J‐divergence‐based Power Allocation in Wireless Sensor Networks with Distributed Detection under Correlated Noises

In this paper, the power allocation problem in a wireless sensor network (WSN) with binary distributed detection is considered. It is assumed that the sensors independently transmit their local decisions to a fusion center (FC) through a slow fading orthogonal multiple access channel (OMAC), where, in every channel, the interferences from other devices are considered as correlated noises. In this channel, the associated power allocation optimization problem with equal power constraint is established between statistical distributions under different hypotheses by using the Jeffrey divergence (J‐divergence) as a performance criterion. It is shown that this criterion for the power allocation problem is more efficient compared to other criteria such as mean square error (MSE). Moreover, several numerical simulations and examples are presented to illustrate the effectiveness of the proposed approach.     

Exploiting IP‐layer traffic prediction analytics to allocate spectrum resources using swarm intelligence

Elastic optical networks emerge as a reliable backbone platform covering the next‐generation connectivity requirements. It consists of advanced enabling components that provide the ability for extensive configuration leading to performance improvement in many areas of interest. Higher layer analytics like data from IP traffic prediction can assist in the process of allocating resources at the optical layer. This way, light connections are established more efficiently while targeting specific performance goals. For that purpose, an algorithm is designed and evaluated that exploits traffic prediction of data transfers between nodes of an optical metro or backbone network. Next, it utilizes adaptive functionality based on particle swarm optimization to find paths with available spectrum resources. These resources can facilitate more efficiently the future traffic demand, since traffic prediction data are considered when finding the related paths. The innovative resource allocation method is evaluated using small and very large real topologies. It scales (in execution time and resource usage) according to node increase, executes in feasible time frames, and reduces transponder utilization resulting to increased energy efficiency.     

Apodized chirped fiber Bragg grating for postdispersion compensation in wavelength division multiplexing optical networks

In this paper, a postdispersion compensation unit is proposed leading to a better performance for the optical communication systems. This unit utilizes a chirped fiber Bragg grating (CFBG). For enhanced performance of the CFBG, a proper apodization function is chosen to improve the quality factor (Q‐factor) and the bit error rate (BER) of the system. A 110‐km wavelength division multiplexing (WDM) optical link is investigated. The system performance is evaluated through its Q‐factor, eye diagram, and BER showing best performance when using the Hamming apodization function.     

A Critical Review on Functionalization of Air‐Cathodes for Nonaqueous Li–O2 Batteries

This review reports on the most updated technological aspects of Li–air battery cathode materials. It provides the reader with recent developments, alongside critical views. The requirements for air‐cathodes, as well as the classification and characterization of carbon‐based and carbon‐free air cathodes, are listed. The effects of two major substituent groups of materials, namely carbon and advanced materials (metals, metal‐oxides, metal‐carbides, and metal‐nitrides) aimed at replacing carbon, are discussed in terms of their chemical and electrochemical stability. The report covers aspects of surface chemistry and structure influence on the electrolyte and discharge products stability. The review also reports on the efforts to suppress side reactions and deterioration of the polymeric binders (if a composite electrode is being considered). This is recognized as a means to enhance Li–air battery performance. The report concludes with an outlook and perspective, providing the readers with some insight on other factors and their impact on the long road toward a viable air‐cathode suitable for Li–air battery operations.     

Ionic Liquid Analogs of AlCl3 with Urea Derivatives as Electrolytes for Aluminum Batteries

The ionic liquid analog, formed through the mixture of urea and AlCl₃, has previously shown to serve as a low‐cost electrolyte for an aluminum‐graphite battery, while maintaining good performance and achieving high Coulombic efficiency. Undesirable are the relatively high viscosity and low conductivity of this electrolyte, when compared to chloroaluminate ionic liquids with organic cations. In this work, the fundamental changes to the electrolyte resulting from using derivatives of urea (N‐methyl urea and N‐ethyl urea), again mixed with AlCl₃, are examined. These electrolytes are shown to have significantly lower viscosities (η = 45, 67, and 133 cP when using N‐ethyl urea, N‐methyl urea, and urea, respectively, at 25 °C). The associated batteries exhibit higher intrinsic discharge voltages (2.04 and 2.08 V for N‐methyl urea and N‐ethyl urea electrolytes, respectively, vs 1.95 V for urea system@100 mA g^?1 specific current for ≈5 mg cm^?2 loading), due to changes in concentrations of ionic species. Aluminum deposition is directly observed to primarily occur through reduction of Al₂Cl₇^? when AlCl₃ is present in excess, in contrast to previously suggested cationic Al‐containing species, via operando Raman spectroscopy performed during cyclic voltammetry.     

Circumventing Dedicated Electrolytes in Light‐Emitting Electrochemical Cells

Light‐emitting electrochemical cells (LECs) are devices that utilize efficient ion redistribution to produce high‐efficiency electroluminescence in a simple device architecture. Prototypical polymer LECs utilize three components in the active layer: a luminescent conducting polymer, a salt, and an electrolyte. Similarly, many small‐molecule LECs also utilize an electrolyte to disperse salts. In these systems, the electrolyte is incorporated to efficiently conduct ions and to maintain phase compatibility between all components. However, certain LEC approaches and materials systems enable device operation without a dedicated electrolyte. This review describes the general methods and materials used to circumvent the use of a dedicated electrolyte in LECs. The techniques of synthetically coupling electrolytes, incorporating ionic liquids, and introducing inorganic salts are presented in view of research efforts to date. The use of these techniques in emerging classes of light‐emitting electrochemical cells is also discussed. These approaches have yielded some of the most efficient, long‐lasting, and commercially applicable LECs to date.     

Recent Advances in Optical Engineering of Light‐Emitting Electrochemical Cells

Since the first demonstration of light‐emitting electrochemical cells (LECs) in 1995, much effort has been made to develop this technology for display and lighting. A common LEC generally contains a single emissive layer blended with a salt, which provides mobile ions under a bias. Ions accumulated at electrodes facilitate electrochemical doping such that operation voltage is low even when employing high‐work‐function inert electrodes. The superior properties of simple device architecture, low‐voltage operation, and compatibility with inert metal electrode render LECs suitable for cost‐effective light‐emitting sources. In addition to enormous progress in developing novel emissive materials for LECs, optical engineering has been shown to improve device performance of LECs in an alternative way. Light outcoupling enhancement technologies recycle the trapped light and increase the light output from LECs. Techniques to estimate emission zone position provide a powerful tool to study carrier balance of LECs and to optimize device performance. Spectral tailoring of the output emission from LECs based on microcavity effect and localized surface plasmon resonance of metal nanoparticles improves the intrinsic emission properties of emissive materials by optical means. These reported optical techniques are overviewed in this review.     

Self‐Assembled Room Temperature Multiferroic BiFeO3‐LiFe5O8 Nanocomposites

Multiferroic materials have driven significant research interest due to their promising technological potential. Developing new room‐temperature multiferroics and understanding their fundamental properties are important to reveal unanticipated physical phenomena and potential applications. Here, a new room temperature multiferroic nanocomposite comprised of an ordered ferrimagnetic spinel α‐LiFe₅O₈ (LFO) and a ferroelectric perovskite BiFeO₃ (BFO) is presented. It is observed that lithium (Li)‐doping in BFO favors the formation of LFO spinel as a secondary phase during the synthesis of Li_xBi_1?xFeO₃ ceramics. Multimodal functional and chemical imaging methods are used to map the relationship between doping‐induced phase separation and local ferroic properties in both the BFO‐LFO composite ceramics and self‐assembled nanocomposite thin films. The energetics of phase separation in Li doped BFO and the formation of BFO‐LFO composites are supported by first principles calculations. These findings shed light on Li's role in the formation of a functionally important room temperature multiferroic and open a new approach in the synthesis of light element doped nanocomposites for future energy, sensing, and memory applications.     

A Water Stable,Near‐Zero‐Strain O3‐Layered Titanium‐Based Anode for Long Cycle Sodium‐Ion Battery

Layered transition metal (TM) oxides of the stoichiometry Na_xMO₂ (M = TM) have shown great promise in sodium‐ion batteries (SIBs); however, they are extremely sensitive to moisture. To date, most reported titanium‐based layered anodes exhibit a P2‐type structure. In contrast, O3‐type compounds are rarely investigated and their synthesis is challenging due to their higher percentage of unstable Ti³⁺ than the P2 type. Here, a pure phase and highly crystalline O3‐type Na_0.73Li_0.36Ti_0.73O₂ with high performance is successfully proposed in SIBs. This material delivers a reversible capacity of 108 mAh g^?1 with a stable and safe potential of 0.75 V versus Na/Na⁺. In situ X‐ray diffraction reveals that this material does not undergo any phase transitions and exhibits a near‐zero volume change upon Na⁺ insertion/de‐insertion, which ensures exceptional long cycle life over 6000 cycles. Importantly, it is found that this O3‐Na_0.73Li_0.36Ti_0.73O₂ shows superior moisture stability, even when immersed into water, which are both elusive for conventional layered TM oxides in SIBs. It is believed that the small interlayer distance and high occupation of interlayer vacancy promise such unprecedented water stability.     

Kinetic‐Oriented Construction of MoS2 Synergistic Interface to Boost pH‐Universal Hydrogen Evolution

As a prerequisite for a sustainable energy economy in the future, designing earth‐abundant MoS₂ catalysts with a comparable hydrogen evolution catalytic performance in both acidic and alkaline environments is still an urgent challenge. Decreasing the energy barriers could enhance the catalysts' activity but is not often a strategy for doing so. Here, the first kinetic‐oriented design of the MoS₂‐based heterostructure is presented for pH‐universal hydrogen evolution catalysis by optimizing the electronic structure based on the simultaneous modulation of the 3d‐band‐offsets of Ni, Co, and Mo near the interface. Benefiting from this desirable electronic structure, the obtained MoS₂/CoNi₂S₄ catalyst achieves an ultralow overpotential of 78 and 81 mV at 10 mA cm^?2, and turnover frequency as high as 2.7 and 1.7 s^?1 at the overpotential of 200 mV in alkaline and acidic media, respectively. The MoS₂/CoNi₂S₄ catalyst represents one of the best hydrogen evolution reaction performing ones among MoS₂‐based catalysts reported to date in both alkaline and acidic environments, and equally important is the remarkable long‐term stability with negligible activity loss after maintaining at 10 mA cm^?2 for 48 h in both acid and base. This work highlights the potential to deeply understand and rationally design highly efficient pH‐universal electrocatalysts for future energy storage and delivery.