纤维素科学与技术研究进展

本文综述纤维素科学与技术的研究进展。阐述了纤维素结构、纤维素的合成、纤维素液晶、功能纤维素、纤维素溶剂、纤维素裂解和纤维素的废物利用等的最新动态。     

Different support effect of M/ZrO2 and M/CeO2 (M = Pd and Pt) catalysts on CO adsorption: A periodic density functional study

CO adsorption over Pd₄ and Pt₄ cluster supported by c-ZrO₂(1 1 1) and CeO₂(1 1 1) catalyst systems was investigated using periodic density functional method in order to clarify the support effect on CO activation. We found that the support increases the CO activation for bridge and three-fold sites but decreases for the atop site. Moreover, it was found that the support changes the site preference for the CO adsorption. Bridge site on both the Pt₄/c-ZrO₂ and Pt₄/CeO₂ show larger CO adsorption energies than those on the other sites while the atop site is energetically preferable on isolated Pt₄ cluster. c-ZrO₂ supported Pd shows the largest CO activation with large charge transfer from the catalyst to the CO molecule. This reveals that ZrO₂ supported Pd can be a good catalyst for CO activation because of its higher probability to the three-fold site CO adsorption. We also found that positively charged M₄ clusters on the support keep their strong electron-donating properties and have enough charge density to contribute to the activation of an adsorbed CO molecule by a charge transfer.     

基于十二烷基衣康酸甘油酯的光电双响应传感器

该文制备了一种利用结构色水凝胶作为导电电极的光电双响应传感器。以十二烷基衣康酸甘油酯(DGI)、丙烯酰胺、十二烷基硫酸钠(SDS)、氯化钠等为原料,通过双分子层自组装的方法,制备了结构色水凝胶。将这种结构色水凝胶与传统电容型传感器相结合,得到了光电双响应传感器。采用SEM、LCR数字电桥、拉力试验机、光纤光谱仪等对器件进行了结构、光学、电学及机械性能的表征。结果表明:传感器在拉伸状态(0～100%)和压缩状态(0～60.9k Pa)下,传感器的电容分别变化了31%和44%,其自身颜色在可见光光谱内可以动态可逆地从红色变化到紫色。经历15000次循环拉伸后,传感器性能依旧保持稳定。利用传感器颜色的刺激响应性,传感器在发生形变时,其表面可以清楚地显示出应变源的位置和形状,这样传感器在检测时就可以实现可视化效果。     

How social distance shapes human–robot interaction

This paper investigates how social distance can serve as a lens through which we can understand human–robot relationships and develop guidelines for robot design. In two studies, we examine the effects of distance based on physical proximity (proxemic distance), organizational status (power distance), and task structure (task distance) on people׳s experiences with and perceptions of a humanlike robot. In Study 1, participants (n=32) played a card-matching game with a humanlike robot. We manipulated the power distance (supervisor vs. subordinate) and proxemic distance (close vs. distant) between participants and the robot. Participants who interacted with the supervisor robot reported a more positive user experience when the robot was close than when the robot was distant, while interactions with the subordinate robot resulted in a more positive experience when the robot was distant than when the robot was close. In Study 2, participants (n=32) played the game in two different task distances (cooperation vs. competition) and proxemic distances (close vs. distant). Participants who cooperated with the robot reported a more positive experience when the robot was distant than when it was close. In contrast, competing with the robot resulted in a more positive experience when it was close than when the robot was distant. The findings from the two studies highlight the importance of consistency between the status and proxemic behaviors of the robot and of task interdependency in fostering cooperation between the robot and its users. This work also demonstrates how social distance may guide efforts toward a better understanding of human–robot interaction and the development of effective design guidelines.     

A comprehensive approach to evaluating watershed models for predicting river flow regimes critical to downstream ecosystem services

Selection of strategies that help reduce riverine inputs requires numerical models that accurately quantify hydrologic processes. While numerous models exist, information on how to evaluate and select the most robust models is limited. Toward this end, we developed a comprehensive approach that helps evaluate watershed models in their ability to simulate flow regimes critical to downstream ecosystem services. We demonstrated the method using the Soil and Water Assessment Tool (SWAT), the Hydrological Simulation Program–FORTRAN (HSPF) model, and Distributed Large Basin Runoff Model (DLBRM) applied to the Maumee River Basin (USA). The approach helped in identifying that each model simulated flows within acceptable ranges. However, each was limited in its ability to simulate flows triggered by extreme weather events, owing to algorithms not being optimized for such events and mismatched physiographic watershed conditions. Ultimately, we found HSPF to best predict river flow, whereas SWAT offered the most flexibility for evaluating agricultural management practices.     

Adaptive tracking control of an autonomous underwater vehicle

This paper presents the trajectory tracking control of an autonomous underwater vehicle(AUV). To cope with parametric uncertainties owing to the hydrodynamic effect, an adaptive control law is developed for the AUV to track the desired trajectory. This desired state-dependent regressor matrix-based controller provides consistent results under hydrodynamic parametric uncertainties.Stability of the developed controller is verified using the Lyapunov s direct method. Numerical simulations are carried out to study the efficacy of the proposed adaptive controller.     

基于国家电网的财务管理系统的开发与研究

随着社会生产力的不断发展,越来越多的企业认识到了财务工作的重要性。企业要利用现代高效的运作方式来开发和管理组织中最重要、最昂贵的资源,实现财务管理的精细化、自动化,提高财务资源的利用率,促进企业的发展。     

液晶材料取代联苯硼酸化合物的研究

以液晶材料取代联苯硼酸化合物异构体混合物为原料,在相转移催化剂正十六烷基三甲基溴化胺的作用下,于碱性条件下,105~115℃反应3~8 h,得到液晶材料取代联苯化合物,它是生产相应的液晶材料取代联苯硼酸化合物的初始原料。并对其结构进行了质谱确认。     

基于时滞分割法的区间变时滞不确定系统鲁棒稳定新判据

针对一类存在泛数有界不确性的区间变时滞线性系统, 利用Lyapunov-Krasovskii (L-K) 泛函方法并结合线性矩阵不等式(LMI) 技术建立一种新的保守性更低的鲁棒稳定性判据. 首先基于时滞分割方法将时滞区间均分成N 等分, 针对不同的子区间构造合适的L-K 泛函; 然后在各自的分割区间采用保守性较小的积分不等式处理泛函沿时间的导数, 基于凸组合技术建立了LMI 形式的时滞相关稳定性新判据; 最后通过数值实例验证了结论的有效性.

     

Retaining and attracting users in social networking services: An empirical investigation of cyber migration

Users are the most critical strategic resource of any online social networking service (SNS). This paper offers strategic recommendations for SNS providers based on an empirical study exploring why users switch from a primary SNS to others. We first identify important characteristics that combine to distinguish SNSs from conventional information systems, then develop a “cyber migration” research model that includes push, pull and mooring factors which influence user intention to switch from one SNS to another. Findings from a field survey of 180 users reveal four significant factors that promote switching: dissatisfaction with socialization support, dissatisfaction with entertainment value, continuity cost, and peer influence. Strategies grounded in these factors are suggested for SNS providers to better attract and retain users.