了实际应用,取得了良好的效果.     

赵凹区块酸化增注技术研究与应用

针对河南油田赵凹区块注水效果不好,欠注严重,酸化效果不理想的实际情况,开展了储层伤害因素分析和酸化增油技术研究,进行了酸液体系的配方优化,优选出的酸液具有对金属腐蚀性小,与地下流体配伍性好,对岩屑溶蚀率高的特点。现场实验取得了较好的增注效果,3口井实施有效率100％,注水压力下降了1-8 MPa。     

ROI-based Watermarking Scheme for JPEG 2000

A new region of interest (ROI)-based watermarking method for JPEG 2000 is presented. The watermark is embedded into the host image based on the characteristics of the ROI to protect rights to the images. This scheme integrates the watermarking process with JPEG 2000 compression procedures. Experimental results have demonstrated that the proposed watermark technique successfully survives JPEG 2000 compression, progressive transmission, and principal attacks.     

郑411块超稠油试油试采工艺技术应用

郑411块沙三段地层疏松出砂、原油粘度高，属中深层超稠油，常规试油试采方法难以突破出油关，采用APR全通径氮气垫测试、地层与井筒复合防砂、水平井配合直井蒸汽吞吐、氮气泡沫封堵调剖和井筒加热举升稠油等配套工艺技术，取得了较好的效果，为中深层超稠油油藏的开发提供了技术思路。     

3^n阶矩阵乘法的分块算法

针对３＾ｎ阶矩阵的乘法运行，给出了一种分块算法，其乘法运行量比常规的矩阵乘法计算方法和补零的基－２算法都有所减少。     

256比特的混沌分组密码

由于密码分析研究的进展及DES自身的弱点,原64比特的DES将不能作为数据加密的标准算法而长期存在。在原来工作的基础上,本文提出了256比特的分组密码方案。密码算法由基于混沌映射的数字滤波器构造。     

Evaluation of rainfall networks using entropy: II. Application

This paper, the second in the series, applies the entropy approach to space and time evaluation of rainfall networks in Louisiana. The evaluation is made for five sampling intervals: daily, 2-day, weekly, monthly, and yearly, and for two separate seasons. In each case, the best combination of raingages is suggested and the lines of equal information (isoinformation contours) are constructed showing the areas of greater or less information transfer. The isoinformation lines are especially suitable in decisions concerning the expansion of the existing network or deleting the unnecessary raingages.     

Viscous behaviour of glass-forming liquids: a thermodynamic approach

The temperature dependence of the viscosity of the undercooled melts exhibits an important role in the study of nucleation, crystal growth and the glass-forming ability of materials. Several attempts have been made to study the viscous behaviour of the glass-forming melts and these investigations are mainly based on free volume theory as well as on the configurational entropy model. In the present investigation, an attempt has been made to correlate the thermodynamic parameters with the viscosity of the glass-forming melts and to study the temperature dependence of the viscosity of undercooled liquids on the basis of the free volume theory as well as on the basis of the configurational entropy model of Adam and Gibbs. The entire study is confined on the expression for thermodynamic parameters reported by the authors recently. The expression obtained has been successfully applied to study the temperature dependence of the viscosity of the metallic, molecular and oxide glass-forming liquids.