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41.
Gradient-corrected density functional theory was used to investigate the adsorption of H2S on Pd(1 1 1) surface. Molecular adsorption was found to be stable with H2S binding preferentially at top sites. In addition, the adsorption of other S moieties (SH and S) was investigated. SH and S were found to be preferentially bind at the bridge and fcc sites, respectively. The reaction pathways and energy profiles for H2S decomposition giving rise to adsorbed S and H were determined. Both H2S(ad) → SH(ad) + H(ad) and SH(ad) → S(ad) + H(ad) reactions were found to have low barriers and high exothermicities. This reveals that the decomposition of H2S on Pd(1 1 1) surface is a facile process. 相似文献
42.
本文介绍在铀矿床工业指标制定中,对未来矿山开采设计方案及经济计算参数几千问题的分析,以利于合理的制定铀矿床工业指标,为铀矿冶企业技术改造,在建企业修改设计和为选择新建企业提供决策依据,进而使铀矿冶企业提高经济效益。 相似文献
43.
44.
ABSTRACT: Crack development during freezing (CDF) is one of the major challenges in individually quick frozen (IQF) cut and peel carrot processing. The effects of processing and freezer storage on crack development were examined on the cut and peel carrot variety, Sugarsnax. Carrot samples were removed from the major processing steps, the trans-slicer, the shaper, the blancher, and the dryer, and examined for crack development by measuring percentage cracked, crack morphology, total soluble solids, moisture levels, and membrane injury index immediately after processing. These parameters were also examined following 20 wk of standard freezer storage for cut and peels. Approximately 2% of nonprocessed carrots were cracked compared to 45% of carrots after the initial trans-slicing stage. As the processing continued, cracking decreased due to the removal of the outer epidermis to 16% of the finished product. This suggests that CDF was initiated at the 1st processing stage. Crack width and depth were 2.3 and 2.6 mm, respectively, at the trans-slicer stage and decreased to 1.1 and 1.8 mm at the end of the line. It was found that CDF was further exacerbated by freezer storage due to inefficient water removal at the dryer stage. Crack width and depth increased to 1.5 and 3.0 mm after 20 wk for freezer storage. Root size also played a role in CDF, suggesting that larger pieces are more susceptible to crack development. Total soluble solid concentrations did not play a role in crack formation during cut and peel processing. 相似文献
45.
Liping Wang Ramana V. Grandhi Dale A. Hopkins 《International journal for numerical methods in engineering》1995,38(10):1721-1738
The objective of this paper is to conduct reliability-based structural optimization in a multidisciplinary environment. An efficient reliability analysis is developed by expanding the limit functions in terms of intermediate design variables. The design constraints are approximated using multivariate splines in searching for the optimum. The reduction in computational cost realized in safety index calculation and optimization are demonstrated through several structural problems. This paper presents safety index computation, analytical sensitivity analysis of reliability constraints and optimization using truss, frame and plate examples. 相似文献
46.
介绍了基于自由载流子对介质折射率调制作用,而建立的监测半导体器件内自由载流子变化情况的实验装置,该装置能实时反映自由载流子变化情况,且对原电路无任何影响。本方法适用于硅和砷化镓材料的电子和光电子器件,也显示了在测量集成电路内部有源器件特性方面的潜在应用前景。 相似文献
47.
迭加与量化水印嵌入方案的比较及量化参数优化 总被引:3,自引:0,他引:3
分别研究了迭加法和量化法的隐蔽性和稳健性,并且提出了量化调制水印方案中的参数优化方法。对两类方法的分析比较表明,迭加法适用于在高频分量嵌入水印,而量化法适用于在低频分量嵌入水印。并以实验验证了这一结论。 相似文献
48.
Evaluate the performance of a stochastic-flow network with cost attribute in terms of minimal cuts 总被引:2,自引:0,他引:2
This paper proposes a performance index to measure the quality level of a stochastic-flow network in which each node has a designated capacity, which will have different lower levels due to various partial and complete failures. The performance index is the probability that the maximum flow of the network equals the demand d without exceeding the budget b. A simple algorithm in terms of minimal cuts is first proposed to generate all upper boundary points for (d, b), and then the probability that the maximum flow is less than or equal to d can be calculated in terms of such points. The upper boundary point for (d, b) is a maximal vector representing the capacity of each arc such that the maximum flow of the network under the budget b is d. The performance index can be calculated by repeating the proposed algorithm to obtain all upper boundary point for (d−1, b). A benchmark example is shown to illustrate the solution procedure. 相似文献
49.
In this work, we co‐formulated an oil‐borne copper naphthenate/permethrin wood preservative system with synthetic polymer‐based fire‐retardant additives prior to the impregnation of Pinus radiata sapwood. We evaluated what effect, if any, the preservative had upon the fire performance properties of the fire retardants and whether the fire retardants impacted on the fungicidal and termiticidal efficacy of the preservative. The fire retardants included halogenated and phosphorus‐based systems. A mass loss calorimeter, in conjunction with a thermopile, was used to measure the time to ignition and the peak heat release rate (PHRR) from which the fire performance index (FPI) was determined. The preservative properties were evaluated using termite and soil‐block decay bioassays. In summary, we found that the rate of fire growth was reduced when the fire retardants were used in combination with the wood preservative. We also found that the PHRR was a better determinant of fire performance than the FPI. The performance of the wood preservative was enhanced against fungal decay and termite attack when used in combination with the fire retardants. The fire retardants also demonstrated some wood preservative properties of their own. Copyright © 2008 John Wiley & Sons, Ltd. 相似文献
50.
改进的GMDH方法及其在参数预报中的应用 总被引:4,自引:0,他引:4
本文在综合了GMDH方法中几种有效的改进算法的基础上,进一步研究了变量预选及部分表达式的构成问题,采用最优化方法确定变量最佳组成式并进行变量筛选,由此得到精度更高、稳定性较好的模型,将其应用于聚丙烯熔指数的预报,仿真结果令人满意。 相似文献