FEM analyses for influences of stress corrosion and pressure solution on THM coupling in dual-porosity rock mass

With the models of stress corrosion and pressure solution, by Yasuhara et al., two computation conditions were designed for a hypothetical nuclear waste repository in an unsaturated dual-porosity rock mass: (i) the fracture apertures are changed with the stress corrosion and pressure solution (the porosity of rock matrix is also a function of stress); (ii) the fracture apertures and the porosity of rock matrix are constants. Then the corresponding two-dimensional FEM analyses for the coupled thermohydro-mec...     

Synthesis of thermosetting poly(phenylene ether) containing allyl groups

New thermosetting poly(2-allyl-6-methylphenol-co-2,6-dimethylphenol)s (3) have been developed by oxidative coupling copolymerization of 2-allyl-6-methylphenol (1) with 2,6-dimethylphenol (2), followed by thermal curing. Copolymerization was conducted in nitrobenzene in the presence of copper(I) chloride and pyridine as the catalyst under a stream of oxygen, producing high molecular weight copolymers (M_n∼50,000) with broad molecular weight distributions (M_w/M_n∼35). The structure of resulting copolymers 3 was characterized by IR, ¹H, and ¹³C NMR spectroscopy. Cross-linking reactions of copolymers were carried out by thermal treatment in the absence or presence of a peroxide (3 wt%, 2,5-dimethyl-2,5-di(tert-butylperoxy)-3-butane). The 10% weight loss and glass transition temperatures of the cured copolymers were 436 °C in nitrogen and 235 °C, respectively after curing at 70 °C for 1 h and 300 °C for 1 h. The average refractive index of the cured copolymer (3b) film was 1.5407, from which the dielectric constant (ε) at 1 MHz was estimated as 2.6. The ε and dissipation factor of copolymer-films at 1 MHz were directly measured from their capacitances as 2.5-2.6 and 0.0015-0.0019, respectively.     

Interannual vegetation phenology estimates from global AVHRR measurements: Comparison with in situ data and applications

In a previous paper, we described a procedure to correct the directional effects in AVHRR reflectance time series. The corrected measurements show much less high frequency variability than their original counterparts, which makes them suitable to study vegetation dynamics. The time series are used here to estimate the start and ending dates of the growing season for 18 years from 1982 to 1999. We focus on the interannual variations of these phenological parameters.A database of in situ phenology observations is used to quantify the accuracy of the satellite-based estimates. Although based on a limited sampling of the Northern mid and high latitudes, the comparison indicates that i) the satellite phenological product contains meaningful information on interannual onset anomalies; ii) there is a higher degree of consistency over regions covered by Broadleaf Forests, Grasses and cereal Crops than over those covered by Needleleaf Forests or Savannas; and iii) the satellite phenological product is of lower quality in regions with mountainous terrain. In favorable conditions, interannual variations of the onset are captured with an accuracy of a few days.As this satellite-derived product captures the interannual onset variability at ground-truth sites, we confidently use it to larger scales studies. Mapped at a continental scale, the onset anomalies show coherent patterns at the regional (≈ 1000 km) scale for the mid and high latitudes of the Northern hemisphere, which is consistent with a meteorological forcing. In the tropics, there is larger spatial heterogeneity, which suggests more complex controls of the phenology. The relation between vegetation phenology and climate is further investigated over Europe by comparing the variability of the satellite-derived vegetation onset and that of the winter North Atlantic Oscillation index, at a fine spatial scale. The strong correlations observed confirm that this climate forcing parameter explains most of the onset variability over a large fraction of Northern Europe (earlier onsets for positive winter NAO), with lower impact towards the south and opposite effects around the Mediterranean basin. The NAO has a predictive character as the January-February NAO index is strongly correlated with the vegetation onset that occurs around April in Northern Europe.     

Molecular simulation of phase coexistence: Finite-size effects and determination of critical parameters for two- and three-dimensional Lennard-Jones fluids

Abstact The subject of this paper is the investigation of finite-size effects and the determination of critical parameters for a class of truncated Lennard-Jones potentials. Despite significant recent progress in our ability to model phase equilibria in multicomponent mixtures from direct molecular simulations, the accurate determination of critical parameters remains a difficult problem. Gibbs ensemble Monte Carlo simulations with systems of controlled linear system size are used to obtain the phase behavior in the near-critical region for two- and three dimensional Lennard-Jones fluids with reduced cutoff radii of 3, 3.5, and 5. For the two-dimensional systems, crossover of the effective exponent for the width of the coexistence curve from mean field ( = 1/2 in the immediate vicinity of the critical point to Ising-like (= 1/8) farther away is observed. Critical parameters determined by fitting the data that follow Ising-like behavior are in good agreement with literature values obtained with finite-size scaling methods. For the three-dimensional systems, no crossover to mean field-type behavior was apparent. Extrapolated results for the critical parameters are consistent with literature estimates for similar fluids. For both two- and three-dimensional fluids, system size effects on the coexistence curves away from the critical point are small, normally within simulation statistical uncertainties.Invited paper presented at the Twelfth Symposium on Thermophysical Properties, June 19–24, 1994, Boulder. Colorado, U.S.A.     

Single-Atom Metal Sites Anchored Hydrogen-Bonded Organic Frameworks for Superior “Two-In-One” Photocatalytic Reaction

Photoredox catalysis is a green solution for organics transformation and CO₂ conversion into valuable fuels, meeting the challenges of sustainable energy and environmental concerns. However, the regulation of single-atomic active sites in organic framework not only influences the photoredox performance, but also limits the understanding of the relationship for photocatalytic selective organic conversion with CO₂ valorization into one reaction system. As a prototype, different single-atomic metal (M) sites (M²⁺ = Fe²⁺, Co²⁺, Ni²⁺, Cu²⁺, and Zn²⁺) in hydrogen-bonded organic frameworks (M-HOF) backbone with bridging structure of metal-nitrogen are constructed by a typical “two-in-one” strategy for superior photocatalytic C N coupling reactions integrated with CO₂ valorization. Remarkably, Zn-HOF achieves 100% conversion of benzylamine oxidative coupling reactions, 91% selectivity of N-benzylidenebenzylamine and CO₂ conversion in one photoredox cycle. From X-ray absorption fine structure analysis and density functional theory calculations, the superior photocatalytic performance is attributed to synergic effect of atomically dispersed metal sites and HOF host, decreasing the reaction energy barriers, enhancing CO₂ adsorption and forming benzylcarbamic acid intermediate to promote the redox recycle. This work not only affords the rational design strategy of single-atom active sites in functional HOF, but also facilitates the fundamental insights upon the mechanism of versatile photoredox coupling reaction systems.     

考虑电网阻抗耦合的模块化多电平换流器交直流侧阻抗通用计算方法

以模块化多电平换流器(modular multilevel converter,MMC)为技术路线的柔性直流输电技术在风电接入、电网异步互联等领域迅速发展。MMC的阻抗建模是分析柔性直流输电系统振荡起源的重要依据。文中分析MMC在交、直流侧激励下的谐波传递机制,建立一种适用于交、直流侧阻抗计算的通用方法。对一次系统频域建模关联了MMC所连接的交、直流侧网络阻抗,并考虑包含解耦双同步参考坐标系锁相环及负序内环控制在内的全部控制模块。通过求解线性方程组对MMC阻抗进行计算,并在PSCAD/EMTDC环境中对双端背靠背MMC系统在多种工况下1～5kHz频段内进行扫频,验证该方法的准确性,并详细分析网络阻抗耦合、控制链路延时、功率等级、负序内环和外环控制等因素对MMC阻抗的影响。     

Studies on microbridges of superconducting YBCO thin film

Critical current densities of the superconducting Y-Ba-Cu-O (YBCO) films have been observed to decrease with the increase of power of microwave radiation. Presence of Josephson type of junctions in the microbridges has been established from the microwave irradiation and magnetic field studies. BCS energy gap parameter (2/kT _c ) has been calculated from thedI/dV characteristics and found to be 3.7 at 13 K.     

Evanescent wave sensor based on permanently bent single mode optical fiber

A novel refractive index sensing scheme based on evanescent wave interaction through locally and permanently bent single mode optical fibers is proposed. Local and permanent bends in single mode optical fibers enable significant power coupling between core and cladding modes. Order and number of excited cladding modes depend on bend features and determine the field profile at the output of the bent region. This in turn constitutes a simple mechanism to tailor the field distribution in single mode optical fibers useful for spatial light modulation. Moreover, since guided cladding modes are strongly influenced by the surrounding refractive index (SRI), the power transmitted at the output of the bent region as well as its dependence on the optical wavelength are strongly sensitive to the SRI opening new scenarios in sensing applications.     

Keyboard design through physiological strain measurements

The physiologically tolerable range of positions for the joints of the upper extremities have been investigated for typing tasks by recording the myoelectric activities of the involved muscles. For long-term typing tasks a split keyboard is recommended allocating a key field to each hand. The fields should be rotated against each other in the horizontal plane and inclined laterally.     

Process control and risky decision-making: moderation by general mental ability and need for cognition

Human factors and ergonomics research could benefit from focusing more strongly on individual differences – especially trait variables. The present study suggests the analysis of moderator effects as a promising way to enhance understanding of trait variables and process control performance. Process control performance was studied by analysing moderator effects of general mental ability (GMA) and need for cognition (NC) on risky decision-making (RDM) and performance. Fifty engineering students were trained on a process control task using a computer-based simulation for three hours and tested twice thereafter. Risky decision-making was measured using a computerised gambling task while GMA and NC were assessed with questionnaires. Risky decision-making in interaction with each GMA and NC explained variance in performance over and above variance explained by the single effects. In conclusion, the analysis of moderator effects between individual difference variables and process control performance seems promising.

Practitioner Summary: Individual difference variables affect learning and performance, but have often not been studied to any great extent in human factors research. This article suggests a promising approach to studying individual differences – moderator analyses – and illustrates how such differences can lead to a better understanding of what determines process control performance.