Pseudocapacitive Sodium Storage by Ferroelectric Sn2P2S6 with Layered Nanostructure

Sodium ion batteries (SIB) are considered promising alternative candidates for lithium ion batteries (LIB) because of the wide availability and low cost of sodium, therefore the development of alternative sodium storage materials with comparable performance to LIB is urgently desired. The sodium ions with larger sizes resist intercalation or alloying because of slow reaction kinetics. Most pseudocapacitive sodium storage materials are based on subtle nanomaterial engineering, which is difficult for large‐scale production. Here, ferroelectric Sn₂P₂S₆ with layered nanostructure is developed as sodium ion storage material. The ferroelectricity‐enhanced pseudocapacitance of sodium ion in the interlayer spacing makes the electrochemical reaction easier and faster, endowing the Sn₂P₂S₆ electrode with excellent rate capability and cycle stability. Furthermore, the facile solid state reaction synthesis and common electrode fabrication make the Sn₂P₂S₆ that becomes a promising anode material of SIB.     

Laser‐Assisted Large‐Scale Fabrication of All‐Solid‐State Asymmetrical Micro‐Supercapacitor Array

The micro‐supercapacitors are of great value for portable, flexible, and integrated electronic equipments. Here, the large‐scale and integrated asymmetrical micro‐supercapacitor (AMSC) array is fabricated in virtue of the laser direct writing and electrodeposition technology. The AMSC shows the ideal flexibility, high areal specific capacitance (21.8 mF cm^?2), and good rate capability. Moreover, its energy density reaches 12.16 µW h cm^?2, outperforming most micro‐supercapacitors reported previously. Meanwhile, large‐scale series‐connected AMSCs are integrated on the flexible substrates (e.g., indium tin oxide‐polyethylene terephthalate film), which can power a veriety of the commercial electronics. The combination of AMSCs array, solar cell, and electronic device proves the feasibility for practical application in the portable, flexible, and integrated electronic equipments.     

基于IEEE1588协议时钟同步精度影响因素的研究

随着分布式测试技术的快速发展,对地理位置分散的测试设备协同完成测试任务的需求也越来越大,而设备之间的时钟同步精度成为制约测试效果的关键因素;为了对时钟同步精度的影响因素进行研究,提出了基于IEEE1588协议的网络时钟同步实现方案;首先对IEEE1588基本原理进行分析,然后提出了IEEE1588协议的实现方案,最后搭建实验平台对影响同步精度的因素进行研究;研究结果表明,同步间隔和网络拓扑结构影响时钟同步精度的两个主要因素。     

基于XMC4500的汽车CAN网络检测卡设计

CAN总线作为车用网络的主要应用总线技术,通过CAN总线获得汽车运行时的实时数据成为汽车电子系统研发、维修及故障分析的主要手段;在对传统CAN总线检测卡分析及研究的基础上,为了使移动PC更加便捷地分析及记录汽车CAN网络中的数据,使基于串口通讯的系统及应用软件能够方便地继承使用,设计了基于XMC4500单片机的汽车CAN网络检测卡;实现了将汽车CAN网络中的数据通过USB端口虚拟的高速串口传输至上位机、实时备份相关数据到Micro SD卡中的功能;实验数据显示在最高1 000kb/s的传输速率下,能够100%正确接收及存储相关数据,满足对该卡实时性和可靠性的要求。     

1–MCP结合EA对蓝靛果贮藏品质及活性氧代谢的影响

目的 探究不同处理对贮藏0~60 d期间蓝靛果实贮藏品质及活性氧(ROS)代谢的影响,为蓝靛果贮藏保鲜提供技术依据。方法 以蓝靛果为实验材料,采后将其装入保鲜箱中,用1−甲基环丙烯(1-MCP)、乙烯吸收剂(EA)、1-MCP+EA进行处理,在(−0.5±0.3)℃下贮藏60 d,每隔15 d取样观察果实的感官品质,并测定其营养、生理及活性氧代谢相关指标。结果 与对照组相比,3种处理方式均能保持果实较好的感官特性,延缓果实抗坏血酸、花色苷、总酚和黄酮等含量的流失,以及果实的软化;在贮藏60 d时,处理组果实的呼吸强度分别比对照组果实的呼吸强度低22.73、12.92、34.04 mg/(kg.h),乙烯生成速率分别比对照组果实的低6.38、3.98、10.11 μL/(kg.h);可抑制超氧阴离子(O2⁻.)活性、过氧化氢(H2O2)含量、丙二醛含量及相对电导率的升高,保持较高的超氧化物歧化酶(SOD)、过氧化氢酶(CAT)、过氧化物酶(POD)、抗坏血酸过氧化物酶(APX)活性。通过SPSS分析可知,综合得分顺序为CK＜EA＜1-MCP＜1-MCP+EA,表明1-MCP+EA处理的效果最好。结论 1-MCP+EA处理对蓝靛果贮藏60 d的保鲜效果最好,可更好地保留果实的外观和内在品质,利于运输和销售。     

磁悬浮飞轮储能系统机电耦合非线性动力学研究

针对磁悬浮飞轮储能系统的"磁悬浮飞轮-发电机"机电耦合非线性动力学特性进行研究.通过推导磁悬浮飞轮储能系统在偏心条件下的动能、势能、发电机系统的磁场能以及系统的耗散函数,由Lagrange-Maxwell方程建立磁悬浮飞轮系统和两相四极永磁发电机系统的机电耦合动力学方程.采用数值法对0.6MW磁悬浮飞轮储能系统进行了仿真分析,研究结果表明,系统机电耦合非线性方程存在稳定的与转速同频的基频和三倍频周期运动解,且基频振动幅值比三倍频振动幅值大.对于稳定的磁悬浮储能飞轮机电耦合系统,飞轮转速增大,或磁轴承系统刚度减小或阻尼增大,或磁场能(电枢反应磁场能或永磁励磁磁场能)减小,可使系统的非线性振动幅值减小.而增大磁轴承系统的刚度,或减小磁轴承系统的阻尼,或增大系统的磁场能有可能破坏机电耦合系统的稳定性,使飞轮失稳.     

Common Knowledge and Update in Finite Environments

Logics of knowledge have been shown to provide a useful approach to the high level specification and analysis of distributed systems. It has been proposed that such systems can be developed using knowledge- based protocols, in which agents' actions have preconditions that test their state of knowledge. Both computer-assisted analysis of the knowledge properties of systems and automated compilation of knowledge-based protocols require the development of algorithms for the computation of states of knowledge. This paper studies one of the computational problems of interest, the model checking problem for knowledge formulae in the S5_nKripke structures generated by finite state environments in which states determine an observation for each agent. Agents are assumed to have perfect recall and may operate synchronously or asynchronously. It is shown that, in this setting, model checking of common knowledge formulae is intractable, but efficient incremental algorithms are developed for formulae containing only knowledge operators. Connections to knowledge updates and compilation of knowledge-based protocols are discussed.     

Design and Configuration Rationales for Digital Video Storage and Delivery Systems

Recent advances in computing technology have brought multimedia information processing to prominence. The ability to digitize, store, retrieve, process, and transport analog information in digital form has changed the dimensions of information handling. Several architectural and network configurations have been proposed for efficient and reliable digital video delivery systems. However, these proposals succeed only in addressing subsets of the whole problem. In this paper, we discuss the characteristics of video services. These include Cable Television, Pay-Per-View, and Video Repository Centers. We also discuss requirements for Video On Demand services. With respect to these video services, we analyze two important video properties: image quality and response time. We discuss and present configurations of a Digital Video Delivery System (DVDS) from three general system components - servers, clients, and connectivities. Pertinent issues in developing each component are also analyzed. We also present an architecture of a DVDS that can support the various functionalities that exist in the various video services. Lastly, we discuss data allocation strategies which impact performance of interactive video on demand (IVOD). We present preliminary results from a study using a limited form of mirroring to support high performance IVOD.     

5000m~3拱顶油罐失稳原因分析

为了保证油罐使用中的安全性,油罐不仅要具有足够的强度,而且还应该具有可靠的稳定性。应用外压失稳理论分析某厂５０００ｍ３拱顶油罐失稳原因,结果表明,该油罐缺乏足够的稳定性设计;为了保证油罐的稳定性,油罐设计必须符合实际工况条件,油罐施工建造必须保证质量标准。