基于吲哚类半花菁染料的钯比率荧光探针

利用6-羟基萘-2-醛和碘化N-乙基-2,3,3-三甲基-3H-吲哚啉季铵盐的缩合反应生成的羟基半花菁染料2与氯甲酸烯丙酯的反应合成了荧光比率型钯探针1.研究表明:在含水介质中,探针1对钯(Pd0和Pd2+)显示出很高的敏感性、选择性和抗干扰性,其荧光比率增强大约72倍,对Pd2+的最低检测极限为0.23μmol/L.探针1对钯的作用机理是钯催化碳酸烯丙酯断裂导致比率荧光变化.     

Aggregate‐induced emission in light‐emitting liquid crystal display technology

Nowadays, liquid crystal displays (LCDs) with light‐emission are considered as energy‐efficient devices and are promising alternatives to conventional LCDs. To realize such possibility, strong fluorescent materials with a dichroic properties are required. Aggregate‐induced emission (AIE) is an unusual photophysical phenomenon shown by some luminogenic materials that will be highly emissive in their aggregate state. In this work, we studied the AIE effect of a luminescent liquid crystalline molecule TPE‐PPE in our LC system as a luminophore dopant. The result showed the excellent AIE effect that higher concentration of luminogen in the nematic LC host induced stronger luminescent intensity. Through exposure of a photoisomeriable alignment material sulfonic‐dye‐1, the photopatterning of a light‐emitting LC device was achieved with the use of the TPE‐PPE/nematic LC mixture.     

A Boronate Ester Driven Rechargeable Antibacterial Membrane for Fast Molecular Sieving

Membrane decorated with biocides is an effective way to suppress biofilm growth. However, their immediate biocidal effect usually suffers from a significant decline due to the irreversible consumption of the biocides. Here, a smart nanofiltration membrane is reported with rechargeable antibacterial capability that is fabricated by a facile interfacial polymerization via 3-aminophenylboronic acid and trimesoyl chloride on a polysulfone substrate. Biocides bearing diol groups can be grafted onto the membrane surface under neutral/alkaline condition and then released from the surface under acidic environment, due to the pH-responsive feature of boronate ester complexes. The resultant membrane exhibits integrated properties of fast bacterial inactivating efficiency, rechargeable antibacterial capability, and impressive stability. In addition, the achieved membrane shows remarkable separation efficiency to dye/monovalent salt system. The successful fabrication of the membrane with rechargeable anti-bacterial property provides new insights into the development of pH-responsive and sustainable antibacterial membranes.     

Defect‐Laden MoSe2 Quantum Dots Made by Turbulent Shear Mixing as Enhanced Electrocatalysts

A high density of edge sites and other defects can significantly improve the catalytic activity of layered 2D materials. Herein, this study demonstrates a novel top‐down strategy to maximize catalytic edge sites of MoSe₂ by breaking up bulk MoSe₂ into quantum dots (QDs) via “turbulent shear mixing” (TSM). The ultrasmall size of the MoSe₂ QDs provides a high fraction of atoms in reactive edge sites, thus significantly improving the catalytic activities. The violent TSM further introduces abundant defects as additional active sites for electrocatalytic reactions. These edge‐proliferated and defect‐laden MoSe₂ QDs are found to be efficient electrocatalysts for the hydrogen evolution reaction, and useful as counter electrodes in dye‐sensitized solar cells. The work provides a new paradigm for creating edge‐proliferated and defect‐rich QDs from bulk layered materials.     

Synthesis and characterization of novel blue azo‐dye derivatives containing acrylate group for dye‐based color filters

Abstract— Even though dyes have a fine resolution and good chromaticities, they are not widely used as coloring materials for color filters (CFs) due to their low thermal stability and chemical resistance. A series of azo‐dye derivatives, which consist of two cross‐linkable acrylate or methacrylate groups to improve thermal and chemical properties, have been synthesized and used to fabricate color filters. The spectral properties and chemical/thermal stabilities of the fabricated CFs were investigated by comparing dye‐based CFs, without a complicated dispersion process, but with pigment‐based CFs using dispersed pigment. Also, more properties including the development test and surface morphologies lithographic properties were studied. The synthesized azo dyes were characterized by elemental analysis, UV‐visible spectra, IR, mass, and ¹H‐NMR spectra.     

Treatment of textile dye effluent using a self-made positively charged nanofiltration membrane

A self-made positively charged nanofi ltration(NF)membrane was used to treat textile dye effluent to generate water for reuse,and the factors affecting nanofi ltration process such as operating pressure,feed flow and membrane cleaning were investigated.With an applied pressure of 1.0 MPa and a feed flow of 40 L/h,this NF membrane has a removal of 93.3% for CODcr and a reduction of approximately 51.0% in TDS,salinity and conductivity achieving the chroma removal of 100%.The permeate obtained through this membrane is suitable for recycling.Moreover,the membrane could be reused after being cleaned with 1% NaOH solution.     

提高锦纶超细纤维匀染性的方法研究

针对锦纶超细纤维上染速率快、竭染率高、且容易产生上染不匀和染色牢度差等问题,从酸性染料的浓度、染色工艺的确定、以及匀染剂的使用等方面,探讨各因素对匀染性的影响．实验结果表明,浓度为3％（owf）,匀染剂用量为2％（owf）,浴比1：50,pH=5．5,100℃保温50min时,可得到较好匀染效果的织物,且耐磨擦牢度可提高至2-3级．     

层状土入渗试验中指流发育的分形特征及入渗规律

土质结构差异较大的层状土入渗过程中易出现指流.为了了解层状土下层介质对指流发生发育的影响,以三种不同粒径的石英砂为下层介质和以砂壤土为上层介质进行了室内积水入渗的染色示踪试验.结果表明,下层介质粒径越大越易出现指流,且指流行进速度越快.指流发生后,入渗过程趋向于稳定,且下层土壤粒径越大,稳定入渗率与累积入渗量越小.采用湿润面积和湿润比描述指流发育的宏观特性,发现湿润面积和平均湿润比都随时间而增大,表明湿润锋趋于均匀.为定量研究层状土入渗中指流发育的分形特征,采用像素点覆盖法编制了计算染色示踪试验中分形维数发育的Matlab程序,对程序进行了验证并计算了四组试验指流发育的计盒维数.结果表明指流分布具有明显的分形特征,下层介质粒径越大计盒维数越小,且计盒维数随时间而增大.     

功能化Fe_3O_4对水中亚甲基蓝染料的吸附性能研究

通过共沉淀法制备了磁性Fe_3O_4纳米粒子,并将其表面包覆二氧化硅外壳,制备了性质稳定,脱色性能较好,同时易于固液分离的功能化磁性纳米粒子.以模拟印染废水的脱色为目标,研究了pH、温度、吸附时间等因素对脱色效果的影响.研究结果表明,磁性吸附剂制备成本低,对亚甲基蓝溶液的脱色效率显著.     

紫外光接枝改性染料棉织物的性能分析

以2-甲基-3-丁烯-2-醇为单体,对C.I.活性红198染料进行改性,经紫外光引发将改性染料接枝到棉织物的表面而实现染色。在正交法和单因素法探讨得出的最佳工艺条件下,对光接枝染色的织物性能进行分析。结果表明,与浸染染色法相比较,光接枝染色织物的染色深度为浸染染色织物的63.4%,拉伸性能降低了3%,透气性减少了21.3%,柔软性能略下降,表面粗糙度增加。