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91.
92.
提出一个基于广义Logistic方程构造的二维混沌映射,采用Feigenbaum常数、相图、分岔图分析的方法,研究该混沌映射的非线性动态特性;然后利用该方程生成混沌序列,将混沌序列进行优化改进,生成密钥序列;最后采用输出反馈的加密方式,改变图像的像素值,达到加密的目的。实验仿真表明,该加密算法对密钥非常敏感,有效地提高了抵御选择明文攻击的能力,密文图像信息熵为7.996 94,非常接近理想值8。加密图像像素值具有类随机均匀分布特性,加密图像和明文图像之间的相关性非常接近于0,相邻像素具有零相关特性,而且密钥空间达到299比特。加密方法大大改变了明文图像的像素值,使得密文能够抵御统计攻击。 相似文献
93.
94.
Influence of Distributed Particle Size on the Determination of the Parabolic Rate Constant for Oxidation by the Powder Method 总被引:1,自引:0,他引:1
The established analysis for the study of oxidation using powder specimens is based on the assumption of monosized particles. The experiments, however, are conducted on powders with a distributed particle size. Here we present a statistical approach for the calculation of the rate constant for oxidation. The results of the analysis are applied to new data on oxidation studies of dense powders of silicon carbonitride amorphous ceramics. The monosized model requires a wide range of values for the rate constant to fit the short term and the long-term data, leading to considerable ambiguity in the estimate of the parabolic rate constant, k p , for oxidation. In contrast the statistical model fits over the entire range of data, yielding a much more reliable value for k p . For example, the monosized approach gave a value in the range 19.7 × 10−18 < k p < 2.7 × 10−18 m2 /s. In contrast, the statistical model yields a specific value of 4.5 × 10−18 m2 /s. 相似文献
95.
The solubility of CO2 in triethylene glycol monomethyl ether (TEGMME) has been measured at 40, 70 and 100°C at pressures up to 8.8 MPa. The results were correlated with the Peng-Robinson (1976) equation of state. The interaction parameters and Henry's constants were derived. 相似文献
96.
A theoretical DFT study was employed to confirm the Kolbe-Schmitt reaction mechanism and investigate solvent effects on this reaction. The use of a solvent in the Kolbe-Schmitt reaction is desirable to facilitate a homogeneous reaction mixture and potentially improve the reaction rate. The candidate solvents were designed using computer aided molecular design (CAMD) and tested using DFT solvation calculations. The results from the quantum mechanical calculations were then used to determine the rate constants for each elementary step, the overall reaction yields and the corresponding residence time. The methodology was tested on the reaction without solvent, with solvents reported in the literature, and with the designed solvents. The study revealed that in the presence of solvents with high dielectric constant the reaction becomes reversible, leading to low product yields. 相似文献
97.
在多个领域都会用到恒温控制系统,设计一种基于变速积分PID的恒温控制系统,系统以STM32为核心处理器。该文讲述了系统的构成,分析了变速积分PID算法,并在恒温控制系统中得到运用。经过长时间的调试,得到合适的PID系数,使得系统的控制精度达到&#177;0.01℃/30min。系统具有性能稳定,可靠性高的优点。 相似文献
98.
研究了meso-四卟啉和meso-四卟啉的离解常数。TBPhP的离解常数为:pKa4=1.13.pKa3=1.88,pKA2=12.21;TTPS的离解常数为:pKa4=4.47,pKa3=6.26。外还发现了两卟啉的酸碱诱导聚合。 相似文献
99.
We have synthesized a series of fully aliphatic polyimides (APIs) from bicyclo[2,2,2]oct‐7‐ene‐2,3,5,6‐tetracarboxylic dianhydride (BOCA) and various aliphatic diamines, including linear aliphatic, flexible alicyclic, and rigid adamantyl diamines. We performed the polymerization reactions using one‐step syntheses in m‐cresol at elevated temperatures without the isolation of poly(amic) acid. The chemical composition and structure of the polymers were characterized by nuclear magnetic resonance (NMR) and infrared (IR) spectrometry. The characterization data are reported from analyses using gel permeation chromatography (GPC), thermogravimetric analysis (TGA), differential scanning calorimeter (DSC), and wide‐angle X‐ray diffraction (WXAD) measurements. The polyimides are also subjected to solubility, solution viscosity, tensile strength, transparency, and dielectric constant measurements. The resultant polyimides possess well‐controlled molecular weight, reasonable intrinsic viscosity, good transparency, enhanced solubility, low dielectric constants, and high glass transition temperature, together with marginal thermal and mechanical stability. These properties were enhanced in copolyimides containing equimolar amounts of rigid and flexible moieties. These rigid‐rod APIs derived from the alicyclic dianhydride and aliphatic diamines are promising candidates as advanced materials for future applications in micro‐ and photoelectronic devices. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 102: 3316–3326, 2006 相似文献
100.
Many rate constants of elementary steps on single crystals have been measured. Their pre-exponential factors can now be compared to those calculated by transition state theory. Such a calculation is presented in this Letter with due attention to microscopic reversibility, standard states, and configurational entropy. 相似文献