应用BP神经网络的单机架可逆式冷轧机弯辊力预设定

针对单机架可逆式冷轧机生产过程中，由于不同热轧生产厂的热轧板形原料性能、板形差别较大、从而造成弯辊力预设定值和实际指标相差较大的问题，利用现场生产工艺数据丰富，采用人工智能BP神经网络的方法，通过大量数据输入进行训练，大大的提高了生产过程中弯辊力预设定值的准确性。     

Effect of ultrasonic power and bonding force on the bonding strength of copper ball bonds

Copper wire, serving as a cost-saving alternative to gold wire, has been used in many high-end thermosonic ball bonding applications. In this paper, the bond shear force, bond shear strength, and the ball bond diameter are adopted to evaluate the bonding quality. It is concluded that the ef/~cient ultrasonic power is needed to soften the ball to form the copper bonds with high bonding strength. However, excessive ultrasonic power would serve as a fatigue loading to weaken the bonding. Excessive or less bonding force would cause cratering in the silicon.     

Al-18%Si合金在梯度强磁场中凝固时初生硅的行为

研究了Al-18%Si合金在10 T梯度强磁场下加热至半固态和全熔态后的凝固过程,观察了初生硅的分布和形态,测定了其冷却曲线.结果表明:在磁场的磁感应强度和磁场梯度的乘积Bz·dBz/dz为正时,初生硅向上部聚集;而在Bz·dBz/dz为负时,初生硅向下部聚集;在强磁场下,加热至全熔态冷却下来的凝固组织中初晶硅的形态发生了明显的改变,由板片状转变为块状,初晶硅显著细化.对强磁场细化初晶硅的机制进行了探讨.     

奥氏体不锈钢车削时刀具磨损对切削因素和表面质量的影响研究

研究了奥氏体不锈钢车削加工过程中刀具后刀面磨损对切削力、切削温度、粗糙度及残余应力影响规律。试验结果表明:当刀具后刀面磨损在一定范围内,F_x与F_z随磨损量的增加而显著增大,而F_y基本保持不变;温度随刀具后刀面磨损量增加而显著增大;工件的表面粗糙度随刀具后刀面磨损量增大而增大;当车刀后刀面磨损为0.167 mm时,工件加工表面的残余应力最大。     

电磁成形中的测量

本文简要介绍了电磁成形中放电电流、管坯与线圈间隙中的磁场测量 ,以及管坯动态变形过程测量的各种方法。通过各种方法的比较分析 ,得出分流器法测放电电流、探测线圈法测感生磁场是切实可行的方法。金属坯料在电磁力作用下的变形过程可用撞针法和高速摄影的办法进行测量 ,每种方法各有其优势和适用范围 ,测量时 ,根据实际情况进行选用。     

由二氧化碳出发合成有机碳酸酯

对以二氧化碳为原料合成有机碳酸酯的环氧路线、酯交换和直接合成方法作了综合评述 ,认为直接合成是最佳的合成路线。碳酸酯的直接合成可在均相及多相催化体系中进行 ,负载金属、金属甲氧基化合物及碱均可作为催化剂。直接法研究的关键在于高性能催化剂的开发、由二氧化碳对金属 -氧键插入反应导致的催化循环的构筑及耦合反应的应用。     

Direct ethoxylation of fatty methyl ester over Al-Mg composite oxide catalyst

For the purpose of estimating the reaction mechanism of the direct ethoxylation of a fatty ester in the presence of an Al-Mg composite oxide catalyst, a labeled fatty methyl ester C₁₁H₂₃CO¹⁸OCH₃ containing ¹⁸O isotope was synthesized and directly ethoxylated. The product was evaluated by gas chromatography-mass spectrometry (GC-MS). The GC-MS spectra showed that the ¹⁸O isotope label was present only in the methoxy group at the molecular end of the ethoxylated fatty methyl ester. This supports the reaction mechanism of coordination anionic polymerization where the bond between the acyl and methoxy groups of the fatty methyl ester molecule was broken, caused by the bifunctional effect of the acid-base active sites; an intermediate chemisorption species was formed; and then ethylene oxide was addition-polymerized sequentially, in parallel.     

Microstructure and morphology of amine-cured epoxy coatings before and after outdoor exposures—An AFM study

Atomic force microscopy (AFM) has been used to study the morphology and microstructure of an amine-cured epoxy before and after outdoor exposure. Measurements were made from samples prepared in an essentially CO₂-free, H₂O-free glove box and from samples prepared in ambient conditions. For those prepared in a CO₂-free glove box, AFM imaging was conducted on (1) an unexposed air/coating surface, (2) an unexposed coating bulk, (3) an unexposed coating/substrate interface, and (4) a field exposed air/coating surface. For samples prepared in ambient conditions, only the unexposed air/coating surface was investigated. The same regions of the exposed samples were scanned periodically by the AFM to monitor changes in the surface morphology of the coating as UV exposure progressed. Small angle neutron scattering and Fourier transform infrared spectroscopy (FTIR) studies were performed to verify the microstructure and to follow chemical changes during outdoor exposure, respectively. The results have shown that amine blushing, which occurs only under ambient conditions, had a significant effect on the surface morphology and microstructure of the epoxy. The surface morphology of the samples prepared under CO₂-free, dry conditions was generally smooth and homogeneous. However, the interface and the bulk samples clearly revealed a two-phase structure consisting of bright nodular domains and dark interstitial regions, indicating an inhomogeneous microstructure. Such heterogeneous structure of the bulk was in good agreement with results obtained by small angle neutron scattering of unexposed samples and by AFM phase imaging of the degraded sample surface. The relationship between submicrometer physical changes and molecular chemical degradation is discussed. Presented at the 82nd Annual Meeting of the Federation of Societies for Coatings Technology, October 27–29, 2004, in Chicago, IL.     

熔体直纺工艺中粘度波动对长丝质量的影响

讨论了熔体粘度波动时熔体的可纺性、POY的物性指标及后加工性能、DTY的质量指标及其染色等情况。结果表明;熔体粘度偏低时,前纺飘丝断头增多,后纺伸头困难,POY和DTY的强度降低、伸长度增大,DTY有较多的点状僵丝,袜带吸色较深且有较多的色斑点;熔体粘度偏高时,熔体泵前压力偏低,后加工张力高,纸筒管易于破裂。POY和DTY纤度偏小,强度增大,伸长度减小,各种不匀增大,袜带吸色较浅且较为均匀。初步确定熔体粘度的波动范围应控制在1.615—1.650.     

甲乙酮工艺水处理装置的改造与应用

根据引进的甲乙酮生产装置仲丁醇反应工艺水处理中出现的问题，对所得实验数据进行分析，最终确定工艺水处理改造方案，并取得了良好的效果，使工艺水处理应用技术得到进一步提高。